ECAT Pre Engineering Chemistry Chapter 8 MCQ Test With Answer

• Moles per dm³ A
• Partial pressures B
• Number of moles C
• Mole fractions D

For which system does the equilibrium constant, KC has units of concentration

• 
  A
• 
  B
• 
  C
• 
  D

The pH of 10^-3mole dm^-3of an aqueous solution of H₂SO₄is

• 3.0 A
• 2.7 B
• 2.0 C
• 1.5 D

If pH of buffer of 1 mole dm^-3of HCOOH + 0.1 mole dm^-3HCOONa having pKa = 3.78 is

• 1.78 A
• 2.78 B
• 3.78 C
• 4.78 D

According to Le-Chatelier's principal, adding heat to a solid and liquid in equilibrium will cause the

• Amount of solid to decrease A
• Amount of liquid to decrease B
• Temperature to rise C
• Temperature to fall D

• High temperature A
• Low temperature B
• Low pressure C
• High pressure D

A chemical reaction A---------->B is said to be in equilibrium when :

• Rate of transformation of A to B is equal to B to A. A
• 50% reactant has been changed to B. B
• Conversion of A to B is 50% complete C
• Complete conversion of A to B has taken place. D

• KC = KP A
• Kp = KcRT B
• Kp = kc(RT)^-2 C
• Kp = Kc(RT)^-1 D

In which of the following cases, the reaction goes farthest to completion

• K = 10³ A
• K = 10^-2 B
• K = 10 C
• K = 10⁰ D

The value of K_pis greater than K_cfor a gaseous reaction when

• Number of molecules of products is greater than the reactants A
• Number of molecules of reactants is greater than those of products B
• Number of molecules of reactants and products equal C
• Catalyst is added D

In the particular reaction for the valueK_{c 1 x}10^-25which statement is correct :

• Almost forward reaction is completed. A
• Amount of reactant is negligible as compared to product. B
• Amount of product is negligible as compared to reactant. C
• Amount of product is equal to amount of reactant. D

K_bfor NH₄OH is 1.81 x 10^-5, then K_avalue of its conjugate base is

• 1.81 x 10⁺⁵ A
• 1.81 x 10^-9 B
• 5.5 x 10^-9 C
• 5.5 x 10^-10 D

• Initial concentration of acetic acid A
• Initial concentration of ethyl acetate B
• Equilibrium concentration of acetic acid C
• Equilibrium concentration of ethyl acetate D

The state of equilibrium refers to

• State of rest A
• Dynamic state B
• Stationary state C
• State of inertness D

For which system does the equilibrium constant, kc has units of (concentration) ?

• N₂+3H_2-------2NH₃

  A

• H₂+L₂---------2HL

  B

• 2NO₂----------N₂O₄

  C

• 2HF--------H2+F₂

  D

The solubility product of AgCl is 2.0 x 10^-3 mol² dm^-6 , The maximum concentration of Ag ion in the solution is :

• 2.0 x 10^-10 mol dm^-3

  A

• 1.41 x 10^-10 mol dm^-3

  B

• 1.0 x 10^-10 mol dm^-3

  C

• 4.0 x 10^-10 mol dm^-3

  D

2SO₂+ O₂⇌2SO₂H= 188KJ mole^-1

Which statement about following equilibrium is correct :

• The value ofK_pfalls with arise in temperature.

  A

• The value ofK_pis equal tok_c.

  B

• The value ofK_pfalls with the increase pressure.

  C

• Adding V₂O₅catalyst increase the equilibrium yield of Sulphur trioxide.

  D

pH of the human blood which is essentially maintained constant due to carbonates, biocarbonates, phosphates etc., is

• 7.00 A
• 7.25 B
• 7.35 C
• 7.47 D

pH and pKa of the buffer are related by Henderson equation which is

• 
  A
• 
  B
• 
  C
• 
  D

The rate of reaction :

• Remain same as reaction proceeds. A
• May decrease or increase as reaction proceeds . B
• Increase as reaction proceeds. C
• Decreases as reaction proceeds. D

• Temperature is increased A
• Pressure is increased B
• HCl is added C
• HCl is removed D

A gas bulb is filled with NO₂gas and immersed in an ice bath at 0°C which becomes colourless after sometimes. This colourless gas will be

• NO₂ A
• N₂O B
• N₂O₄ C
• N₂O₅ D

• 
  A
• 
  B
• 
  C
• 
  D

The substance which increases rate of reaction but remains unchanged at the end of reaction is called :

• Catalyst. A
• Indicator. B
• Promoter. C
• Activator. D

In 1000 molecules of 0.001 M acetic acid the number of H⁺ions is 12.6, then its percentage of ionization is

• 1.33% A
• 1.26% B
• 12.6 C
• 1% D

For which system does the equilibrium constant. K_c has units of

• 
  A
• 
  B
• 
  C
• 
  D

• The value of K_pfalls with rise in temperature A
• The value of K_pfalls with increasing pressure B
• Addition of V₂O₅catalyst increase the concentration of SO₃ C
• The value of K_pis equal to K_c D

When H₂and I₂are mixed and equilibrium is attained, then

• Amount of HI formed is equal to the amount of H₂dissociated A
• HI dissociation stops B
• The reaction stops completely C
• None of these D

Which of the following solution have zero pH

• 1 M HCI A
• MH₂SO₄ B
• 0.1 M HNO₃ C
• 1 M CH₃COOH D

• [A] = [B] A
• [A] < [B] B
• [B] = [C] C
• [A] > [B] D