ECAT Pre Engineering Chemistry Chapter 8 MCQ Test With Answer

The solubility of PbF₂is 2.6 x 10^-3mole dm^-3 then its solubility product is

• 2.6 x 10^-3 A
• 6.76 x 10^-6 B
• 5.2 x 10^-6 C
• 7.0 x 10^-8 D

In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled then the equilibrium constant will

• Also be doubled A
• Be halved B
• Becomes one fourth C
• Remains the same D

Ifk_cof a reaction productis verylarge, it indicates that equilibrium occurs :

• With the help of a catalyst. A
• With no forward reaction. B
• At a low product concentration. C
• At a high product concentration. D

In exothermic reversible reaction increase in temperature shift the equilibrium to :

• Remains unchanged. A
• Product side. B
• Reactant side. C
• None of above. D

• Forward A
• Backward B
• Already in equilibrium C
• K_cis never less D

• High temperature and low pressure A
• Low temperature and high pressure B
• Low temperature and low pressure C
• High temperature and high pressure D

A gas bulb is filled with NO₂gas and immersed in an ice bath at 0°C which becomes colourless after sometimes. This colourless gas will be

• NO₂ A
• N₂O B
• N₂O₄ C
• N₂O₅ D

The rate of reaction :

• Remain same as reaction proceeds. A
• May decrease or increase as reaction proceeds . B
• Increase as reaction proceeds. C
• Decreases as reaction proceeds. D

• Pressure change A
• Temperature change B
• Concentration change C
• Catalyst D

A solution having pH = 4 its OH^-ion concentration in mole dm^-3is

• 1.0 x 10^-4 A
• 1.0 x 10^-10 B
• 1.0 x 10^-14 C
• 1 x 10⁰ D

Which statement about the following equilibrium in correct?

2SO_{2 (g)}+ O_2(g)---------------2sO_3(g)H= - 188.3 KJ mol-1

• T value of K_{p falls witha rise in temperate.} A
• The value of K_{p falls withincreasing pressure}
  B
• Adding V_2O5catalyst increase the equilibrium yield of sulfur trioxide
  C
• The value of K_{p is equal to}K_p D
• 
  
  E

The best buffer is prepared when molar concentrations of the salt and acid are equal, then its pH and pKa value are related

• pH = pKa A
• pH < pKa B
• pH > pKa C
• pH x pKa = 14 D

• 0.60 A
• 1.67 B
• 0.66 C
• 2.6 D

An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtration. What are the main ions in the filtrate

• 
  A
• 
  B
• 
  C
• 
  D

• Increase in concentration of 1 A
• Decrease in concentration of I₂ B
• Increase in temperature C
• Increase in total pressure D

• Equal volumes of N₂and H₂are reacting A
• Equal masses of N₂and H₂are reacting B
• The reaction has stopped C
• The same amount of ammonia is formed as is decomposed into N₂and H₂ D

• 0.12 A
• 0.50 B
• 0.25 C
• 4.00 D

The correct relation b/wK_{c and}K_{p is :}

• K_p = K_c[P/N] ^Δn

  A

• K_{c =} K_p(RT) ^Δn

  B

• K_{p =} K_c(RT) ^Δn

  C

• K_{p =} K_c(RT) ^Δn

  D

• Initial concentration of acetic acid A
• Initial concentration of ethyl acetate B
• Equilibrium concentration of acetic acid C
• Equilibrium concentration of ethyl acetate D

• Reversible reaction A
• Irreversible reaction B
• Spontaneous reaction C
• None of these D

When the rate of formation of reactants is equal to the rate of formation of products, this is known as

• Chemical reaction A
• Chemical equilibrium B
• Chemical kinetics C
• None D

• Favour the formation of N₂O₄ A
• Favour the decomposition of N₂O₄ B
• Not alter the equilibrium C
• Stop the reaction D

The avtive mass of 64 g of HI in a two litre flask would be

• 2 A
• 1 B
• 5 C
• 0.25 D

A solution has pH = 0, its H⁺ion concentration is

• 1 x 10^-14 A
• 1 x 10¹⁴ B
• 1 x 10¹ C
• 1 D

If pH of buffer of 1 mole dm^-3of HCOOH + 0.1 mole dm^-3HCOONa having pKa = 3.78 is

• 1.78 A
• 2.78 B
• 3.78 C
• 4.78 D

• Shift reaction toward forward direction A
• Shift reaction backward B
• Lower the value of K_c C
• No change in reaction D

The solubility product of AgCl is 2.0 x 10^-10mole ²dm^-6. The maximum concentration of Ag⁺ions in the solution is

• 2.0 x 10^-10mole dm^-3 A
• 1.41 x 10^-5mole dm^-3 B
• 1.0 x 10^-10 C
• 4.0 x 10^-20mole dm^-3 D

When a weak acid is dissolved in water or a weak base dissolved in water, then in both cases the conjugate acid base pair is produced. The ionization constants K_aand K_bof a pair are related with each other as

• K_a= K_b A
• K_a. K_b= K_w B
• K_a. K_w= K_b C
• K_b. K_w= K_a D

What happens when reaction is at equilibrium and more reactant is added :

• Forward reaction rate is increased. A
• Forward reaction rate is decreased. B
• Backward reaction rate is increased. C
• Equilibrium remains unchanged. D

The solubility product of AgCl is 2.0 x 10^-10mol²dm^-6The maximum concentration of Ag⁺ions in the solution is

• 2.0 x 10^-10mol dm^-3 A
• 1.41 x 10^-5mol dm^-3 B
• 1.0 x 10^-10mol dm^-3 C
• 4.0 x 10^-20mol dm^-3 D