ECAT Pre Engineering Chemistry Chapter 8 MCQ Test With Answer

The rate at which a substance reacts is directly proportional to its active mass and the rate of reaction is directly proportional to the product of the active masses of reacting substances, is called

• Law of conservation of energy A
• Le-Chateliers principle B
• Law of mass action C
• None of these D

• Le-chatlier's principle A
• Only adding catalyst B
• Decreasing pressure C
• Decreasing temperature D

• 
  A
• 
  B
• 
  C
• 
  D

• Reaction occurs at STP A
• Reaction is exothermic B
• Reaction is endothermic C
• Number of moles of production and reactant are same D

A chemical reaction is in equilibrium when

• Formation of product is minimum A
• Reactants are completely transformed into products B
• Rates of forward and backward reactions are equal C
• Equal amounts of reactants and products are present D

A buffer of a 0.09 molar acetic acid and 0.11 molar sodium acetate has pH = 4.83. If 0.01 mole NaOH in 1 dm³of the buffer solution is added, then pH of the buffer becomes

• 4.74 A
• 4.92 B
• 5.0 C
• 4.0 D

The solubility of PbF₂is 2.6 x 10^-3mole dm^-3 then its solubility product is

• 2.6 x 10^-3 A
• 6.76 x 10^-6 B
• 5.2 x 10^-6 C
• 7.0 x 10^-8 D

According to Le-Chatelier's principal, adding heat to a solid and liquid in equilibrium will cause the

• Amount of solid to decrease A
• Amount of liquid to decrease B
• Temperature to rise C
• Temperature to fall D

Product of concentration of ions raised to the power equal to the co-efficient of ions in balanced equation for saturated solution of a salt is called

• Ionic product A
• Equilibrium constant K_c B
• K_w C
• Solubility product (K_sp) D

• 450°C A
• 250°C B
• 850°C C
• 1000°C D

The best buffer is prepared when molar concentrations of the salt and acid are equal, then its pH and pKa value are related

• pH = pKa A
• pH < pKa B
• pH > pKa C
• pH x pKa = 14 D

In 1000 molecules of 0.001 M acetic acid the number of H⁺ions is 12.6, then its percentage of ionization is

• 1.33% A
• 1.26% B
• 12.6 C
• 1% D

• Moles^-2dm⁺⁶ A
• No units B
• Mole dm^-3 C
• Mole^-1dm^-3 D

Almost forward reaction is complete when value of k_{c :}

• Neither larger nor very small. A
• Very small. B
• Very large. C
• Negligible. D

The state of equilibrium refers to

• State of rest A
• Dynamic state B
• Stationary state C
• State of inertness D

The solubility product of Ca(OH)₂is 6.5 x 10^-6. The concentration of OH^-ions is

• 1.175 x 10^-2 A
• 2.35 x 10^-2 B
• 3.25 x 10^-3 C
• 3.25 x 10^-4 D

When the rate of formation of reactants is equal to the rate of formation of products, this is known as

• Chemical reaction A
• Chemical equilibrium B
• Chemical kinetics C
• None D

• At equilibrium there is no further change in the concentration of Hl A
• At equilibrium concentration of l₂remains constant B
• At equilibrium concentration of H₂remains unaltered C
• At equilibrium the rate of formation of Hl is equal to the rate of decomposition of Hl D

• 32 A
• 64 B
• 16 C
• 4 D

In which of the following cases, the reaction goes farthest to completion

• K = 10³ A
• K = 10^-2 B
• K = 10 C
• K = 10⁰ D

N₂3H₂⇌ 2NH₃

_{Which of the following change will favorthe formation of more}NH₃at equilibrium in above reaction :

• By adding NH_3. A
• By removingH_2. B
• By decreasing pressure. C
• By increasing pressure. D

A reaction is reversible because :

• Products are stable. A
• Reactants are reactive. B
• Products are reactive. C
• Reactants re stable. D

• HF is stable and does not decompose even at 2000°C A
• HF is stable and slowly decomposes at 2000°C B
• HF is strong acid C
• HF produces equal moles of hydrogen and fluorine D

A chemical reaction A---------->B is said to be in equilibrium when :

• Rate of transformation of A to B is equal to B to A. A
• 50% reactant has been changed to B. B
• Conversion of A to B is 50% complete C
• Complete conversion of A to B has taken place. D

The value of K_pis greater than K_cfor a gaseous reaction when

• Number of molecules of products is greater than the reactants A
• Number of molecules of reactants is greater than those of products B
• Number of molecules of reactants and products equal C
• Catalyst is added D

The rate of forward reaction is two times that of the reverse reaction at a given temperature and identical concentration, K equilibrium is

• 0.5 A
• 1.5 B
• 2.5 C
• 2.0 D

• KC = KP A
• Kp = KcRT B
• Kp = kc(RT)^-2 C
• Kp = Kc(RT)^-1 D

pH of the human blood which is essentially maintained constant due to carbonates, biocarbonates, phosphates etc., is

• 7.00 A
• 7.25 B
• 7.35 C
• 7.47 D

K_spvalue for PbSO₄= 1.8 x 10^-8mole²dm^-6. The maximum concentration of Pb⁺⁺ions is

• 1.34 x 10^-4mole dm^-3 A
• 1.8 x 10^-4 B
• 3.6 x 10^-16mole dm^-3 C
• 1.0 x 10^-8mole dm^-3 D

Which one of the following is a buffer

• HCI + NaCI solution A
• CH₃COOH + CH₃COONH₄solution B
• H₂SO₄+ CaSO₄solution C
• CH₃COOH + CH₃COONa D