ECAT Pre Engineering Chemistry Chapter 8 MCQ Test With Answer

Almost forward reaction is complete when value of k_{c :}

• Neither larger nor very small. A
• Very small. B
• Very large. C
• Negligible. D

N₂ +3H₂⇌ 2NH_{3 + Heat for above equation, themaximum product will be obtained at :}

• Low temperature at high pressure. A
• High temperature and low pressure. B
• High temperature and high pressure. C
• Low temperature at low pressure. D

Acetic acid is 1.33% ionized, In 1000 molecules of 0.1 M acetic acid the number of H⁺ions is

• 1.33 A
• 13.3 B
• 1.33 C
• 1 D

A chemical reaction is in equilibrium when

• Formation of product is minimum A
• Reactants are completely transformed into products B
• Rates of forward and backward reactions are equal C
• Equal amounts of reactants and products are present D

For which system does the equilibrium constant, kc has units of (concentration) ?

• N₂+3H_2-------2NH₃

  A

• H₂+L₂---------2HL

  B

• 2NO₂----------N₂O₄

  C

• 2HF--------H2+F₂

  D

An aqueous solution is neutral when its

• pH = 14 A
• pH = zero B
• pH = 7 C
• Kw = 10^-7 D

K_spvalue for PbSO₄= 1.8 x 10^-8mole²dm^-6. The maximum concentration of Pb⁺⁺ions is

• 1.34 x 10^-4mole dm^-3 A
• 1.8 x 10^-4 B
• 3.6 x 10^-16mole dm^-3 C
• 1.0 x 10^-8mole dm^-3 D

In which of the following cases, the reaction goes farthest to completion

• K = 10³ A
• K = 10^-2 B
• K = 10 C
• K = 10⁰ D

Which one of the following is a buffer

• HCI + NaCI solution A
• CH₃COOH + CH₃COONH₄solution B
• H₂SO₄+ CaSO₄solution C
• CH₃COOH + CH₃COONa D

The rate of reaction :

• Remain same as reaction proceeds. A
• May decrease or increase as reaction proceeds . B
• Increase as reaction proceeds. C
• Decreases as reaction proceeds. D

H₂ + L₂ ----2Hl

In the above equilibrium system, if the concentration of reactants at 25°C is increased, the value K_C will :

• Remains Constant A
• Increases B
• Cecreases C
• Depends upon nature of reactans D

• Equal volumes of N₂and H₂are reacting A
• Equal masses of N₂and H₂are reacting B
• The reaction has stopped C
• The same amount of ammonia is formed as is decomposed into N₂and H₂ D

• 0.073 A
• 0.147 B
• 0.05 C
• 0.026 D

Units of Kw are

• Mole dm^-3 A
• Mole²dm^-3 B
• Mole²dm^-6 C
• Mole²dm^-3 D

In a lime kiln, to get higher yield of CO₂, the measure that can be taken is

• To main high temperature A
• To pump out CO₂ B
• To remove Cao C
• To add more CaCO₃ D

• Temperature is increased A
• Pressure is increased B
• HCl is added C
• HCl is removed D

• Introduction of an inert gas at constant volume A
• Introduction of PCl₃(g) at constant B
• Introduction of PCl₅(g) at constant volume C
• Introduction of Cl₂at constant volume D

• 0.02 A
• 0.2 B
• 50 C
• 25 D

• Increase in concentration of 1 A
• Decrease in concentration of I₂ B
• Increase in temperature C
• Increase in total pressure D

Which of the following factors will favour the reverse reaction in a chemical equilibrium?

• Increase in concentration of one of the reactants A
• Increase in concentration of one of the products B
• Removal of one of the products regularly C
• None of these D

• 8 A
• 4 B
• 9 C
• 3 D

Extent to H₂ + L₂ à2Hl can be increased by :

• Increasing temperature.

  A

• Increasing product.

  B

• Increasing pressure.

  C

• Adding a catalyst.

  D

• The value of K_pfalls with rise in temperature A
• The value of K_pfalls with increasing pressure B
• Addition of V₂O₅catalyst increase the concentration of SO₃ C
• The value of K_pis equal to K_c D

An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtration. What are the main ions in the filtrate

• 
  A
• 
  B
• 
  C
• 
  D

The solubility product of AgCl is 2.0 x 10^-3 mol² dm^-6 , The maximum concentration of Ag ion in the solution is :

• 2.0 x 10^-10 mol dm^-3

  A

• 1.41 x 10^-10 mol dm^-3

  B

• 1.0 x 10^-10 mol dm^-3

  C

• 4.0 x 10^-10 mol dm^-3

  D

A buffer solution of 0.1 molar HCOOH and 0.1 molar HCCONa has pH = 3.78 To is 0.01 molar HCl is added, then pH of the buffer solution becomes

• 2.78 A
• 4.78 B
• 3.78 C
• 3.70 D

In exothermic reversible reaction increase in temperature shift the equilibrium to :

• Remains unchanged. A
• Product side. B
• Reactant side. C
• None of above. D

• 
  A
• 
  B
• 
  C
• 
  D

ph of the buffer CH₃COOh + CH₃COONa is 3.76. If the mixture contains 1 molar acetic acid and 0.1 molar sodium acetate, then pKa of this buffer is

• 3.76 A
• 4.76 B
• 5.76 C
• 6.76 D

If pH of buffer of 1 mole dm^-3of HCOOH + 0.1 mole dm^-3HCOONa having pKa = 3.78 is

• 1.78 A
• 2.78 B
• 3.78 C
• 4.78 D