ECAT Pre Engineering Chemistry Chapter 8 MCQ Test With Answer

pKb value of NH₄OH is 4.74. If the concentration of NH₄OH is 1 molar containing 0.1 molar NH₄Cl, then pH of this buffer will be

• 3.74 A
• 10.26 B
• 4.74 C
• 9.26 D

A solution having pH = 4 its OH^-ion concentration in mole dm^-3is

• 1.0 x 10^-4 A
• 1.0 x 10^-10 B
• 1.0 x 10^-14 C
• 1 x 10⁰ D

• Increases A
• Decreases B
• Remains same C
• Cannot be predicted D

Chemical equilibrium involving reactants and products in more than one phase is called

• Static A
• Dynamic B
• Homogeneous C
• Heterogeneous D

• Forward A
• Backward B
• Already in equilibrium C
• K_cis never less D

• Equal volumes of N₂and H₂are reacting A
• Equal masses of N₂and H₂are reacting B
• The reaction has stopped C
• The same amount of ammonia is formed as is decomposed into N₂and H₂ D

• 32 A
• 64 B
• 16 C
• 4 D

I a chemical reaction equilibrium is said to have been established when :

• Rate of opposing reactions are equal. A
• Rate constants of opposing reactions are equal. B
• Opposing reactions stop. C
• Concentration of reactants and products are equal D

• Reversible reaction A
• Irreversible reaction B
• Spontaneous reaction C
• None of these D

• Le-chatlier's principle A
• Only adding catalyst B
• Decreasing pressure C
• Decreasing temperature D

• Increase in concentration of 1 A
• Decrease in concentration of I₂ B
• Increase in temperature C
• Increase in total pressure D

Which statement about the following equilibrium in correct?

2SO_{2 (g)}+ O_2(g)---------------2sO_3(g)H= - 188.3 KJ mol-1

• T value of K_{p falls witha rise in temperate.} A
• The value of K_{p falls withincreasing pressure}
  B
• Adding V_2O5catalyst increase the equilibrium yield of sulfur trioxide
  C
• The value of K_{p is equal to}K_p D
• 
  
  E

The ionization constant of an acid is expressed in term of the following constant

• Kw A
• Kn B
• Ka C
• Kb D

• 4 mole per dm³ A
• 2 mole per dm³ B
• 0.33 mole per dm³ C
• 0.67 mole per dm³ D

0.1 MHCI has pH = 1.0, it is about 100 times stronger than acetic acid. Then pH of acetic acid will be

• 0.1 A
• 2.0 B
• 1.3 C
• 3.0 D

The rate of which the reaction proceeds is directly proportional to the product of the active masses of the reactants is according to

• Law of mass action A
• Le Chateliers principle B
• Equilibrium law C
• Law of constant proportion D

• 1 A
• 10 B
• 5 C
• 0.33 D

The rate of forward reaction is two times that of the reverse reaction at a given temperature and identical concentration, K equilibrium is

• 0.5 A
• 1.5 B
• 2.5 C
• 2.0 D

The state of equilibrium refers to

• State of rest A
• Dynamic state B
• Stationary state C
• State of inertness D

• 450°C A
• 250°C B
• 850°C C
• 1000°C D

In an exothermic reaction, a 10° rise in temperature will

• Decrease the value of equilibrium constant A
• Double the value of K_c B
• Not produce any change in K_c C
• Produce some increase in K_c D

For the above reaction the relationship b/w k_c and k_p will be :

• K_p = K_cRT

  A

• Kp = K_c(RT)_-1

  B

• K_p = K_c(RT)_-2

  C

• K_c = K_p

  D

1.1 mol of A is mixed with 2.2 mol of B and the mixture is kept in on litre flask till the equilibrium is reached. At equilibrium, 0.2 mol of C is formed. If the equilibrium reaction is A+2B 2C+D, the value of equilibrium constant is

• 0.002 A
• 0.004 B
• 0.001 C
• 0.003 D

The equilibrium constant in a reversible chemical reaction at a given temperature

• Depends on the initial concentration of the reactants A
• Depends on the concentration of one of the products at equilibrium B
• Does not depend on the initial concentration of rectants C
• It is characteristic of the reaction D

• Decrease in temperature favour more dissolution of the salt A
• Increase in temperature favour more dissolution of the salt B
• Lowering pressure favour more dissolution of the salt C
• Increasing pressure favour more dissolution of the salt D

A buffer solution of 0.1 molar HCOOH and 0.1 molar HCCONa has pH = 3.78 To is 0.01 molar HCl is added, then pH of the buffer solution becomes

• 2.78 A
• 4.78 B
• 3.78 C
• 3.70 D

• Favour the formation of N₂O₄ A
• Favour the decomposition of N₂O₄ B
• Not alter the equilibrium C
• Stop the reaction D

• Introduction of an inert gas at constant volume A
• Introduction of PCl₃(g) at constant B
• Introduction of PCl₅(g) at constant volume C
• Introduction of Cl₂at constant volume D

2SO₂ + O₂ ⇌ 2SO₂ H= 188KJ mole^-1

Which statement about following equilibrium is correct :

• The value ofK_pfalls with arise in temperature. A
• The value ofK_pis equal tok_c. B
• The value ofK_pfalls with the increase pressure. C
• Adding V₂O₅ catalyst increase the equilibrium yield of Sulphur trioxide.
  D

• High temperature and low pressure A
• Low temperature and high pressure B
• Low temperature and low pressure C
• High temperature and high pressure D