ECAT Pre Engineering Chemistry Chapter 8 MCQ Test With Answer

A buffer solution of 0.1 molar HCOOH and 0.1 molar HCCONa has pH = 3.78 To is 0.01 molar HCl is added, then pH of the buffer solution becomes

• 2.78 A
• 4.78 B
• 3.78 C
• 3.70 D

Which of the following solution have zero pH

• 1 M HCI A
• MH₂SO₄ B
• 0.1 M HNO₃ C
• 1 M CH₃COOH D

Addition of solid NaHCO₃in water causes ionization of NaCHO₃its K_a= 4.7 x 10^-1. Then this solution has character

• Acidic A
• Very weakly basic B
• Alkaline C
• Neutral D

• Shift reaction toward forward direction A
• Shift reaction backward B
• Lower the value of K_c C
• No change in reaction D

Extent to H₂ + L₂ à2Hl can be increased by :

• Increasing temperature.

  A

• Increasing product.

  B

• Increasing pressure.

  C

• Adding a catalyst.

  D

• Moles^-2dm⁺⁶ A
• No units B
• Mole dm^-3 C
• Mole^-1dm^-3 D

An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtration. What are the main ion in filtrate?

• Ag⁺ and NO_3- only

  A

• Ag⁺ and Ba² and NO^-3

  B

• Ba² and NO^-3

  C

• Ba² and NO^-3 and Cl-

  D

• [A] = [B] A
• [A] < [B] B
• [B] = [C] C
• [A] > [B] D

• KC = KP A
• Kp = KcRT B
• Kp = kc(RT)^-2 C
• Kp = Kc(RT)^-1 D

1 mole of N₂and 2 moles of H₂are allowed to react in a 1 dm³vessel. At equilibrium 0.8 mole of NH₃is formed. The concentration of H₂in the vessel is

• 0.6 mole A
• 0.8 mole B
• 0.2 mole C
• 0.4 mole D

The solubility product of AgCl is 2.0 x 10^-10mole ²dm^-6. The maximum concentration of Ag⁺ions in the solution is

• 2.0 x 10^-10mole dm^-3 A
• 1.41 x 10^-5mole dm^-3 B
• 1.0 x 10^-10 C
• 4.0 x 10^-20mole dm^-3 D

Reactions that proceed on both sides and never go to completion are called

• Irreversible reactions A
• Reversible reactions B
• Opposing reactions C
• Spontaneous reactions D

The solubility of KCIO₃salt in water is decreased by adding

• NaCIO₃ A
• NaCI B
• KCIO₄ C
• KCI D

The relation between Kc and Kp is

• 
  A
• 
  B
• 
  C
• 
  D

A reaction is reversible because :

• Products are stable. A
• Reactants are reactive. B
• Products are reactive. C
• Reactants re stable. D

Acetic acid is 1.33% ionized, In 1000 molecules of 0.1 M acetic acid the number of H⁺ions is

• 1.33 A
• 13.3 B
• 1.33 C
• 1 D

In which of the following cases, the reaction goes farthest to completion

• K = 10³ A
• K = 10^-2 B
• K = 10 C
• K = 10⁰ D

Units of Kw are

• Mole dm^-3 A
• Mole²dm^-3 B
• Mole²dm^-6 C
• Mole²dm^-3 D

• At equilibrium there is no further change in the concentration of Hl A
• At equilibrium concentration of l₂remains constant B
• At equilibrium concentration of H₂remains unaltered C
• At equilibrium the rate of formation of Hl is equal to the rate of decomposition of Hl D

If the difference of pKa values of the two acids is 2, then

• Acid with smaller pKa is 10 times stronger acid A
• Acid with greater pKa is 10 times stronger acid B
• Acid with smaller pKa is 100 times stronger acid C
• Acid with greater pKa is 100 times stronger acid D

Under what condition of temperature and pressure the formation of atomic hydrogen from molecular hydrogen will be favourd

• High temperature and high pressure A
• Low temperature and low pressure B
• High temperature and low pressure C
• :Low temperature and high pressure D

The solubility product of AgCl is 2.0 x 10^-10mol²dm^-6The maximum concentration of Ag⁺ions in the solution is

• 2.0 x 10^-10mol dm^-3 A
• 1.41 x 10^-5mol dm^-3 B
• 1.0 x 10^-10mol dm^-3 C
• 4.0 x 10^-20mol dm^-3 D

The solubility product of AgCl is 2.0 x 10^-3 mol² dm^-6 , The maximum concentration of Ag ion in the solution is :

• 2.0 x 10^-10 mol dm^-3

  A

• 1.41 x 10^-10 mol dm^-3

  B

• 1.0 x 10^-10 mol dm^-3

  C

• 4.0 x 10^-10 mol dm^-3

  D

• Shift reaction toward forward direction A
• Shift reaction backward B
• Lower the value of K_c C
• No change in reaction D

Which of the following in an example of reversible reaction

• 
  A
• 
  B
• 
  C
• 
  D

• Reaction occurs at STP A
• Reaction is exothermic B
• Reaction is endothermic C
• Number of moles of production and reactant are same D

The avtive mass of 64 g of HI in a two litre flask would be

• 2 A
• 1 B
• 5 C
• 0.25 D

pH and pKa of the buffer are related by Henderson equation which is

• 
  A
• 
  B
• 
  C
• 
  D

The optimum conditions of temperature and pressure to get maximum NH₃form N₂and H₂gases is

• 2000°C and 10 atmosphere A
• 0°C and 1 atmosphere B
• 400°C and 200-300 atmosphere C
• 200°C and 100 atmosphere D

2SO₂+ O₂⇌2SO₂H= 188KJ mole^-1

Which statement about following equilibrium is correct :

• The value ofK_pfalls with arise in temperature.

  A

• The value ofK_pis equal tok_c.

  B

• The value ofK_pfalls with the increase pressure.

  C

• Adding V₂O₅catalyst increase the equilibrium yield of Sulphur trioxide.

  D