| 1 |
In OF2, number of bond pairs and Ione paris of electrons are respectively
|
A. 2,6
B. 2,8
C. 2,10
D. 2,9
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| 2 |
The three N - Hσ-bonds are made by
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A. sp3- s overlap
B. sp2- s overlap
C. P - p overlap
D. sp - overlap
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| 3 |
The shape of gaseous SnCl2is
|
A. Tetrahedral
B. Linear
C. Angular
D. T-shaped
|
| 4 |
Water H2O is liquid while hydrogen sulphide H2S is a gas beause
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A. Water has higher molecular weight
B. Hydrogen sulphide is a weak acid
C. Sulphure has high electronegativity than oxyhe
D. Water molecules associate through hydrogen bonding
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| 5 |
When of the following is isolelectronic with krypton
|
A. Ca++
B. Al+++
C. Br-1
D. I-1
|
| 6 |
Number of sigma bonds in P4O10is
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A. 6
B. 7
C. 17
D. 16
|
| 7 |
Which of the following molecules has unpaired electrons in anti-bonding molecular orbitals?
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A. O2
B. N2
C. Br2
D. F2
|
| 8 |
Which of the following has zero depole-moment?
|
A. CIF
B. PCl3
C. SiF4
D. CFCl4
|
| 9 |
The geometry of 4 sp3hybrid orbitals on an atom is
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A. Square planar
B. Tetrahedral
C. Trigonal planar
D. Linear
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| 10 |
Elements have the tendency to attain 8 electrons in their valence shell. This is known as
|
A. Octer rule
B. Hunds rule
C. Pauli exclusion principle
D. Auf ban principle
|
| 11 |
Which of the following statements is not correct regarding bonding molecular orbitals?
|
A. Bonding molecular orbitals possess less energy than atomic orbitals from which they are formed
B. Bonding molecular orbitals have low electron density between the two nuclei
C. Every electron in the bonding molecular orbitals contributes to the attraction between atoms
D. Bonding molecular orbitals are formed when the electron waves undergo constructive interference
|
| 12 |
From the difference between expected bond energies for the normal covalent bond and experimentally determined values Pauling calculated the values of
|
A. Ionization potential of elements
B. Electron affinity of elements
C. Electronegativity of elements
D. Bond length
|
| 13 |
The bond angle depends upon the
|
A. Types of bonds
B. Number of bonds
C. Non-bonding electron pairs
D. All of the above
|
| 14 |
Antibonding MO is formed by
|
A. Addition of atomic orbitals
B. Substraction of atomic orbitals
C. Multiplication of atomic orbitals
D. None of these
|
| 15 |
Size of an anion is increased as compared to its atom because of the
|
A. Addition of new shell
B. Repulsion of electrons in the valence shell
C. Decrease in nuclear charge
D. Increase in the unclear charge
|
| 16 |
Which of the following is a polar molecules
|
A. Carbon dioxide
B. Carbon tetrachloride
C. Methanol
D. Ethane
|
| 17 |
The number of electron pairs shared in carbon tetrachloride molecule is
|
A. 2
B. 3
C. 4
D. 1
|
| 18 |
The atomic radius of hydrogen is 37
|
A. Pecometer
B. Manometer
C. Angstrom
D. Micrometer
|
| 19 |
Shielding effect intervening electrons causes
|
A. Decreases in atomic radii in a period from right to left
B. Increase in atomic radii in a period from left to righ t
C. Decrease in atomic radii down the group
D. Increase in atomic radii down the group
|
| 20 |
Coordinate covalent bond is present in the molecules
|
A. H2O
B. BF3
C. SiO2
D. SO2
|
| 21 |
|
A. Excitantion of an electron from 2s to 2p-orbital
B. Transfer of three electrons from B to the other atoms
C. Excitation of two electrons form 2s orbital to 2p orbital
D. Formation of molecular ion
|
| 22 |
The structure of ICI2is
|
A. Trigonal
B. Trigonal bipyramidal
C. Octahedral
D. Square planar
|
| 23 |
Covalent compounds are soluble in
|
A. Polar solvents
B. Non-polar solvents
C. Concentrated acids
D. All solvents
|
| 24 |
In a group the atomic size increase downward due to
|
A. Addition of electronic shells
B. Increase in the proton number
C. Repulsion of electrons
D. All of the above
|
| 25 |
Among the alkaline earth metals the element forming predominantly covalent compounds is
|
A. Be
B. Mg
C. Sr
D. calcium
|
| 26 |
Which of the following geometry is associated with the compound in which the central atom assumes sp3d hybridization?
|
A. Planar
B. Pyramidal
C. Angular
D. Trigonal bipyramidal
|
| 27 |
Which of the following molecules have its central atom sp2hybridized
|
A. CH4
B. C2H2
C. C2H4
D. CCl4
|
| 28 |
Which of the following has highest bond order
|
A.
B.
C.
D.
|
| 29 |
Atoms obey octet rule by sharing-electrons making covalent bonds according to
|
A. Lewis and Kossal theory
B. Valance bond theory
C. VSEPR theory
D. Molecular orbital theory
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| 30 |
Which of the following molecules have sp3hybridized carbon
|
A. CH4
B. C2H4
C. C2H2
D. CO2
|