| 1 |
The shape of CIO-3according to valence shell electron pair repulsion theory will be
|
A. Planar triangle
B. Pyramidal
C. Tetrahedral
D. Square planar
|
| 2 |
The number of antibonding electron pairs in O2-molecular ion on the basis of MOT is
|
A. 4
B. 3
C. 2
D. 5
|
| 3 |
Electronegativity values of the elements F, CI and Br vary
|
A. F > CI > Br
B. Br > CI > F
C. Cl > Br > F
D. CI > F > Br
|
| 4 |
N-atom forms three covalent bonds, its electronic configuration is
|
A.
B.
C.
D.
|
| 5 |
The bond order O2molecule is
|
A. 1
B. 2
C. 3
D. Zero
|
| 6 |
Nitrogen in NH3is sp3hybridized but the bond angle in NH3is 107° and not 109.5° due to
|
A. sp3orbital planar
B. sp3orbital trigonal
C. Repulsion between lone pair and bonded pairs
D. None of them
|
| 7 |
Which of the following molecules has a net dipole moments
|
A. CO2
B. CS2
C. SO2
D. CCI4
|
| 8 |
Noble gases have the electronic configuration with their valance shell ns2np6except one
|
A. He
B. Ne
C. Kr
D. Xe
|
| 9 |
The bond order of individual C - C bond is benzene is
|
A. One
B. Two
C. Between one and two
D. One and two alternately
|
| 10 |
Inter molecular forces in solid hydrogen are
|
A. Covalent forces
B. Van der Waal forces or London dispersion forces
C. Hydrogen bonds
D. All of these
|
| 11 |
The three N - Hσ-bonds are made by
|
A. sp3- s overlap
B. sp2- s overlap
C. P - p overlap
D. sp - overlap
|
| 12 |
Which of the following statements is not correct regarding bonding molecular orbitals?
|
A. Bonding molecular orbitals possess less energy than atomic orbitals from which they are formed
B. Bonding molecular orbitals have low electron density between the two nuclei
C. Every electron in the bonding molecular orbitals contributes to the attraction between atoms
D. Bonding molecular orbitals are formed when the electron waves undergo constructive interference
|
| 13 |
The shape of gaseous SnCl2is
|
A. Tetrahedral
B. Linear
C. Angular
D. T-shaped
|
| 14 |
Antibonding MO is formed by
|
A. Addition of atomic orbitals
B. Substraction of atomic orbitals
C. Multiplication of atomic orbitals
D. None of these
|
| 15 |
|
A. Excitantion of an electron from 2s to 2p-orbital
B. Transfer of three electrons from B to the other atoms
C. Excitation of two electrons form 2s orbital to 2p orbital
D. Formation of molecular ion
|
| 16 |
The bond order for He2molecule is
|
A. zero
B. 1/2
C. 1
D. 2
|
| 17 |
Which of the following has polar bond
|
A. O2
B. N2
C. HCl
D. Cl2
|
| 18 |
Which is made by coordinate covalent bond
|
A. H3O+
B. H2O
C. CH4
D. HCl
|
| 19 |
The shape of the molecule SF2Cl2is
|
A. Trigonal bipyradmidal
B. Cubic
C. Octahedral
D. Tetrahedral
|
| 20 |
One of the following bonds is polar but compound is non-polar
|
A. H2O
B. NH3
C. HCl
D. CO2
|
| 21 |
During the formation of a chemical bond the potential energy of the system
|
A. Decreases
B. Increases
C. Does not change
D. None of these
|
| 22 |
The tendency of an atom to attract shared electron pair towards itself is called
|
A. Covelent bond
B. Electronegativity
C. Ionization potential
D. Electronic affinity
|
| 23 |
Which of the following molecules has unpaired electrons in anti-bonding molecular orbitals?
|
A. O2
B. N2
C. Br2
D. F2
|
| 24 |
A bond between two atoms may be obtained by sharing of electrons such a bond is called
|
A. An ionic bond
B. A coordinate bond
C. A dative bond
D. A covalent bond
|
| 25 |
|
A. The ionization energy of A is high and electron affinity of B is low
B. The ionization energy of A is low and electron affinity of B is high
C. Both the ionization energy of A and electron off affinity of B are high
D. Both the ionization energy of A and electron affinity of B are low
|
| 26 |
The electronegativity of elements in a period from left to right
|
A. Decreases
B. Increases
C. First decreases then increases
D. First increases then decreases
|
| 27 |
Which of the following species has unpaired electrons in antibonding molecular orbitals
|
A.
B.
C.
D.
|
| 28 |
When two hydrogen atoms approach to form a chemical bond
|
A. The repulsive forces dominate the attractive forces
B. The attractive forces, dominate the repulsive forces
C. The energy of atoms increases
D. The two atoms start ionization
|
| 29 |
When of the following is isolelectronic with krypton
|
A. Ca++
B. Al+++
C. Br-1
D. I-1
|
| 30 |
An ionic compound M2S3is formed by the metal M,, the metal is
|
A. Ca
B. Ba
C. K
D. Al
|