| 1 |
Nitrogen in NH3is sp3hybridized but the bond angle in NH3is 107° and not 109.5° due to
|
A. sp3orbital planar
B. sp3orbital trigonal
C. Repulsion between lone pair and bonded pairs
D. None of them
|
| 2 |
Shape of CIO3is
|
A. Triangular pyramidal
B. Tetrahedral
C. Triangular planar
D. Triangular bipyramidal
|
| 3 |
Which of the following statements is not correct regarding bonding molecular orbitals?
|
A. Bonding molecular orbitals possess less energy than atomic orbitals from which they are formed
B. Bonding molecular orbitals have low electron density between the two nuclei
C. Every electron in the bonding molecular orbitals contributes to the attraction between atoms
D. Bonding molecular orbitals are formed when the electron waves undergo constructive interference
|
| 4 |
Three sp2hybrid are co-planar at an angle of
|
A. 104.5°
B. 109.5°
C. 107°
D. 120°
|
| 5 |
Which of the following has highest bond order
|
A.
B.
C.
D.
|
| 6 |
Antibonding MO is formed by
|
A. Addition of atomic orbitals
B. Substraction of atomic orbitals
C. Multiplication of atomic orbitals
D. None of these
|
| 7 |
Planar geometry of molecules is due to
|
A. sp3hybridization
B. sp2hybridization
C. sp hybridization
D. P - p overlap
|
| 8 |
Which of the following species has unpaired electrons in antibonding molecular orbitals
|
A.
B.
C.
D.
|
| 9 |
Atomic number of Al is 13. When it forms ionic bond with oxygen the number of electrons lost by 1 Al atom is
|
A. 1
B. 2
C. 3
D. 4
|
| 10 |
Which of the following molecules have multiple bonds
|
A. CH4
B. C2H4
C. C2H6
D. CCI4
|
| 11 |
The Electro-negatively difference for ionic bond must be greater than
|
A. 1.6
B. 1.7
C. 1.8
D. 1.0
|
| 12 |
The nature of interparticle forces in benzene is
|
A. Dipole-dipole interaction
B. Dispersion force
C. Ion-dipole interaction
D. H-bonding
|
| 13 |
|
A. Excitantion of an electron from 2s to 2p-orbital
B. Transfer of three electrons from B to the other atoms
C. Excitation of two electrons form 2s orbital to 2p orbital
D. Formation of molecular ion
|
| 14 |
Hydrogen chloride molecule contains
|
A. Covalent bond
B. Double bond
C. Co-ordinate bond
D. Electrovalent bond
|
| 15 |
The geometry of 4 sp3hybrid orbitals on an atom is
|
A. Square planar
B. Tetrahedral
C. Trigonal planar
D. Linear
|
| 16 |
Which of the following has unchanged valency?
|
A. H
B. Na
C. Fe
D. Oxygen
|
| 17 |
Which carbon is more electronegative?
|
A. sp3- hybridized carbon
B. sp-hybridized carbon
C. sp2-hybridized carbon
D. always same irrespective of its hybrid state
|
| 18 |
Water H2O is liquid while hydrogen sulphide H2S is a gas beause
|
A. Water has higher molecular weight
B. Hydrogen sulphide is a weak acid
C. Sulphure has high electronegativity than oxyhe
D. Water molecules associate through hydrogen bonding
|
| 19 |
The bond angles in methane CH4are equal to
|
A. 109.5°
B. 107.5°
C. 104.5°
D. 120°
|
| 20 |
The bond order of individual C - C bond is benzene is
|
A. One
B. Two
C. Between one and two
D. One and two alternately
|
| 21 |
Which of the following hydrides has the lowest boiling point?
|
A. H2O
B. H2S
C. H2S3
D. H2Te
|
| 22 |
The electron affinity of chlorine may be represented by the equation
|
A.
B.
C.
D.
|
| 23 |
In OF2, number of bond pairs and Ione paris of electrons are respectively
|
A. 2,6
B. 2,8
C. 2,10
D. 2,9
|
| 24 |
One of the following bonds is polar but compound is non-polar
|
A. H2O
B. NH3
C. HCl
D. CO2
|
| 25 |
Generally ionization energy of atoms decreases by
|
A. Decreases in atomic size
B. Increase in atomic size
C. Increase in nuclear charge
D. None of these
|
| 26 |
Covalent compounds are soluble in
|
A. Polar solvents
B. Non-polar solvents
C. Concentrated acids
D. All solvents
|
| 27 |
The bond angle depends upon the
|
A. Types of bonds
B. Number of bonds
C. Non-bonding electron pairs
D. All of the above
|
| 28 |
During the formation of a chemical bond the potential energy of the system
|
A. Decreases
B. Increases
C. Does not change
D. None of these
|
| 29 |
According to VSEPR theory, the shape of the water molecule is
|
A. Octahedral
B. Distorted tetrahedral
C. Planar triangle
D. Linear
|
| 30 |
Tripple bond is present in
|
A. O2
B. H2
C. N2
D. Cl2
|