ECAT Pre Engineering Chemistry Chapter 5 MCQ Test With Answer

Electrons arranged in orbitals according to the increasing order of their n + l values, this rule is named as

• Hund's rule A
• Heisenberg's principle B
• Paulit exclusion principle C
• Auf bau principle D

Schrodinger wave equation describes electron completely because

• It describes a set of four quantum number A
• It describes the particle nature of electron B
• It measures wavelength of electron C
• It describes electron moving in specific orbit D

Maximum potential energy that an electron can have within the atom is:

• Equal to zero. A
• Less than zero. B
• Greater than zero. C
• Infinite D

Sodium chloride imparts a yellow colour to the Bunsen flame. This can be interpreted due to the

• low ionization energy of sodium A
• sublimation of metallic sodium to give yellow vapour B
• emission of excess energy absorbed as a radiation in the visible region as a radiation in the visible region C
• photosenitivity D

Electrons in degenerate orbitals are placed in separate orbitals with same spin according to

• Hund's rule A
• Pauli exclusion principle B
• Aufbau principle C
• Mosley's law D

Azimuthal quantum number of last electron of ₁₁Na is

• 1 A
• 2 B
• 3 C
• 0 D

Which of the following is not a property of cathode rays

• They can produce x-rays when they strike a heavy metal anode A
• They can cause reduction reaction B
• They produce fluorescence in rare earth and minerals C
• They comprise neutral particles D

The electronic configuration of an atom/ion can be defined by the following

• Aufbau principle A
• Pauli's exclusion principle B
• Hund's Rule C
• All the above D

The nature of positive ray depend on:

• The nature of electrode. A
• The nature of discharge tube. B
• The nature of residual gas. C
• All of above. D

The atomic number of an element is 35 what is the total number of electrons present in all the p-orbitals of the ground state atom of that element?

• 6 A
• 11 B
• 17 C
• 23 D

Which of the following particles has longest wavelength, if they have same speed:

• Proton. A
• Neutron. B
• Electron. C
• Positron. D

Which have better penetrating power

• Alpha rays A
• Beta rays B
• Gamma rays C
• X-rays D

The total number of orbitals possible for the quantum number n is

• n A
• n² B
• 2n C
• 2n² D

In Bohr model of hydrogen atom the distance between adjacent orbits increases away from the nucleus, the energy difference between the orbits

• Increases A
• Decreases B
• Reaming same C
• Orbits coincide D

No cathode rays are produced in the discharged tube when gas is under ordinary pressure even if voltage of 5000 to 10000 is applies. This reason is

• Voltage is low A
• Discharge tube is not coloured B
• Gas does not conduct current under ordinary pressure C
• Temperature low D

The valence orbital configuration of an element with atomic number 23 is

• 3d⁵ A
• 3d³, 4s² B
• 3d³, 4s¹, 4p¹ C
• 3d²,4s²,4p¹ D

Which of the atoms has 1s², 2s², 2p_x²2p¹_y2p¹_zconfiguration

• Nitrogen A
• Carbon B
• Fluorine C
• Oxygen D

The wave number of light emitted by a certain source is 2 x 10⁵m. The wavelength of this light will be:

• 500 NM. A
• 500 M. B
• 200 NM. C
• 5 x 10⁷m D

An electron has principal quantum number 3. The number of its 1 subshell and 2 orbitals would be respectively

• 3 and 5 A
• 3 and 7 B
• 3 and 9 C
• 2 and 5 D

Quantum number values for 2p orbitals are

• n = 2, l = 1 A
• n = 1, l = 2 B
• n = 1, l = 0 C
• n = 2, l = 0 D

Rutherford's atomic model suggests the existence of

• Atom A
• Nucleus B
• alpha particle C
• Measons D

Smallest charge of electricity that has been measured so far is

• Charge on a-rays A
• Charge on electron (1.602 x 10^-19C) B
• Charge on x-rays C
• Charge on gamma rays D

If the value of azimuthal quantum number is 3, then values of m the magnetic quantum no. will be

• 0, 1, 2, 3 A
• +3, +2, +1, -1, -2, -3 B
• 0, -1, -2 ,-3 C
• -3, 0, +3 D

Consider the ground state of Cr atom (Z=24). The numbers of electrons with the azimuthal quantum numbers l = 1 and l = 2 are respectively

• 12 and 4 A
• 16 and 5 B
• 16 and 4 C
• 12 and 5 D

The number of electrons in the M shell of the element with atomic number 24 is

• 24 A
• 12 B
• 13 C
• 8 D

The order of distance between the various Bohr orbits is

• r₂- r₁> r₃- r₂> r₄- r₃> ...... A
• r₁> r₂> r₂- r₃> r₄-r₃> ..... B
• r₂-r₁= r₃- r₂= r₄- r₃> ..... C
• r₂- r₁> r₃- r₂< r₄- r₃< .... D

In which of the following pairs, the numbers of electrons in the outermost shell are different?

• As,Sb A
• Ge,Sn B
• In,pt C
• Se,Te D

• s A
• p B
• d C
• f D

When the 6d orbital is completed the entering electron goes into

• 7f A
• 7 s B
• 7 p C
• 7 d D

When electrons revolve in stationary orbits

• There is no change in energy level A
• They vecome stationary B
• They are gaining kinetic energy C
• There is increase in energy D