ECAT Pre Engineering Chemistry Chapter 5 MCQ Test With Answer

The quantum number which describes the shape of the orbital is

• Principle quantum number A
• Spin quantum number B
• Azimathal quantum number C
• Magnetic quantum number D

Energy of electron in the infinite Bohr orbit of H-atom is

• 0 KJ/mole A
• 1 KJ/mole B
• -1 KJ/mole C
• -1313.32 KJ/mole D

The value of Plank's constant 'h' is

• 6.625 x 10^-34 A
• 6.625 x 10^-34J sec B
• 6.625 x 10^-34KJ C
• 6.625 x 10^-34K Cal D

Which of the following element's outermost orbits last electron has magnetic quantum number m=0?

• Na A
• O B
• Cl C
• N D

Splitting of spectral lines of the hydrogen atom under the influence or magnetic field is called

• Stark effect A
• Zeeman effect B
• Compton effect C
• Photoelectric effect D

Balmer's series is in ______ region

• Visible A
• U V B
• I. R. C
• None D

When the electron jumps form third, fourth, fifth orbits to the second orbit, the transitions are known as

• Paschen A
• Pfund B
• Balmer C
• Brackett D

What is the packet of energy called?

• Electron A
• Photon B
• Positron C
• Proton D

When 3p orbital is complete, the entering electron goes into

• 4s A
• 3d B
• 4p C
• 4f D

Quantum number values for 2p orbitals are

• n = 2, l = 1 A
• n = 1, l = 2 B
• n = 1, l = 0 C
• n = 2, l = 0 D

Energy of electron in an orbit according to Bohr theory is negative due to

• Repulsion of electrons in the same orb A
• At infinity energy is zero ad a traction towards nucleus decreases energy B
• Electron has negative charge C
• Product of positive nuclear charge and negative charge is negative D

With the reference of w/m ratio of anode rays, the e/m ratio of cathode rays s:

• Greater. A
• same. B
• Smaller. C
• Not fixed. D

Negatively charged particle nature of cathode rays was first demonstrated in 1895 by:

• Millikan. A
• J. Perrin. B
• Hittrof C
• J.J. Thomson. D

When cathode rays strike the anode metal X-rays are emitted and not the positive rays because

• Cathode rays are material particles A
• Cathode rays knock out electrons from anode, which emit X-rays when outer electron take their place B
• Cathode rays are absorbed by the nucleus C
• Cathode rays become heated D

If the radius of first Bohr orbit be a_o, then the radius of third Bohr orbit would be

• 3 x a_o A
• 6 x a_o B
• 9 x a_o C
• 1/2 x a_o D

• s A
• p B
• d C
• f D

The de-Brogile wavelength of a particle with mass 1g and velocity 100 m/s is

• 6.63 x 10^-33m A
• 6.63 x 10^-34m B
• 6.63 x 10^-35m C
• 6.65 x 10^-35m D

The ratio of the ionization energy of H and Be³⁺is

• 1 : 1 A
• 1 : 3 B
• 1 : 9 C
• 1 : 16 D

e/m of cathode rays is same but for positive rays e/m changes by changing gas in the discharge tube because

• Cathode rays are small sized particles A
• Cathode rays have same charge B
• Nature of cathode rays same for all gasses, but masses of nuclei are different for different gases C
• Temperature of cathode rays higher D

Which of the following was discovered first:

• Charge to mass ratio of electrons. A
• Mass of electrons. B
• Charge of electrons. C
• All of above at same time. D

Rutherford's model of atom failed because:

• The atom did o have a nucleus and electrons A
• It did not account fro the attraction b/w protons and neutrons B
• It did no account for the stability of the atom. C
• There is actually no space b/w the nucleus ad the electrons. D

Number of neutrons in heavy hydrogen atom is

• 0 A
• 1 B
• 2 C
• 3 D

Cathode rays drive a small paddle wheel placed in their path. This observation shows that

• Cathode rays travel in straight lines A
• Cathode rays are negatively charged B
• Cathode rays produce x-rays C
• Cathode rays are material particles having momentum D

The quantum number which determines the shape of the orbital is

• principal A
• azimuthal B
• magnetic C
• spin D

Find the magnetic moment of a divalent ion in aqueous solution if its atomic number is 25

• 3.0 BM A
• 4.9 BM B
• 5.9 BM C
• 6.9 BM D

Four d-orbitals contain four lobes while fifth contains only two lobes the orbital is

• dxy A
• dxz B
• dz² C
• dx²- y² D

The wave length of electron as wave is 0.5 nm. What is the wave length in meter

• 5 x 10^-9 A
• 5 x 10^-12 B
• 5 x 10^-6 C
• 5 x 10^-10 D

No cathode rays are produced in the discharged tube when gas is under ordinary pressure even if voltage of 5000 to 10000 is applies. This reason is

• Voltage is low A
• Discharge tube is not coloured B
• Gas does not conduct current under ordinary pressure C
• Temperature low D

Mass of simple electron is:

• 9.1 x 10^-31 kg

  A

• 9.1 x 10^-30 kg

  B

• 1.66 x 10^-31 kg

  C

• 9.1 x 10^-31 kg

  D

In the ground state of an atom the electron is present

• In the nucleus A
• In the second shell B
• Nearest to the nucleus C
• Farthest from the nucleus D