ECAT Pre Engineering Chemistry Chapter 5 MCQ Test With Answer

Light emitted from a source has its wave length 500nm, then its wave number will be

• 2 x 10⁶m^-1 A
• 2 x 10⁷m^-1 B
• 5 x 10⁸ m^-1 C
• 5 x 10⁹m^-1 D

Which of the following particles has longest wavelength, if they have same speed:

• Proton. A
• Neutron. B
• Electron. C
• Positron. D

Balmer's series is in ______ region

• Visible A
• U V B
• I. R. C
• None D

The wave number of the light emitted by a certain source is 2 x 10⁶m^-1. The wavelength of this light will be

• 500 nm A
• 500 m B
• 200 nm C
• 5 x 10⁷m D

The number of de-electrons retained in Fe²⁺ (At.No. of Fe = 26) ions is

• 3 A
• 4 B
• 5 C
• 6 D

The configuration 1s²2s²2p⁵3s¹shows

• Excited state of O₂ A
• Excited state of neon B
• Excited state of fluorine C
• Ground state of fluorine atom D

Rutherford's experiment led to the discovery of

• Nucleus A
• Electron B
• Proton C
• alpha particle D

Which one of the following statements is true about discovery of neutrons?

• These particles were formed by the bombardment of Alpha-particles on Beryllium. A
• These particles are formed by the spiting of alpha-particles. B
• These particles were discovered by natural radioactivity. C
• None of above. D

In Bohr model of hydrogen atom the distance between adjacent orbits increases away from the nucleus, the energy difference between the orbits

• Increases A
• Decreases B
• Reaming same C
• Orbits coincide D

The ratio of the ionization energy of H and Be³⁺is

• 1 : 1 A
• 1 : 3 B
• 1 : 9 C
• 1 : 16 D

In the ground state of an atom, the electron is present:

• In the nucleus. A
• In the second shell. B
• Nearest to the nucleus. C
• farthest from the nucleus. D

When 3p orbital is complete, the entering electron goes into

• 4s A
• 3d B
• 4p C
• 4f D

An electron has principal quantum number 3. The number of its 1 subshell and 2 orbitals would be respectively

• 3 and 5 A
• 3 and 7 B
• 3 and 9 C
• 2 and 5 D

The de-Brogile wavelength of a particle with mass 1g and velocity 100 m/s is

• 6.63 x 10^-33m A
• 6.63 x 10^-34m B
• 6.63 x 10^-35m C
• 6.65 x 10^-35m D

Negatively charged particle nature of cathode rays was first demonstrated in 1895 by:

• Millikan. A
• J. Perrin. B
• Hittrof C
• J.J. Thomson. D

The mass of the neutron is of the order of

• 10^-23 kg A
• 10^-24kg B
• 10^-26kg C
• 10^-27kg D

Bohr model of atom is contradicted by:

• Planck's quantum theory A
• Pauli's exclusion theory B
• Heisenberg's uncertainty principle. C
• All of above. D

The third line of the Balmer series, in the emission spectrum of the hydrogen atom,is due to the transition from the

• Fourth Bohr orbit to the first Bohr orbit A
• Fifth Bohr orbit to the second Bohr orbit B
• Sixth Bohr orbit to the third Bohr orbit C
• Seventh Bohr orbit to the third Bohr orbit D

The wave length of electron as wave is 0.5 nm. What is the wave length in meter

• 5 x 10^-9 A
• 5 x 10^-12 B
• 5 x 10^-6 C
• 5 x 10^-10 D

Energy of electron in an orbit according to Bohr theory is negative due to

• Repulsion of electrons in the same orb A
• At infinity energy is zero ad a traction towards nucleus decreases energy B
• Electron has negative charge C
• Product of positive nuclear charge and negative charge is negative D

Number of neutrons in heavy hydrogen atom is

• 0 A
• 1 B
• 2 C
• 3 D

The e.m value for positive rays maximum for:

• Oxygen. A
• Nitrogen. B
• Helium. C
• Hydrogen. D

Rutherford's atomic model suggests the existence of

• Atom A
• Nucleus B
• alpha particle C
• Measons D

The valence orbital configuration of an element with atomic number 23 is

• 3d⁵ A
• 3d³, 4s² B
• 3d³, 4s¹, 4p¹ C
• 3d²,4s²,4p¹ D

n + l value for 4f will

• 2 A
• 5 B
• 7 C
• 9 D

Sodium chloride imparts a yellow colour to the Bunsen flame. This can be interpreted due to the

• low ionization energy of sodium A
• sublimation of metallic sodium to give yellow vapour B
• emission of excess energy absorbed as a radiation in the visible region as a radiation in the visible region C
• photosenitivity D

Smallest charge of electricity that has been measured so far is

• Charge on a-rays A
• Charge on electron (1.602 x 10^-19C) B
• Charge on x-rays C
• Charge on gamma rays D

The number of electrons in the M shell of the element with atomic number 24 is

• 24 A
• 12 B
• 13 C
• 8 D

• Plank's equations A
• de Broglie's equations B
• Heisenburg's equation C
• None D

Quantum number value for 2p orbitals are:

• n=2 ,l=1 A
• n=1 ,l=2 B
• n= ,l=0 C
• n=2 ,l=0 D