ECAT Pre Engineering Chemistry Chapter 23 MCQ Test With Answer

MCQ's Test For ECAT Chemistry Chapter 23 Aldehydes and Ketones

Try The MCQ's Test For ECAT Chemistry Chapter 23 Aldehydes and Ketones

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ECAT Chemistry Chapter 23 Aldehydes and Ketones

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Question # 1

Which compound on reaction with hydrogen cyanide produces a compound with a chiral centre

Question # 2

Which reaction is of condensation or addition elimination reaction?

Question # 3

A compound R has all of the following properties. It is neutral; It gives an orange precipitate with 2,4-dinitrophenythydrazine; it evolves hydrogen chloride when treated with PCI5in the cold What could R be

Question # 4

Reaction of Grignard's reagent with formaldehyde gives:

Question # 5

Which of the following reagent will react with both aldehyde and ketones?

Question # 6

Which compound would undergo nucleophilic addition

Question # 7

Acetone reacts with HCN to form a cyanohydrin. It is an example of

Question # 8

Cannizzaro's reaction in not given by

Question # 9

An organic compound has the following properties ; It gives a positive tri-iodomethane test; it gives a yellow ppt, with 2, 4-DNP regent; it does not react with Tollen's reagent . Which compound would give these results

Question # 10

Silver mirror test is applied for

Question # 11

The homologous series of aldehydes and ketones have general formula:

Question # 12

What is formed when propanone is refluxed with an anhydrous solution of NaBH4

Question # 13

Aldehydes give reactions :

Question # 14

In formadaldehyde and KOH are heated then we get

Question # 15

Which of the following react with NaOH to produce an acid and an alcohol?

Question # 16

Reduction with aluminium isopropoxide in excess of Isopropyl alcohol is called Meerwein Ponndroff-Verley reduction (MPV). What will be the final product when cyclohex-2-enone is selectively reduces in MPV reaction?

Question # 17

Which of the following gives iodoform on heating with a solution of I2containing Na2CO3?

Question # 18

Ethanal may be converted into a three-carbon acid in a two-step process.
Which compound is the intermediate

Question # 19

Distillation of calcium salts of acetic acid and formic acids gives acetaldehyde. What compound would be obtained if only calcium salt of acetic acid is distilled

Question # 20

When vapours of isopropyl alcohol are passed over heated copper, the major product obtained is

Question # 21

Wolf-kishner reduction is used for the reduction of

Question # 22

The color of ppts formed by Fehling's test is

Question # 23

Which is mild oxidizing agent ?

Question # 24

A compound possessingα-hydrogen atom, in the presence of dilute alkali formsβ-hydroxy aldehyde. This product on heating with dilute acid forms an unsaturated crotonaldehyde. The compound is

Question # 25

C2H5CHO and (CH3)2CO can be distunguished by testing with

Question # 26

Which of the following compounds gives a ketone with Grignard's reagent?

Question # 27

Which of the following does not turn Schiff's reagent to pink?

Question # 28

Chromic acid used to oxidize

Question # 29

The colour of ppts formed by Fehling's test is

Question # 30

Which of the following will have the highest boiling point?

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ECAT Chemistry Chapter 23 Important MCQ's

Sr.# Question Answer
1 Aldehydes which do not haveα-hydrogen undergo
A. Aldol combination
B. Cannizzaro's reaction
C. Substitution
D. Elimination
2 Reduction with aluminium isopropoxide in excess of Isopropyl alcohol is called Meerwein Ponndroff-Verley reduction (MPV). What will be the final product when cyclohex-2-enone is selectively reduces in MPV reaction?
A. Cyclohexanol
B. Cyclohex-2-enol
C. Cyclohexanone
D. Benzene
3 Which of the following reagent will react with both aldehyde and ketones?
A. Grinard's reagent
B. Tollen's reagent
C. Fehling's reagent
D. Benedict's reagent
4 Which of the following gives iodoform on heating with a solution of I2containing Na2CO3?
A. Ethyl alcohol
B. Acetone
C. Ethyl alcohol as well as acetone
D. Methyl alcohol
5 A compound A has a molecular formula C2Cl3OH. It reduces Fehling solution and on oxidation produces a monocarboxylic acid B.A can also be obtained by the action of Cl2on Ethanol. A is
A. Chloral hydrate
B. CHCl3
C. CH3Cl
D. Chloroacetic acid
6 Self condensation of acetaldehyde in the presence of dilute alkalies gives
A. An acetal
B. An aldol
C. Mesitylene
D. Propionaldehyde
7 Which of the following is hypnotic?
A. Acetaldehyde
B. Metaldehyde
C. Paraldehyde
D. None
8 Give IUPAC name fo Acetone
A. Ethanal
B. Propanone
C. Butanone
D. Propanal
9 A nucleophilic reagent will readily Attack
A. Ethylene
B. Ethanal
C. Ethanol
D. Ethylamine
10 An organic compound has the following properties ; It gives a positive tri-iodomethane test; it gives a yellow ppt, with 2, 4-DNP regent; it does not react with Tollen's reagent . Which compound would give these results
A. CH3CHO
B. CH3CH2OH
C. CH3CH2COCH3
D. CH3CH2CH2CHO

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