ECAT Pre Engineering Chemistry Chapter 11 MCQ Test With Answer

• 1st order A
• 2nd order B
• Zero order C
• 3rd order D

The reaction rate is expressed in the units of

• mol dm^-3S^- A
• mol dm^-3 B
• mol dm^-3N^- C
• dm^-3S^- D

For a chemical reaction to take place the particles must have sufficient energy for the effective collisions, the energy is called

• Average energy A
• Activation energy B
• Potential energy C
• Collision energy D

• 
  A
• 
  B
• 
  C
• 
  D

The catalytic activity of Pt is much higher when

• It is mixed with asbestos A
• It is mixed with Pd B
• It is mixed with arsenic C
• In is made colloidal platinum D

If the rate of decay of radioactive isotope decreases from 200 cpm to 25 cpm after 24 hours, what is its half life :

• 8 hours A
• 6 hours B
• 4 hours C
• 3 hours D

In the hydrolysis of CH₃COOC₂H₅the acid produced is

• Inhibitor A
• Catalyst B
• Auto catalyst C
• None of above D

A pseudo uni-molecular reaction has order of reaction :

• 3 A
• 2 B
• 1 C
• 0 D

It rate law of an equation is written asdx/dt=K[A][B] ?

• Reaction is independent of the concentration of A and B. A
• Product is decreasing with passage of time. B
• Reactant in increasing with passage of time. C
• Reactant is increasing with passage of time. D

• Zero A
• 1 B
• 2 C
• 1.5 D

The rate equation for a reaction is Rate =k[A]. what are unit of K ?

• Mole-1 dm³ S^-1

  A

• Mole dm³ S^-1

  B

• Mole dm³

  C

• S^-1

  D

Group l-A elements react with water fastly than the reaction of group ll-A elements because

• l_Aelements are more soft then ll_A A
• l_Aelements are non-metals B
• l_Aelements have 1 electron in their outermost s-orbital and are strongly electropositive C
• l_Aelements make ionic bond D

The rate of reaction b/w two specific time intervals is called :

• Instantaneous rate of reaction. A
• Average rate of reaction. B
• Rate of a reaction. C
• Minimum rate of a reaction. D

All reactions occur in :

• A single step. A
• A series of steps B
• Two steps. C
• Both (a) and (b) D

The number of atoms or molecules whose concentrations determine the rate of the reaction is called

• Molecularity A
• Order B
• Rate of reaction C
• Rate constant D

A white precipitate ofsilver chlorideimmediately formed on additionof :

• Silver nitrate solution to sodium chloride solution. A
• Silver chloride solution to sodium nitrate solution. B
• Silver nitrate solution to potassium chloride solution C
• Silver nitrate solution to hydrogen chloride solution. D

Half life period of a first order reaction is independent of:

• Presence of catalyst. A
• Conditions of temperature B
• Initial concentration of the compound C
• All of above D

• Measuring pH A
• Measuring density B
• Titration against standard NaOH C
• Titration against standard KMnO₄solution D

Dilatometer method is useful for the reaction that involve :

• Small volume changes in solutions A
• Change in infractive indices B
• Where reactants absorb U.V, visible or infrared radiation C

It is common observation that rates of chemical reactions differ :

• Greatly. A
• A little bit. B
• Moderately. C

By the use of catalysis the energy of activation is

• Decreased A
• Increased B
• Not affected C
• None D

The unit rate of constan K ismole^-1 dm³S^-1for a chemical reaction, the order of reaction is :

• 3 A
• 2 B
• 1 C
• 0 D

Hydrogenation of vegetable oils is accelerated by Ni catalyst. The catalytic activity of Bi is increased by a promoter of activator which is

• Na and K A
• Na and Hg B
• Hg and Zn C
• Cu and Te D

Which statement is not correct

• Enzymes catalyst a specific reaction A
• Enzymes show catalytic activity at a specific temperature B
• The catalytic activity of enzymes is stopped if optimum pH is changed C
• The catalytic activity is poisoned by a co-enzymes D

The experimental relationship between a reaction rate and the concentration of reactants is called

• Order or reaction A
• Rate law B
• Activated complex C
• Molecularity D

Which one of the following reaction rate is effected by the light

• 
  A
• 
  B
• 
  C
• 
  D

When copper is allowed to react with HNO₃, the reaction is slow in the beginning, finally becomes very fast. It is due to the formation of an auto catalyst which is

• Cu(NO₃)₂ A
• CuO B
• O₂ C
• HNO₂ D

In thermal decomposition of N₂O the half life period for two different initial concentrations of N₂O are

(i) 255 second for initial N₂O 290 mm Hg

(ii) 212 second for initial N₂O 360 mm Hg then it is

• Zero order A
• First order B
• Second order C
• Third order D

The rate of reaction is denoted by

• dc/dp A
• dc/ac B
• dc/dT C
• dc/dt D

When the rate of reaction is entirely independent of the conc. of reaction molecules then order of reaction is

• Zero A
• First B
• Second C
• Third D