ECAT Pre Engineering Chemistry Chapter 11 MCQ Test With Answer

MCQ's Test For ECAT Chemistry Chapter 11 Reaction Kinetics

Try The MCQ's Test For ECAT Chemistry Chapter 11 Reaction Kinetics

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ECAT Chemistry Chapter 11 Reaction Kinetics

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Question # 1

The rate constant k of a reaction activation energy Ea and temperature are related by Arrhenius in the form of an equation which is

Question # 2

The reaction rate is expressed in the units of

Question # 3

For effective collisions the molecules slow down before collision and their kinetic energy decreases which results in increase in their

Question # 4

In an experiment the concentration of a reactant 'A' is doubled the rate increases four times. If concentration in tripled, then rate increases nint times. Thus the rate is proportional to ______ of concentration of 'A'

Question # 5

The reaction rate is expressed in the units of

Question # 6

A pseudo uni-molecular reaction has order of reaction :

Question # 7

Group l-A elements react with water fastly than the reaction of group ll-A elements because

Question # 8

The rate of reaction between two specific time intervals is called

Question # 9

Hydrolysis of ethyl-acetate (ester) has order of reaction :

Question # 10

The catalytic activity of Pt is much higher when

Question # 11

In the manufacture of NH3by Haber's process catalyst used is iron its catalytic efficiency is poisoned by

Question # 12

Which of the following will affect the rate :

Question # 13

The rate of reaction :

Question # 14

The rate of reaction is denoted by

Question # 15

A catalyst is a substance which increase the rate of a chemical reaction, but remains unchanged at the end of reaction, nut remains unchanged at the end of reaction, because

Question # 16

The unit rate of constan K ismole-1 dm3S-1for a chemical reaction, the order of reaction is :

Question # 17

Which of the following may affect the rate constant (k) fro a reaction :

Question # 18

It rate law of an equation is written asdx/dt=K[A][B] ?

Question # 19

Half life period of a first order reaction is independent of:

Question # 20

A white precipitate ofsilver chlorideimmediately formed on additionof :

Question # 21

If half life period of a reaction is independent of the concentration of the reactants, then the reaction is

Question # 22

In the rate equation when the concentration of reactants are unity, then rate is equal to

Question # 23

If the rate equation of a reaction 2A+B-------->Products is , Rate = K[A] [B], and A is present in large excess, then order of reaction is :

Question # 24

If initial concentration of the reactants and half life period of the reaction is known, then we can determine

Question # 25

In the reaction of oxalic acid with KMnO4and H2SO4is slow at the beginning but after sometimes the reaction becomes faster due to

Question # 26

For a chemical reaction to take place the particles must have sufficient energy for the effective collisions, the energy is called

Question # 27

Which of the following is not affected by light

Question # 28

Which technique is used to determine the absorption of radiations?

Question # 29

The experimental relationship between a reaction rate and the concentration of reactants is called

Question # 30

If the rate of decay of radioactive isotope decreases from 200 cpm to 25 cpm after 24 hours, what is its half life :

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Sr.# Question Answer
1 The rate of reaction :
A. Decreases as the reaction proceeds
B. Increases as the reaction proceeds
C. May decrease or increase reaction proceeds
D. Remains same as the reaction proceeds
2 Half life period of a first order reaction is independent of:
A. Presence of catalyst.
B. Conditions of temperature
C. Initial concentration of the compound
D. All of above
3 Activation energy is the difference of energy between the energy of the reactant and
A. The product
B. The activated complex
C. Both a and b
D. None of these
4 Which of the following will affect the rate :
A. First step of reaction.
B. Last step of reaction.
C. Rate determining step.
D. Fastest step.
5

A pseudo uni-molecular reaction has order of reaction :

A. 3
B. 2
C. 1
D. 0
6
Question Image
A. Initial concentration of reaction
B. Initial concentration of products
C. Final concentration of products
D. Order of the reaction
7 In the rate equation when the concentration of reactants are unity, then rate is equal to
A. Instantaneous rate
B. Average rate
C. Active mass of products
D. Specific rate constant
8 Dilatometer method is useful for the reaction that involve :
A. Small volume changes in solutions
B. Change in infractive indices
C. Where reactants absorb U.V, visible or infrared radiation
9 The number of atoms or molecules whose concentrations determine the rate of the reaction is called
A. Molecularity
B. Order
C. Rate of reaction
D. Rate constant
10 The rate of reaction b/w two specific time intervals is called :
A. Instantaneous rate of reaction.
B. Average rate of reaction.
C. Rate of a reaction.
D. Minimum rate of a reaction.
11 Platinum is poisoned by
A. Arsenic
B. Silver
C. Argon
D. Zinc
12 With the progressive of the reaction the slope of the curve between concentration of product and time
A. Gradually becomes more steep
B. Gradually becomes less steep
C. No change occurs in slope
D. None of these occurs
13 Which statement is not correct
A. Enzymes catalyst a specific reaction
B. Enzymes show catalytic activity at a specific temperature
C. The catalytic activity of enzymes is stopped if optimum pH is changed
D. The catalytic activity is poisoned by a co-enzymes
14 To determine the rate of reaction chemically a graphical method is applied. A graph is plotted between the amount or reactant decomposed or product formed against the time. The rate dx/dtat any time is equal to
A. k
B. Tangentθ
C. 1/a, a is initial conc.
D. 1/a2
15 The unit of the rate constant is the same as that of rate of reaction in :
A. Third order reaction
B. Second order reaction
C. First order reaction
D. Zero order reaction
16 Factor which slows down the rate of reaction is
A. Small size of the particles of the reactant
B. High temperature of reaction
C. More concentration of reactant
D. Lowering the temperature
17 The sum of the exponents of the conc. terms in the rate equation is called
A. Rate of reaction
B. Order of reaction
C. Specific rate constant
D. Average rate
18 which one of the following is a heteroheneous catalysis
A. Choice 1
B. Choice 2
C. Choice 3
D. Choice 4
19 In the manufacture of NH3by Haber's process catalyst used is iron its catalytic efficiency is poisoned by
A. Presence of Al2O3
B. Presence of Cr2O3
C. MnO2
D. CO present with H2gas
20 When the rate of reaction is entirely independent of the conc. of reaction molecules then order of reaction is
A. Zero
B. First
C. Second
D. Third
21 A zero order reaction is one in which :
A. Rate is not affected by changing concentration of reactants.
B. concentration of reactants do not change with the passage of time.
C. Reactants do not react.
D. One reactants in large excess.
22 In zero order reaction, the rate is independent of :
A. Temperature of reaction
B. Concentration ofreactants
C. Concentration of products
D. None of these.
23 The unit of rate of reaction is
A. mole dm-3
B. mole Kg-1
C. moles dm-3sec-1
D. grams dm-3
24
Question Image
A. Rate = k[FeCl3] [Kl]2
B. Rate = k[Fe+3][Cl-1] [Kl]
C. Rate = k[Fe+3] [Cl-1][K;]
D. Rate = k[Kl]3[FeCl3
25 A catalyst is a substance which increase the rate of a chemical reaction, but remains unchanged at the end of reaction, nut remains unchanged at the end of reaction, because
A. It increases the temperature
B. It increase the surface area
C. It increases the rate constant
D. It decrease the energy energy of activation
26 The unit rate of constan K ismole-1 dm3S-1for a chemical reaction, the order of reaction is :
A. 3
B. 2
C. 1
D. 0
27 Which of the following may affect the rate constant (k) fro a reaction :
A. Change in concentration.
B. Change in pressure.
C. Change in pH.
D. Change in temperature.
28 The reaction rate is expressed in the units of
A. mol dm-3S-
B. mol dm-3
C. mol dm-3N-
D. dm-3S-
29 Which one of the following reaction rate is effected by the light
A. Choice 1
B. Choice 2
C. Choice 3
D. Choice 4
30 When copper is allowed to react with HNO3, the reaction is slow in the beginning, finally becomes very fast. It is due to the formation of an auto catalyst which is
A. Cu(NO3)2
B. CuO
C. O2
D. HNO2

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