ECAT Pre Engineering Chemistry Chapter 11 MCQ Test With Answer

Value of rate constant k is specific for a reaction, and varies from reaction to reaction. The value of k of a reaction changes with

• Time A
• Temperature B
• Concentration of reactants C
• Order of reaction D

If the rate of reaction is independent of the concentration of the reactant, the reaction is of

• Zero order A
• First order B
• Second order C
• Third order D

The rate of reaction determined at a given time is called

• Average rate A
• Instantaneous rate B
• Specific rate C
• Overall rate D

The factor which effect the rate of reaction

• Nature of reactants A
• Surface area B
• Light C
• All of the above D

• 2 A
• 3 B
• 4 C
• 9 D

If a reactant or product of a reaction absorbs radiation, then physical method for determining the rate of reaction is

• Spectrometry A
• Refractometry B
• Conductivity measurement C
• Optical method D

The change in concentration of reactant or product per unit time is called :

• Rate constant. A
• Rate of reaction. B
• Rate equation. C
• Rate law. D

A white precipitate ofsilver chlorideimmediately formed on additionof :

• Silver nitrate solution to sodium chloride solution. A
• Silver chloride solution to sodium nitrate solution. B
• Silver nitrate solution to potassium chloride solution C
• Silver nitrate solution to hydrogen chloride solution. D

Which statement is not correct

• Enzymes catalyst a specific reaction A
• Enzymes show catalytic activity at a specific temperature B
• The catalytic activity of enzymes is stopped if optimum pH is changed C
• The catalytic activity is poisoned by a co-enzymes D

The value of activation energy Ea of a reaction can be determined from the value of slope of the straight line obtained by plotting a graph between 1/T and log k. the value of Ea is equal to

• Slope A
• 1/Slope B
• Slope x R C
• Slope x 2.303 R D

For a chemical reaction to take place the particles must have sufficient energy for the effective collisions, the energy is called

• Average energy A
• Activation energy B
• Potential energy C
• Collision energy D

The unit of rate constant k is the same as that of the rate of reaction in

• First order reaction A
• Second order reaction B
• Third order reaction C
• Zero order reaction D

Which of the following reactions occur at moderate rate :

• Rusting of iron A
• Chemical weathering of stone work of buildings by acidic gases in atmosphere. B
• Hydrolysis of an ester C
• Fermentation of sugars D

Optical rotation method is sued when

• Reaction involve ions A
• Change of refractive indices B
• Reactions involving change of optical activity C
• None of the above D

In the hydrolysis of CH₃COOC₂H₅the acid produced is

• Inhibitor A
• Catalyst B
• Auto catalyst C
• None of above D

With the progressive of the reaction the slope of the curve between concentration of product and time

• Gradually becomes more steep A
• Gradually becomes less steep B
• No change occurs in slope C
• None of these occurs D

• First order A
• Pseudo first order B
• Second order C
• Zero order D

In thermal decomposition of N₂O the half life period for two different initial concentrations of N₂O are

(i) 255 second for initial N₂O 290 mm Hg

(ii) 212 second for initial N₂O 360 mm Hg then it is

• Zero order A
• First order B
• Second order C
• Third order D

Which statement is true about order of reaction :

• Order of reaction can only be determined by an experiment. A
• Order of reaction can be determined from a balance equation only. B
• Order of reaction increase by increasing temperature. C
• Order of reaction must be in whole number and not in fraction. D

The rate of reaction between two specific time intervals is called

• Instantaneous rate A
• Average rate B
• Specific rate C
• Ordinary rate D

• 
  A
• 
  B
• 
  C
• 
  D

Half life period of a reaction is inversely proportion to the initial concentration of the reactant, then order of reaction is

• Third order A
• Second order B
• Fist order C
• Zero order D

The unit of rate of reaction is

• mole dm^-3 A
• mole Kg^-1 B
• moles dm^-3sec^-1 C
• grams dm^-3 D

The rate of reaction determined at a given time is called

• Average rate A
• Instantaneous rate B
• Specific rate C
• Overall rate D

Decreases om concentration of reactant is denoted by

• dc/dt A
• -dc/dt B
• +dc/dt C
• None D

Rate law of an equation is obtained :

• From a balance equation. A
• Can be calculated theoretically as well as determined experimentally. B
• It is only calculated theoretically. C
• Experimentally. D

In an experiment the concentration of a reactant 'A' is doubled the rate increases four times. If concentration in tripled, then rate increases nint times. Thus the rate is proportional to ______ of concentration of 'A'

• Square root A
• Square B
• Twice C
• Cube D

The example of a photo chemical reaction is photosynthesis has order of reaction :

• 1 A
• 2 B
• 0 C
• 3 D

Which of the following may affect the rate constant (k) fro a reaction :

• Change in concentration. A
• Change in pressure. B
• Change in pH. C
• Change in temperature. D

The effective activity of a metal catalyst is increased if it is in

• Solid form A
• Liquid state B
• Gaseous state C
• Finely divided form D