ECAT Pre Engineering Chemistry Chapter 11 MCQ Test With Answer for Chemistry chapter 11 (Reaction Kinetics)

The experimental relationship between a reaction rate and the concentration of reactants is known as

• Order A
• Molecularity B
• Rate constant C
• Rate law D

Dilatometer method is useful for the reaction that involve :

• Small volume changes in solutions A
• Change in infractive indices B
• Where reactants absorb U.V, visible or infrared radiation C

The rate of reaction determined at a given time is called

• Average rate A
• Instantaneous rate B
• Specific rate C
• Overall rate D

• 
  A
• 
  B
• 
  C
• 
  D

The catalytic activity of Pt is much higher when

• It is mixed with asbestos A
• It is mixed with Pd B
• It is mixed with arsenic C
• In is made colloidal platinum D

The reaction rate is expressed in the units of

• Mol dm^-3S^- A
• Mol dm^-3 B
• Mol dm^-3N^- C
• dm^-3S^- D

Which of the following reactions occur at moderate rate :

• Rusting of iron A
• Chemical weathering of stone work of buildings by acidic gases in atmosphere. B
• Hydrolysis of an ester C
• Fermentation of sugars D

The unit of the rate constant is the same as that of rate of reaction in :

• Third order reaction A
• Second order reaction B
• First order reaction C
• Zero order reaction D

• Zero A
• 1 B
• 2 C
• 1.5 D

A white precipitate ofsilver chlorideimmediately formed on additionof :

• Silver nitrate solution to sodium chloride solution. A
• Silver chloride solution to sodium nitrate solution. B
• Silver nitrate solution to potassium chloride solution C
• Silver nitrate solution to hydrogen chloride solution. D

Value of rate constant k is specific for a reaction, and varies from reaction to reaction. The value of k of a reaction changes with

• Time A
• Temperature B
• Concentration of reactants C
• Order of reaction D

The reaction rate is expressed in the units of

• mol dm^-3S^- A
• mol dm^-3 B
• mol dm^-3N^- C
• dm^-3S^- D

It rate law of an equation is written asdx/dt=K[A][B] ?

• Reaction is independent of the concentration of A and B. A
• Product is decreasing with passage of time. B
• Reactant in increasing with passage of time. C
• Reactant is increasing with passage of time. D

A catalyst is a substance which increase the rate of a chemical reaction, but remains unchanged at the end of reaction, nut remains unchanged at the end of reaction, because

• It increases the temperature A
• It increase the surface area B
• It increases the rate constant C
• It decrease the energy energy of activation D

The number of atoms or molecules whose concentrations determine the rate of the reaction is called

• Molecularity A
• Order B
• Rate of reaction C
• Rate constant D

By the use of catalysis the energy of activation is

• Decreased A
• Increased B
• Not affected C
• None D

Factor which slows down the rate of reaction is

• Small size of the particles of the reactant A
• High temperature of reaction B
• More concentration of reactant C
• Lowering the temperature D

• 2 A
• 3 B
• 4 C
• 9 D

The rate constant k of a reaction activation energy Ea and temperature are related by Arrhenius in the form of an equation which is

• 
  A
• 
  B
• 
  C
• 
  D

The example of a photo chemical reaction is photosynthesis has order of reaction :

• 1 A
• 2 B
• 0 C
• 3 D

For effective collisions the molecules slow down before collision and their kinetic energy decreases which results in increase in their

• Activation energy A
• Average energy B
• Potential energy C
• Collisions frequency D

Hydrolysis of ethyl-acetate (ester) has order of reaction :

• 3 A
• 2 B
• 1 C
• 1 D

Which statement is true about order of reaction :

• Order of reaction can only be determined by an experiment. A
• Order of reaction can be determined from a balance equation only. B
• Order of reaction increase by increasing temperature. C
• Order of reaction must be in whole number and not in fraction. D

Rate law of an equation is obtained :

• From a balance equation. A
• Can be calculated theoretically as well as determined experimentally. B
• It is only calculated theoretically. C
• Experimentally. D

The rate of reaction between two specific time intervals is called

• Instantaneous rate A
• Average rate B
• Specific rate C
• Ordinary rate D

Which of the following may affect the rate constant (k) fro a reaction :

• Change in concentration. A
• Change in pressure. B
• Change in pH. C
• Change in temperature. D

Which of the following is not affected by light

• 
  A
• 
  B
• 
  C
• 
  D

In the expression rate = K [A]^a[B]^bK is

• The order of reaction A
• The speed of reaction B
• The specific rate constant C
• The overall order of reaction D

Hydrogenation of vegetable oils is accelerated by Ni catalyst. The catalytic activity of Bi is increased by a promoter of activator which is

• Na and K A
• Na and Hg B
• Hg and Zn C
• Cu and Te D

The unit of rate constant K ismole^-1 dm³for a chemical reaction, the order of reaction is :

• Order of reaction can determined by an experiment A
• Order of reaction can determined from a balance equation only. B
• Order of reaction can determined increases by increasing temperate. C
• Order of reaction must be in whole number and not in fraction. D