ECAT Pre Engineering Chemistry Chapter 11 MCQ Test With Answer

In thermal decomposition of N₂O the half life period for two different initial concentrations of N₂O are

(i) 255 second for initial N₂O 290 mm Hg

(ii) 212 second for initial N₂O 360 mm Hg then it is

• Zero order A
• First order B
• Second order C
• Third order D

In the hydrolysis of CH₃COOC₂H₅the acid produced is

• Inhibitor A
• Catalyst B
• Auto catalyst C
• None of above D

Which of the following is not affected by light

• 
  A
• 
  B
• 
  C
• 
  D

The rate of reaction determined at a given time is called

• Average rate A
• Instantaneous rate B
• Specific rate C
• Overall rate D

The rate constant k of a reaction activation energy Ea and temperature are related by Arrhenius in the form of an equation which is

• 
  A
• 
  B
• 
  C
• 
  D

In the hydrolysis of CH₃COOC₂H₅the acid produced is

• Inhibitor A
• Catalyst B
• Auto catalyst C
• None of above D

A white precipitate ofsilver chlorideimmediately formed on additionof :

• Silver nitrate solution to sodium chloride solution. A
• Silver chloride solution to sodium nitrate solution. B
• Silver nitrate solution to potassium chloride solution C
• Silver nitrate solution to hydrogen chloride solution. D

• Zero A
• 253 sec B
• 150 sec C
• 500 sec D

Half life period of a first order reaction is independent of:

• Presence of catalyst. A
• Conditions of temperature B
• Initial concentration of the compound C
• All of above D

which one of the following is a heteroheneous catalysis

• 
  A
• 
  B
• 
  C
• 
  D

• Measuring pH A
• Measuring density B
• Titration against standard NaOH C
• Titration against standard KMnO₄solution D

• Diastase A
• Lipase B
• Inverters C
• Zymase D

• Homogeneous A
• Heterogeneous B
• Isogeneous C
• None D

The unit of rate of reaction is

• mole dm^-3 A
• mole Kg^-1 B
• moles dm^-3sec^-1 C
• grams dm^-3 D

With increases of 10°C temperature the rate of reactiondoubles. This increase in rate of reactionis due to :

• Decrease in activation energy or reaction. A
• Decrease in number of collisions between reactant molecules. B
• Increase in activation energy of reactants. C
• Increase in number of effective collisions D

In exothermic reaction decrease in potential energy of the products will result in

• Decreases in kinetic energy of the particles A
• Increases in kinetic energy of the particles B
• No change in kinetic energy C
• Decreases in activation energy D

The rate of reaction determined at a given time is called

• Average rate A
• Instantaneous rate B
• Specific rate C
• Overall rate D

It rate law of an equation is written asdx/dt=K[A][B] ?

• Reaction is independent of the concentration of A and B. A
• Product is decreasing with passage of time. B
• Reactant in increasing with passage of time. C
• Reactant is increasing with passage of time. D

Rate of chemical reaction depends upon :

• The number of total collisions per second. A
• Number of molecules taking part in a chemical reaction. B
• Number of fruitful collisions per second C
• Number of fruitless collisions per second. D

If initial concentration of the reactants and half life period of the reaction is known, then we can determine

• Average rate of reaction A
• Order of reaction B
• Rate constant k C
• Instantaneous rate D

The catalytic activity of Pt is much higher when

• It is mixed with asbestos A
• It is mixed with Pd B
• It is mixed with arsenic C
• In is made colloidal platinum D

Which of the following factors does not influenced the rate of reaction

• Concentration of the reaction A
• Nature of the reactants B
• Molecularity of the reaction C
• Temperature D

It is common observation that rates of chemical reactions differ :

• Greatly. A
• A little bit. B
• Moderately. C

A catalyst is a substance which increase the rate of a chemical reaction, but remains unchanged at the end of reaction, nut remains unchanged at the end of reaction, because

• It increases the temperature A
• It increase the surface area B
• It increases the rate constant C
• It decrease the energy energy of activation D

The unit of rate constant K ismole^-1 dm³for a chemical reaction, the order of reaction is :

• Order of reaction can determined by an experiment A
• Order of reaction can determined from a balance equation only. B
• Order of reaction can determined increases by increasing temperate. C
• Order of reaction must be in whole number and not in fraction. D

______ are called biocatalysts

• Organic acids A
• Organic bases B
• Enzymes C
• All D

Optical rotation method is sued when

• Reaction involve ions A
• Change of refractive indices B
• Reactions involving change of optical activity C
• None of the above D

A pseudo uni-molecular reaction has order of reaction :

• 3 A
• 2 B
• 1 C
• 0 D

• Rate = k[FeCl₃] [Kl]² A
• Rate = k[Fe⁺³][Cl^-1] [Kl] B
• Rate = k[Fe⁺³] [Cl^-1][K;] C
• Rate = k[Kl]³[FeCl₃]° D

The experimental relationship between a reaction rate and the concentration of reactants is called

• Order or reaction A
• Rate law B
• Activated complex C
• Molecularity D