1 |
Pick out incorrect statement about K2Cr2O7 |
It oxidizes acidified solution H2SO4 to S
It oxidizes KI to I2
It oxidizes HCl to Cl2
It gives oxygen, when treated with cold conc. H2SO4
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2 |
Pick out the incorrect statement about K2Cr2O7 |
It is thermally stable
It dissolves in alkali to form chromate
It oxidizes acidified FeSO4 solution to Fe2(SO4)3
It is used as cleansing agent for glassware. etc. When mixed with cold con. H2SO4
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3 |
The yellow colour of chromates changes to orange red on acidification, due to the formation of. |
Cr3+
Cr2O3
Cr2O7<sup>2-</sup>
Cro3
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4 |
Which one of the following oxides is basic. |
MnO
Mn2O3
MnO2
Mn2O7
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5 |
The first ionization energies of the elements of the first transition series. (Ti _____ Cu) |
Increases as the atomic number increases
decreases as the atomic number increases
Do not show any change as the addition of electrons takes place in the inner (n-1) d -orbitals.
Increases from Ti to Mn and then decreases from Mn to Cu
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6 |
Which one of the following statements is not true. |
Transition metals form alloys
Transition metals form complexes
Zn, Cd and Hg are transition metals
K2[PtCl6] is a well known compound but corresponding nikel compound is not knonwn
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7 |
Pick out the incorrect statements for transition metals. |
They have low melting and boiling points
5d-element have higher energies than 3d or 4 d elements
Zr and Hf have almost identical atomic and ionic radii
They form interstitial compounds.
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8 |
The atomic number of Potassium is 19 and that of manganese is 25. Although the coloured of MnO4 is dark violet yet the K+ is colourles.. This is due to the fact that |
Mn is a transition element while K+ is not
[MnO4]is negatively charged while K+ has a positive charge
The effective atomicnumebr of Mn is [MnO4] is 26 while for K+ the atomic number is 18
The Mn in a high positive oxidation state allows charge transfer transitions
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9 |
Pick out the incorrect statement for transition metals. |
Cu+ is not a transition metal ion
Transition metals do not exhibit variable oxidation states
Transition metal ions are coloured
Transition metals and majority of their compounds are paramagnetic
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10 |
The electronic configuration of chromium is 4s1, 3d5, The elements tungsten (W) belongs to the same group and has atomic number 74.The configuration of its valence shell is. |
5s1, 4d5
6s1, 5d5
6s1, 5d6
6s1, 5d4
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11 |
Which of the following has maximum number of unpaired electrons. |
Fe3+
Fe2+
Co2+
CO3+
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12 |
Of the molecules, SF4 Xe F4 and CF4 which have square planar geometry. |
SF4 , Xe f4 and CF4
SF4 only
CF4 only
XeF4 only
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13 |
Which of the following is not known. |
KrF6
XeF6
XeO3
KrF2
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14 |
Xenon reacts best with |
The most electropositive elements
The most electronegative elements
The hydrogen halides
Non metals
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15 |
Which one of the following is not correct. |
Ar is used in electric bulbs
Kr is obtained during radioactive decay
Boiling point of H2 is lowest among all noble gases.
Xe forms Xe OF4
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16 |
Which one of the following is not formed when an electric discharge passes through helium. |
HeH+
HeH2+
He2+
He2-
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17 |
The state of hybridization of Xe in Xe F6 are |
sp2
sp3
sp3 d
dsp3
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18 |
The geometry of Xe F2 is |
Triangular planar
Square planar
Linear
Trigonal bipyramidal
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19 |
Xe reacts directly with |
O2
Cl2
F2
Br2
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20 |
The noble gases which does not I do not form any clathrates is. |
He
Ne
Argpm
Both He and Ne
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