1 |
Which of the following statements is not correct with respect to second law of thermodynamics. |
It helps in know the position of chemical equilibrium
It helps to know the position of chemical equilibrium
It determines the conversion of heat into work
It is based on Nerst heat theorem
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2 |
When two bodies have equality of temperature with a 3rd body they in turn have equality of temperature with each other. This is a statement of. |
First law of thermodynamics
Zeroth law of thermodynamics
Second law of thermodynamics
Third law of thermodynamics
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3 |
Regarding the internal energy of the molecules, which one of the following statements in not correct. |
It is the sum of vibration rotational and electronic energy
It is a path function
It is a state function
It is an exact differential
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4 |
Which of the following enthalpies is always negative. |
Enthalpy of melting
Enthalpy of combustion
Enthalpy of solution
Enthalpy of formation
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5 |
Which of the following reactions have small enthalpy change. |
NaOH with HCl
NaOH with CH3 COOH
HCl with NH4 OH
None of these
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6 |
The variation of enthalpy of reaction with temperature is given by. |
Hesse's law
Clasisus Clapayron equation
Kirchoffs equation
Arrhenious equation.
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7 |
Which of the following statements is not related with joule Thomson effect. |
Joule Thomson is 0 isenthalpic in nature
H2 and He show heating effect
All gases show change in temperature
The change in temperature depends on initial temperature and nature of the gas.
Joule Thomson coefficient is defined as meo= (op/oT)H
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8 |
Which of the following is always true for the adiabatic expansion of gas. |
Temperature rises
Pressure rises
W=0
Q = 0
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9 |
Which of the following statement is not related to applications and limitations of first law of thermodynamics. |
This law explains why chemical reactions proceed to completion
It is silent about the source of heat
It is silent about the direction of heat
It does not tell us about the reversible process.
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10 |
In an isochoric process |
Energy remains constant
Volume remains constant
Pressure remains constant
Temperature remains constant
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11 |
A process in which no heat enters leaves the system is called. |
Isochoric
Isobaric
Adiabatic
Reveraible
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12 |
Which of the following is not an extensive property. |
Work
Entropy
Free energy
Volume
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13 |
Which of the following is not an intensive property. |
Melting point
Refractive index
Entropy
Density
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14 |
Any property whose magnitude is independent of the amount of substance present is called a/an |
Extensive property
Colligative property
Structural propety
Intensive property
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15 |
A closed system is one which can exchange with surrounding. |
Matter but not energy
Energy but not matter
Both matter and energy
Neither matter nor energy
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16 |
A system which can exchange energy as well as natter with its surrounding is said to be a/an |
Closed system
Inert system
Open system
All of above
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17 |
Branch of chemistry that deals with the basic principles governing energy changes during various processes is called. |
Wave mechanics
Chemical kinetics
Chemical thermodynamics
Electro chemistry
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18 |
The compound contains two types of X and Y its crystal structure is a cubic lattice with X-atoms at the corners of the unit cells and Y-atom t the body centre, The simplest formulae of this compound is. |
X2Y
XY
XY2
X8Y
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19 |
In sodium chloride type lattice, the ratio of coordination number of cation to anion is. |
6:6
7:7
4:8
4:4
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20 |
The particle would be stationary in a lattice only at. |
273 K
0 K
298 K
373 K
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