1 |
The vapour pressure of a liquid |
Always increase's with temperature
Always decreases with temperature
Is independent of temperature
Increase up to the boiling point
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2 |
Which of the following molecules has the lowest average speed at 273 K. |
CO2
CO
CH4
O2
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3 |
Which of the following equations is the most general equation of state. |
Vander Waal's equation
Dielectric equation
Clasuaiua equation
Kamberling Onnes equation
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4 |
The velocity possessed by maximum fraction of molecules at a given temperature is called. |
Average velocity
Root mean aquare velocity
Most probable velocity
None of the above
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5 |
The vibration degrees of freedom for a linear and non liner poly atomic molecule of seven atoms each an respectively |
30 and 29
30 and 32
28 and 29
None of above
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6 |
An Ideal gas is one which obeys all the gas law at. |
Low pressure
High Pressure
Low and High temperature
All condition of pressure and temperate re
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7 |
The temperate of a gas below which only the gas cools when allowed to expand is know as. |
Inversion temperature
Ideal temperature
Critical temperature
Joule Thomaon temperatu4re
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8 |
The reciprocal of the coefficient of viscosity in called. |
Density
Specific gravity
Fluidity
Conductance
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9 |
The number of coordinates required to specify the position of all the atoms in a molecule is called number of degree of freedom. The vibration degrees of freedom of a linear molecule containing N atoms are |
2N-5
2N -6
3N -5
N-6
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10 |
The value of comprehensibility factor (z) = pV/nRTfor an ideal gas is equal to. |
R
1
2
3
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11 |
At extremely low pressures, the van der Waals equations for one mole may be written as. |
PV = RT + Pb
PV = RT
PV = RT - a/V
(P +a) (V-b) = RT
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12 |
A gas obeying the van Waals equation will closely resemble and ideal gas if |
The parameters 'a' and 'b' are small
'a' is small but 'b' is large
'a' is large but 'b' is mall
None of the above
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13 |
For one mole a gas, the total kinetic energy is equal to. |
2/3 Rt
3/2 RT
2/3 kT
3/2 kT
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14 |
Which of the following is not a correct postulate of the kinetic theory of gases. |
The molecules are in random motion
The gaseous collisions are perfectly elastic
The average kinetic energies of different gases are equal at a particular temperature.
The pressure exerted on the walls of the container is due to inter molecular forces.
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15 |
The gases H2, N2, O2 and NH3 . H2 =2 , N2 = 28, O2 = 32 and NH3 =17 will effuse in the order. |
H2> N2> O2 > NH3
NH3 >O2 > N2 > H2
H2 > N2 > NH3 > O2
H2 >NH3 > N2 > O2
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16 |
For a given mass of a gas, if pressure in reduced to half and temperature in doubled, then volume. |
2V<sup>2</sup>
4V
8 V
V<sup>2</sup>
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17 |
For a given mass of a gas at constant temperature, if the value V becomes a times, the pressure will become. |
3P
P/3
9P
3P/T
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18 |
Which of the following statement is not correct regarding the constant R . and in ideal gas equation PV= nRT |
Its value in independent of temperature
Its value is independent of pressure
In SI Units its value is 8.314 K<sup>-1</sup> mol<sup>-1</sup>
It is called the universal gas constant per molecule.
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19 |
For a given mass of a gas if temperature increase |
Pressure and volume remain Constance
Volume increases provided pressure is kept constant
Pressure decreases provided volume is constant
Both volume and pressure decrease
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20 |
Total pressure exerted by a mistress of two or more than two gases in a definite volume as any given temperature is equal to the sum of partial pressures which each gas would exert, if it occupied the same volume alone, at the same temperature This is a statement. |
Boyle's law
Charle's law
Graham's law
Dalton's law
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21 |
The constant temperature and pressure,the rates of effusion of various gases vary inversely as square root of their denature. This is a statement of. |
Boyle's law
<div>Charles's law</div>
Graham's law
Daltons's law
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22 |
Equal volumes of all gases, under similar conditions of temperature and pressure, contain equal number of molecules. This is a statement of. |
Graham's law
Dalton's law
Avogadro' law
Boyle's law
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23 |
The volume of given mass of gas at constant pressure is directly proportional to the absolute temperature.This is a statement of. |
Charles's law
Boyle's law
Avogadro's law
Dalton's law
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24 |
The volume of a given mass of gas at constant temperature varies inversely with the pressure. This is a statement of. |
Charlea's law
Avogadro's law
Boyle's law
Dalton 's law
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25 |
The SI unit of pressure is Pascal it is define da sa force per unit are of 1N/m2 one atmosphere of pressure is equal to. |
760 mm of Hg
1 bar
101 k Pa
760 torr
All are correct
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26 |
Which of the following statement is not related to the characteristics of gaseous state. |
The inter molecular forces of attraction are not strong in gaseous state
The gases do not have definite shape and volume
The gases are characterized by low density.
The gases have low comprehensibility
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27 |
A theoretical link between quantum mechanics and thermodynamic is. |
Electrochemistry
Kinetic theory of gases
Spectroscopic analysis
Statistical thermodynamics
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28 |
Which of the following is not evoked in quantum theory? |
Schrodinger wave equation
The rigid rotor approximation
The particle in a box
Boltzmann distribution
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29 |
The Schrodinger equation when solved for any system gives. |
The mean force path
The Polarizability
The energy function
The wave function
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30 |
In quantum theory, which of the following tells us that the prediction of quantum mechanics must pass smoothly into those of classical mechanics as we progress in a continuous way from microsopic to macroecopic. |
Uncertainty principle
Correspondence principle
Probability distribution
Aufbau principle
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