1 |
The equivalent conductance of a 1 N solution of an electrolyte is nearly |
The same as its specific conductance
10<sup>3</sup> times more than its specific conductance
10-3 times its specific conductance
100 times its specific conductance.
|
2 |
According to the Debye-Huckel theory of strong electrolytes, and ion moving in an atmosphere of oppositely charged ions experience a drag This effect is known as |
Aaymmetric effect
Electrophoretic effect
Inter ionic effect
Concentration effect
|
3 |
During the titration of weak acid against NaOH the conductance of the solution after the neutralization point. |
Is constant
Decreases
Varies irregularly
Increase
|
4 |
When a concentrated solute of an electrolyte is diluted. |
Its specific conductance increases
Its equivalent conductance decreases
The specific conductance decreases and equivalent conductance increases
Both specific and equivalent conductance increase
|
5 |
If for a solution of an electrolyte. It is the transport number of the cation, then the transport number of the anion I, is equal to |
t/2
1 - t+
1 + t+
(i -t) /2
|
6 |
The fraction of the total current carried to an ion is called itss. |
Ionic mobility
Transport number
Limiting ionic conductance
None of these
|
7 |
Equivalent conductance is expressed in the units. |
S cm-1 eq -1
S cm eq-1
S cm2 eq-1
S cm2 eq
|
8 |
Which of the following statements is not correct. |
The conductance of one cm3 of a material is called specific conductance
Specific conductance increase while equivalent conductance decreases on progressive dilution
The limiting equivalent conductance of weak electrolytes cannot be determined by extrapolation of the plot of A against concentration
The conductivity of metals is due to the movement of elctrons.
|
9 |
Which of the following statement is not correct with reference to cell constant. |
The dimensions of cell constant is cm-1
It is used to determine the specific conductance
It is measured with KCl solution
Specific conductance does not vary with concentration.
|
10 |
Which of the following expressions represent the equivalent conductance. |
A = l s x 1000/V
A = Ls x 1000/C
A = Ls l/A
A = Ls/V
|
11 |
The conductance of 1 cm3 of an electrolytes solution is called its. |
Specific resistance
Specific conductance
Molar conductance
Equivalent conductance
|
12 |
The unit of specific conductance will be |
S cm-1
Ohm cm
Ohm cm-1
Mho cm
|
13 |
The expression of specific conductance is given by |
Ls= I/R , l/A
Ls = L I/A
Ls = I/L , A/l
LS = r l/A<br>
|
14 |
Which of the following statements is not true with reference to ionic conductors. |
Ionic conductance is due to movement of the ions
It involves the transfer of matter
It involves oxidation reduction reactions
It decreases with rise in temperature.
|
15 |
The blue colour of CuSO4 disappears on adding Zn granules to it . it is because of . |
Oxidation of Cu atom
Oxidation of Zn<sup>2+</sup>
Oxidation Cu<sup>2+</sup>
Oxidation of Zn<sup>2+</sup>
|
16 |
When some quantity of electricity is passed though two electrolytic cells. The ratio of the mass of the products obtained at the cathode is the same as the ratio of their |
Densities
Atomic masses
Equivalent masses
Atomic numbers
|
17 |
Which of the following relation corresponds to Faraday law of electrolysis. |
m = ZI t
E = mc<sup>2</sup>
E = ho
None of the above
|
18 |
The device that convert the chemical energy of fuel directly into electrical energy is called. |
Galvanic cell
Electrolytic cell
Fuel cell
Concentration cell
|
19 |
The branch of chemistry which is concerned with the interrelation of electrical and chemical energy is called. |
Reaction dynamics
Electrochemisty
Surface chemistry
Kinetics
|
20 |
Which of the following solids is a better conductor of electricity. |
Pore NaCl cyrstal
Diamond
Graphite
Marble pieces
|
21 |
The point group of XeOF4 is. |
C6v
C4h
D4h
D2h
|
22 |
How many planes of symmetry are present in benzene. |
1 plane
3 planes
5 planes
7 planes
|
23 |
Ethylene belongs to. |
C<sub>2v</sub> group
D<sub>2h</sub> group
C<sub>2</sub> group
D<sub>ah</sub> group
|
24 |
CO belong to which group. |
C<sub>2v</sub>
D<sub>2h</sub>
C<sub>av</sub>
D<sub>ah</sub>
|
25 |
Which of the following molecules belongs to Cav point group. |
H2O
H2S
NH3
BF3
|
26 |
Which of the following statement is not correct with respect to group theory. |
Two elements of a group combine to form a third element of a group
An element combines with itself to form another element of the group.
Each element of the group obey associative law of combination
Each group element has no reciprocal
|
27 |
Which of the following molecules have centre of symmetry. |
H2O
HCl
CO2
H2SO4
|
28 |
Linear molecules have ____________ axis of rotation |
C1
C2
C
C3
|
29 |
In C4-axis of rotation, an object in rotated through an angle of. |
120<sup> o</sup>
180<sup> o</sup>
100 <sup>o</sup>
90<sup> o</sup>
|
30 |
In proper rotation (Cn) an object is rotated through an angle of. |
a/n radians
2n/n radians
3n/n radians
4n/n radians
|