1 |
Ziegler -Natta catalysta is |
(C2H3)3 Al
TiCl4
(C2H5)3 Al/TiCl4
(C2H3)3 B/TiCl2
|
2 |
Which of the following type of polymerization is used for the preparation of synthetic rubber. |
Free radical
Zingler natta
Cationic
Anionic
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3 |
Casionic polymerization is initiated by |
BF3
NaNH2
Bul
Both b and c
|
4 |
In which polymerization branching of chain cannot be possible. |
Free radical
Cationic
Anionic
Anionic and Zieglar Natta
|
5 |
In propagation step the reaction intermediate of radical polymerization is |
Carbocation
Carbonion
Free radical
Carbene
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6 |
Which of the following compounds cannot be a monomer. |
CH3-CHOOH -CH2OH
NH2 -CH2-NH2
CH3-CH2-NH3
NH2-CH2-CH-CH2 -NH2<div><br></div><div> CH3</div>
|
7 |
Polyamide jinkage is present in |
Nylon
Silk
Protein
All of these
|
8 |
Which of the following is branch chain polymer. |
Glycogen
Terylene
PVC
Orlen
|
9 |
Which type of polymers the Vulcanised rubbers is. |
Linear
Cross jinked
Branch chain
Any one of these
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10 |
Which of the following linear polymer. |
Polypeptide
Protein
Starch
Phenol formaldehyde resin
|
11 |
Which of the following statements are correct for Linear polymers. |
Linear polymers may be condensation as well as addition polymers
Structure is well packed in nature
Linear polymers have higher density higher melting point and higher tensile strength
All are correct
|
12 |
Which type of polymer the Nylon -06 is |
Polyamide
Polyester
Addition
Homopolymer
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13 |
Which of the following is homopolymer. |
Starch
Plexiglas
Orlon
All of these
|
14 |
Monomer of Nylon -6 is |
Adipic acid
Hexamethylenediamine
Caprolactam
All of these
|
15 |
Which of the following is not a biodegradable polymer. |
Protein
PVC
Cellulose
Nucleic acid
|
16 |
Which one of the following is natural polymer. |
Starch
Nylon-6
Neoprene
Buna-S, SBR
|
17 |
Glycerol on dehyeration gives |
Allyl alcohol
Aerolein
CHOH = C= CHOH
-CHO -CHOH -CH2OH
|
18 |
Rectified spirit obtained by formentation contains 5% of water .So in order to remove it, rectified spirit is mixed with suitable quantity of benzene and heated Benzene helps because. |
It is dehydreating agent and so removes water
It forms the loweer layer which retains all the water so that alcohol can be distilled off
It form an azeotropic mixture having high boiling point and thus allows the alcohol to distall over
It forms low boiling azeotropic mixture which distille over leaving behind pure alcohol which can than be distilled.
|
19 |
Treatment of phenol with cold dilute nitric acid gives. |
Only o-nitro phenol
Only p-nitro phenol
2,4,6 -Teinitro phenol
Mixture of o-and p-nitro phenol
|
20 |
Each of the following when present at para position decreases the acidic strength of phenol except. |
-NH2
-Cl
CH3O-
CH3-
|
21 |
Phenol on reaction with ethanoic anhydrides in the presence of sodium ethanoate gives. |
Phenyl benzoate
Ethyl benzoate
Phenyl ethanoate
Phenyl methyl ether
|
22 |
Which of the following statements regarding phenols is not correct. |
Phenol ls are stronger acids than water and alcohols.
Phenol are weaker acids than carboxylic acids
Phenol are solubel in both aqueous NaOH and aqueous sodium hydrogen carbonate
Phenoxides ions are more stable than the corresponding phenol
|
23 |
An aromatic compound has a molecules formula C7H8O. How many isomers are possible for this compound. |
3
4
5
6
|
24 |
Which of the following reagent cannot be used to detect the phenolic group. |
Neutral FeCl3
I2/NaOH
NaOH solution
Br2/H2O
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25 |
An organic liquid (X) containing C, H and H has a pleasent odour with a boiling point of 78 oC. On boiling X with conc. H2SO4 a colourless gas is produced which decolourless bromine water and alkaline KMnO4 One mole of this gas also takes one mole of H2. The organic liquid (X) is. |
n-C3H7OH
iso-C3H7OH
C2H5CHO
CH3CH2OH
|
26 |
In which of the following group, each member given a positive iodoform test. |
Methanol, ethanol, propanone
Ethanol, isopropyl alcohol, methanol
Ethanol, ethanal, isopropyl alcohol
Propanal 2-propanol, propanone
|
27 |
The reason why phenylamine is a much weaker base tahn ammonia when each is in aqueous solution to that. |
Teh ion pair of electron on two nitrogen atom of phenylamine is delocalised over the benzene ring.
The phenylamine molecule is too large to capture hydrogen ion easily
Phenylamine is much less soluble is water than is ammonia
The benzene ring has a tendency to increase the acidity of its substituents.
|
28 |
Which of the following compounds would you use in order to obtain a crystalline derivative of an aromatic amine. |
2,4 Dinitrophenyl hydrazine
Nitrous acid
Benzoyl chlride
None of these
|
29 |
Carbylamine reaction proceeds via the intermediate formation of. |
Alkyl isocyanide
Chloride ion
Alkyl carbonion
Dichloro methylene
|
30 |
The reagent which can be used to distinguish acetophenone from benzophenone is. |
2,4 -dinito phenyl hydrazine
Li AIH4
Benedict reagetn
I2 and Na2CO3
|