1 |
Which of the following statements is not correct with respect to applications of Hammett equations. |
It develops a quantitative relationship between structure and reactivity
This equation on can be used to calculate the value of pK<sub>a</sub>
This equation does not help to calculate the rate of some reactions
This equation has mechanistic implications
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2 |
The equation which relates the reaction rates and equilibrium constants of many reactions is known as. |
Taft equation
Hammett equation
Differential equation
Linear equation
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3 |
Which of the following haloacids is stronger acids. |
FCH2COOH
ClCH2COOH
Br CH2COOH
ICH2COOH
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4 |
Which of the following groups exert -1 effect. |
- NO2
- CN
-COOH
<C = 0
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5 |
Which of the following factors effect the strengths of acids and bases. |
Inductive effect
Romance effect
Hydrogen effect
All above
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6 |
Which of the following statements not correct with the concept of Bronsted concept of acids and bases. |
An acid can donate a proton
A base can accept a proton
This concept has many bases that have OH- ions
This concept is more general
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7 |
Which of of the following statement is not correct in respect of Arrhenius concept. |
This concept is applicable only for aqueous systems.
Neutralization takes place in aqueous medium only
H+ ion concept remain as such in water
This concept is applicable for non aqueous system only.
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8 |
Inorganic acids (HCl, HBr, HNO3 etc) have K value. |
< 1
>1
>10
<10
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9 |
Which of the following statements do not represent Lewis idea of acids and base? |
Compounds which have completely filled orbitals
Compounds which have incompletely filled orbitals
Compounds in which the central atom can expand its octel
All simple metal ions like Ag+, Al3+ etc.
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10 |
Which of the following does not represent Lewis base. |
Pyridine
NaNH2
PCl3
NaOH
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11 |
Which of the following does not represent Lewis acid. |
ZnCl2
FeCl2
BF3
Bul4
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12 |
Which of the following pairs does not represent Lowery acid base pair. |
H2O+NH3
H2O +H2O
HCL + H2O
CH3NH2 + BF3
|
13 |
Which of the following statements is not correct with the concept of Bronsted concept of acids and bases. |
An acid can donate a proton
A base can accept a proton
This concept has many bases that have OH- ions
This concept is more general
|
14 |
Which of the following statement is not correct n respect of Arrhenius concept. |
The concept is applicable only for aqueous systems.
Neutralization takes place in aqueous mediam only
TH+ ion cannot remain as such in water
This concept is applicable for non aqueous system only.
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15 |
Which of the following is strong adheaive. |
Epoxy resin
Melamine -formadehyde resin
Alkyd resins
Bakelite
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16 |
SAN is a polymer of |
Styrene
Acrylonitrile
Both A and B
Vinyl chloride
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17 |
Which of the following polymers is chlorinated. |
Orlon
Neoprene
Dacron
None of these
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18 |
Soft drinks and baby feeding bottles are generally made up |
Polyeater
Polyurethens
Polyamide
Polyetyrene
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19 |
What type of inter molecular force present in nylon-66o |
Vander wall
Hydrogen bond
Dipole -dipole interactions
Sulphide linkage
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20 |
Which is not true about polymers. |
Polymers do not carry any charge
Polymers have high viscosity
Polymers scatter light
Polymers have low molecular weight
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21 |
Which of the following contains isoprene unite. |
Natural rubber
Nylong -6,6
Polyethylene
Decron
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22 |
Orion is polymer of. |
Styrene
CF2 = CF2
Vinyl chloride
Acrylontrile
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23 |
Which of the following is used to make non-stick material. |
Vinyl cyanide
Tetrafluoroethene
Vinyl chloride
Styrene
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24 |
Monomer of neoprene rubber to |
1-chloro 1,3- butadiene
2- chlro, 1,3-butadiene
2-Bromo -1,3- butadiene
2-Methyl 1,3-butadiene
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25 |
Monomers are Teflon is |
Monochloroethene
1,2- Difluoroethene
1,1,2- Trifluoroethene
Tetrafluoroethene
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26 |
In order to give strength and elasticity natural rubber is heated with. |
Sulphur
Oxygen
Nitrogen
Chlorine
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27 |
Gutta percha is |
Cis poly imprene
Trans -polyisoprene
Polyethylene
Polyisobutylene
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28 |
Monomer of natural rubber is |
1,3-Butadiene
2-Methyl -1,3-butadiene
1,2 -Butadiene
1,3 - Pentadiene
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29 |
In which polymer the strength of inter molecular forces is maximum |
Elastomers
Thermoplastic
Fibre
Cross linked polymer
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30 |
High density polyethylene has which type of structure. |
Linear
Branch chain
Cross linked
Any one of these
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