1 |
The most reactive compound for electrophilic nitration will be |
Benzyl chloride
Benzoic acid
Nitrobenzene
Chlorobenzene
|
2 |
What happens when CCl4is treated with AgNO3solution? |
NO<sub>2</sub>will be evolved
A white ppt. of AgCl will form
CCl<sub>4</sub>will dissolve in AgNO<sub>3</sub>solution
Nothing will happen
|
3 |
Reaction of ethylamine with chloroform in alcoholic KOH produces |
CH<sub>3</sub>OH
CH<sub>3</sub>NC
C<sub>2</sub>H<sub>5</sub>NC
C<sub>2</sub>H<sub>5</sub>CN
|
4 |
Ethyl chloride on treatment with aqueous alkali gives |
Ethane
Ethene
Ethanal
Ethanol
|
5 |
DDT is formed from |
Benzene and Chlorobenzene
Chloral and Chlorobenzene
Chloral and benzene
Chlorobenzene and chlorine
|
6 |
Which of the following with aqueous KOH will give acetaldehyde? |
1, 2-Dichloroethane
1, 1-Dichloroethane
Chloroacetic acid
Ethyl chloride
|
7 |
Aryl halides are less reactive towards nucleophilic substitution reactions as compared to alkyl halides due to |
The formation of less stable carbonium ion
Resonance stabilization
Larger carbon -halogen bond
The inductive effect
|
8 |
Carbon atom holding halogen in aryl halides is |
sp<sup>2</sup>-hybridesed
sp<sup>3</sup>-hybridesed
sp-hybridesed
sp<sup>3</sup>d-hybridesed
|
9 |
Which of the following reagent cannot be used for preparing alkyl chloride from alcohol? |
HCl + anhyd. ZnCl<sub>2</sub>
NaCl
PCl<sub>5</sub>
SOCl<sub>2</sub>
|
10 |
Octane number can be changed by |
Isomerisation
alkylation
Cyclisation
All of these
|
11 |
The treatment of benzene with isobutene in the presence of sulphuric acid give |
isobutyl benzene
tert-Butyl benzene
n- Butyl benzene
no reaction
|
12 |
Which of the following possesses the highest melting point? |
Chlorobenzene
o- Dichlorobenzene
m-Dichlorobenzene
p-Dichlorobenzene
|
13 |
Which of the following species participate in sulphonation of benzene ring? |
H<sub>2</sub>SO<sub>4</sub>
HSO<sup>-</sup><sub>3</sub>
SO<sub>3</sub>
SO<sup>-</sup><sub>2</sub>
|
14 |
Heating a micture of sodium benzoate and soda lime gives |
Benzene
Methane
Sodium benzoate
Calcium benzoate
|
15 |
Benezene is obtained by fractional distillation of |
Heavy oil
Anthracene oil
Middle oil
Light oil
|
16 |
Which species represents the electrpohile in aromatic nitrotaion? |
NO<sup>-</sup><sub>2</sub>
NO<sup>+</sup><sub>2</sub>
NO2
NO<sup>-</sup><sub>3</sub>
|
17 |
Which reaction sequence would be best to prepare 3-chloro-aniline from benzene? |
Chlorination, nitration, reduction
Nitration, Chlorination, reduction
Nitration, reduction, chlorination
Nitration, reduction, acylation, chorination, hydrolysis
|
18 |
Most common reactions of benzene and its derivatives are |
Electrophilic addition reactions
Electrophilic subsitution reactions
Nucleoophilic addition reactions
Nucleophilic substitution reactions
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19 |
The reaction/method that does not give an alkane is |
Catalytic hydrogenation of alkanes
Wurtz reaction
Hydrolysis of alkyl magnesium bromide
Dehydrohalogenation of an alkyl halide.
|
20 |
Which of the following method is most appropriate for the manufacture of methane? |
By reduction of CH2SL2
Wurtz reaction
Liquification of natural gas
None of these
|