1 |
In cold countries ethylene glycol is added to water in radiators of cars during winter. It results in |
Lowering in b.pt.
Reducing viscity
Reducing specific heat
Lowering in freezing pt.
|
2 |
What happens when isotonic solution of a (mol. wt. 342) and B (mol. wt 60) are put in to communication through semiperme-able membrane? |
Transference of solvent from solution A to that of B take place
Transference of solvent from solution B to that of A takes place
No transference of solvent from solution A to that of B takes place
Change in temperature of solutions takes place.
|
3 |
The freezing point of 1 molal NaCl solution assuming NaCl to be 100% dissociated in water in |
-1.86<span style="color: rgb(34, 34, 34); font-family: "Times New Roman"; font-size: 18px; background-color: rgb(255, 255, 248);">°C</span>
-3.72<span style="font-family: "Times New Roman"; font-size: 18px; color: rgb(34, 34, 34); background-color: rgb(255, 255, 248);">°C</span>
+1.86<span style="font-family: "Times New Roman"; font-size: 18px; color: rgb(34, 34, 34); background-color: rgb(255, 255, 248);">°C</span>
+3.72<span style="font-family: "Times New Roman"; font-size: 18px; color: rgb(34, 34, 34); background-color: rgb(255, 255, 248);">°C</span>
|
4 |
Which of the following value ofΔHf represent that product is least stable? |
-94.0 kcal mol<sup>-1</sup>
-231.6 kcal mol<sup>-1</sup>
+21.4 kcal mol<sup>-1</sup>
+64.8 kcal mol<sup>-1</sup>
|
5 |
All the naturally occurring processes proceed spontaneously in a direction which lead to |
Decrease of entropy
Increase of enthalpy
Increase of free energy
Decrease of free energy
|
6 |
ΔHneutralisationis always |
positive
Negative
Zero
Positive or negative
|
7 |
The heat evolved in combustion of rhombic and monoclinic sulphur are -70960 and -71030 cal mol-1respectively. What will be heat of conversion of rhombic sulphur to monoclinic? |
70960 calories
71030 calories
-70 calories
+70 calories
|
8 |
Hess's law deals with |
Changes in heat or reaction
Rate of reaction
Equilibrium constant
Influence of pressure on volume of a gas.
|
9 |
An endothermic reaction is one in which the reacting substances |
Have more energy than the products
Have less energy than the products
Have the same energy as the products
Are at a higher temperature than the products.
|
10 |
Which of the following units represents largest amount of energy? |
Calorie
Joule
Erg
Electron vol.
|
11 |
Evaporation of water is |
An exothermic change
an endothermic change
A process where no heat changes occur
A process accompanied by chemical reaction.
|
12 |
Inter molecular forces in solid hydrogen are |
Covalent forces
Van der Waal forces or London dispersion forces
Hydrogen bonds
All of these.
|
13 |
According to MO theory, the species O+2 |
Bond order of 2.5
Three unpaired electrons
Diamagnetic character
Stability lower then O<sub>2</sub>
|
14 |
The bond angle H-O-H in ice is closest to |
120<span style="color: rgb(34, 34, 34); font-family: "Times New Roman"; font-size: 18px; background-color: rgb(255, 255, 248);">° . 28'</span>
60<span style="font-family: "Times New Roman"; font-size: 18px; color: rgb(34, 34, 34); background-color: rgb(255, 255, 248);">°</span>
90<span style="font-family: "Times New Roman"; font-size: 18px; color: rgb(34, 34, 34); background-color: rgb(255, 255, 248);">°</span>
109<span style="font-family: "Times New Roman"; font-size: 18px; color: rgb(34, 34, 34); background-color: rgb(255, 255, 248);">°</span>
|
15 |
The carbon atoms in calcium carbide are held by |
Ionic bonds
Sigma bonds
2 covalent, one co-ordinate bond
<i>2</i><span style="color: rgb(34, 34, 34); font-family: "Times New Roman"; font-size: 24px; text-align: center; background-color: rgb(255, 255, 224);"><i>π</i> <i>and one</i></span><span style="color: rgb(34, 34, 34); font-family: "Times New Roman"; font-size: 24px; text-align: center; background-color: rgb(255, 255, 248);"><i>α bond</i></span>
|
16 |
Outermost shells of two elements X and Y have two and six electrons respectively. If they combine, the expected formula of compound will be |
XY
X<sub>2</sub>Y
X<sub>2</sub>Y<sub>3</sub>
XY<sub>2</sub>
|
17 |
Which of the following geometry is associated with the compound in which the central atom assumes sp3d hybridization? |
Planar
Pyramidal
Angular
Trigonal bipyramidal
|
18 |
Covalent compounds are soluble in |
Polar solvents
Non-polar solvents
Concentrated acids
All solvents
|
19 |
Among the alkaline earth metals the element forming predominantly covalent compounds is |
Be
Mg
Sr
Calcium
|
20 |
Hydrogen chloride molecule contains |
Covalent bond
Double bond
Co-ordinate bond
Electrovalent bond
|