| 1 |
An organic compound will decolorise dill acidified (aq) KMnO4on warming, but will not decolorise bromine water. What is the compound |
KMnO<sub>4</sub>
Ethanol
Ethane
CH<sub>3</sub>CH<sub>2</sub>Cl
|
| 2 |
Which structure shows a tertiary alcohol |
CH<sub>3</sub>CH<sub>2</sub>OH
(CH<sub>3</sub>)<sub>2</sub>CHOH
(CH<sub>3</sub>)<sub>3</sub>COH
CH<sub>2</sub>OH
|
| 3 |
How many secondary alcoholic groups are present in the structure of glucose OHC CHOH CHOHCH OH CHOH CH2OH |
1
2
3
4
|
| 4 |
What will react differently with the two isomeric pentols, (CH3)3CCH2OH and (CH3)2CH CH2CH2OH |
Acidified (aq) KMnO<sub>4</sub>
Concentrated H<sub>2</sub>SO<sub>4</sub>
PCl
Sodium
|
| 5 |
Which alcohol gives only one oxidation product when wormed with dil acidified K2Cr2O7 |
Butan-1-ol
Butan-2-ol
2-methyl propan-1-ol
2-methyl propan-2-ol
|
| 6 |
How many alcohol (including both structural isomers and stereoisomers) can have the molecular formula C4H10O |
3
4
5
6
|
| 7 |
|
NH<sub>3</sub> HCl
KCN in C<sub>2</sub>H<sub>5</sub>OH NaOH
KCN in C<sub>2</sub>H<sub>5</sub>OH HCl
HCN NaOH
|
| 8 |
|
Electrophilic substitution
Free radical reduction
Isomerisation
Nucleophilic substitution
|
| 9 |
Which reaction is example of nucleophilic substitution |
|
| 10 |
What is the total number of different chloroethanes, formula C2H6-nCln, where n can be any integer from 1 to 4 |
4
6
7
8
|
| 11 |
|
Condensation
Electrophilic substitution
Free radical substitution
Nucleophilic substitution
|
| 12 |
Each of the following compounds is effective as a refrigerant. The release of which one of these causes the greatest depletion of the ozone layer |
CCl<sub>2</sub>F<sub>2</sub>
CH<sub>3</sub>OCH<sub>3</sub>
CH<sub>3</sub>CHF<sub>2</sub>
CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub>
|
| 13 |
CFCs undergo homolytic fission by uv light in the stratosphere which radical could result from this irradiations of CHCICF2Cl. |
CHF Cl C FCl
CH Cl CF<sub>2</sub>Cl
CHF CF<sub>2</sub>Cl
C FCl CF<sub>2</sub>Cl
|
| 14 |
What is the total number of different chloroethanes of formula C2H6-nClnpossible (n may be 1 to 6) |
6
8
9
10
|
| 15 |
|
Electrophilic addition
Electrophilic substitution
Free radical substitution
Nuclophilic addition
|
| 16 |
Which one of the following is not a nucleophile |
H<sub>2</sub>O
H<sub>2</sub>S
BF<sub>3</sub>
NH<sub>3</sub>
|
| 17 |
Alkyl halides ae considered to be very reactive compounds towards nucleophiles because |
They have an electrophilic carbon
They have an electrophilic carbon and a good leaving group
They have an electrophilic carbon and a bad leaving group
They have a nucleophilic carbon and a good leaving group
|
| 18 |
When CO2is made to react with ethyl magnesium iodide, followed by acid hydrolysis, the product formed is |
Propane
Propanoic acid
Propanal
Propanol
|
| 19 |
Grignard's reagent is |
Alkyl halide
Magnesium halide
Alkyl magnesium halide
Ethereal solution of an alkyl halide
|
| 20 |
When formaldehyde is added to Grignard reagent we get |
Aldehyde
Acetone
Primary alcohol
Secondary alcohol
|
| 21 |
The compounds or species in search of electrons are called |
Elctrophiles
Nucleophile
Nitrities
Bases
|
| 22 |
Thre rate of SN2 reaction depends upon the |
Concentration of alkyl halides
Concentration of nucleophile
Concentration of alkyl halides and nucleophile
None of the above
|
| 23 |
When alkyl halide is heated with aqueous solution of ammonia at 100°C the major product is |
Primary amine
Secondary amine
Tertiary amine
Mixture of amines and salt
|
| 24 |
Which of the following alkyl halides is used as a mathylating agent |
CH<sub>2</sub>H<sub>5</sub>l
CH<sub>3</sub>l
C<sub>2</sub>H<sub>5</sub>Pr
C<sub>2</sub>H<sub>5</sub>Cl
|
| 25 |
During nitration of benzene, the active nitrating agent is |
NO3
NO2+
NO2-
HNO3
|
| 26 |
Amongst the following the compound that can be most readily sulphonated is |
Toluene
Benzene
Nitrobenzene
Chlorobenzene
|
| 27 |
Benzene does not undergo |
Substitution reaction
Addition reaction
Oxidation reaction
Elimination reaction
|
| 28 |
Aromatic hydrocarbons are the derivatives of |
Normal series of paraffins
Alkene
Benzene
Cyclohexane
|
| 29 |
The benzene molecule contains |
Three double bonds
Two double bonds
One double bonds
Delocalizedπ-electron charge
|
| 30 |
A single benzene ring can have ______ ortho position maximally |
One
Two
Three
Four
|