| 1 |
Pick out the wrong statement. In electrochemical cell |
Electrons are released at anode
Cathode is regarded as negative electrode
Chemical energy is converted into electrical energy
Salt bridge maintains the electrical neutrality of the solution
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| 2 |
What will be the weight of deposited silver on passing 965 coulombs of electricity in solution of AgNO3? |
1.08 g
2.16 g
0.54 g
0.27 g
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| 3 |
The number of coulombs required for the deposition of 107.870 g of silver is |
96500
48250
193000
10000
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| 4 |
The art of electroplating was given by |
Faraday
Edison
Thomas Gradam
Brugan
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| 5 |
96500 C electricity is passed through CuSO4. The amount of copper precipitated is |
0.25 mole
0.5 mole
1.0 mole
2.00 mole
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| 6 |
Reaction takes place at anode is |
Ionization
Reduction
Oxidation
Hydrolysis
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| 7 |
2.5 faradays of electricity is passed through solution of CuSO4. The number of gram equivalents of copper deposited on the cathode would be |
1
2
2.5
1.25
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| 8 |
In a solution of CuSO4how much time will be required to precipitate 2g copper by 0.5 ampere current? |
12157.48 sec
102 sec
510 sec
642 sec
|
| 9 |
Which of the following is the use of electrolysis? |
Eletrorefining
Electroplating
Both A and B
None of the above
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| 10 |
96500 C of electricity liberates from CuSO4solution |
63.5 g of Cu
31.75 g of Cu
96500 g of Cu
100 g of Cu
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| 11 |
Pure water does not conduct electricity because it |
Has low boiling point
Is almost unionized
Is neutral
Is readily decomposed
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| 12 |
Which of the following is a strong electrolyte? |
Ca(NO<sub>3</sub>)<sub>2</sub>
HCN
CH<sub>3</sub>COOH
NH<sub>4</sub>OH
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| 13 |
When electricity is passed through molten electrolyte consisting of alumina and cryolite, 13.5 g of Al are deposited. The number of faradays of electricity passed must be |
2.0
1.5
1.0
0.5
|
| 14 |
In a Galvanic cell |
Chemical energy is converted into electricity
Chemical energy is converted into heat
Electrical energy is converted into heat
Electrical energy is converted into chemical energy
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| 15 |
The amount of electricity that can deposit 108 g of silver from silver nitrate solution is |
1 ampere
1 coulomb
1 faraday
2 ampere
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| 16 |
The conductivity of strong electrolyte |
Increases on dilution slightly
Does not change on dilution
Decreases on dilution
Depends on density of electrolyte it self
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| 17 |
Out of Cu, Ag, Fe and Zn the metal which can displace all others from theri salt solution is |
Ag
Cu
Zn
Fe
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| 18 |
A certain current liberate 0.5 g of hydrogen in 2 h. How many grams of copper can be liberated by the same time in a copper sulphate solution? |
12.7 gm
15.9 gm
31.8 gm
63.5 gm
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| 19 |
A current of 9.65 ampere flowing for 10 minutes deposits 3.0 g of the metal which is monovalent. The atomic mass of the metal is |
10
50
30
96.5
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| 20 |
A solution of sodium sulphate was electrolysed using some insert electrodes. The products at the electrodes are |
O<sub>2</sub>, H<sub>2</sub>
O<sub>2</sub>, Na
O<sub>2</sub>, SO<sub>2</sub>
O<sub>2</sub>, S<sub>2</sub>O<sub>8</sub><sup>2</sup>
|
| 21 |
A cell constant is generally found by measuring the conductivity of aqueous solution of |
BaCl<sub>2</sub>
KCl
NaCl
MgCl<sub>2</sub>
|
| 22 |
An electrolyte |
Forms complex ions solution
Gives ions only when electricity is passed
Possesses ions even in solid state
Gives ions only when dissolved in water
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| 23 |
When electrically is passed through molten Al2O3+ Na3AlF6and 13.5 gms of Al are deposited, the number of farady must be |
0.5
1.0
1.5
2.0
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| 24 |
The reference calomel electrode is made from which of the following? |
ZnCl<sub>2</sub>
CuSO<sub>4</sub>
Hg<sub>2</sub>Cl<sub>2</sub>
HgCl<sub>2</sub>
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| 25 |
If a salt bridge is removed between the two half cells, the voltage |
Drops to zero
Does not change
Increases gradually
Increases rapidly
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| 26 |
When quantity of electricity passed is one faraday then the mass deposited at the electrode is equal to |
One gm, atomic weight
One gm, Equivalent
Eletrochemical equivalent
None of the above
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| 27 |
Which of the substances Na, Hg, S Pt and graphite can be used as electrodes in electrolytic cells having aqueous solution? |
Na, Pt and graphite
Na and Hg
Pt and graphite only
Na and S only
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| 28 |
The osmotic pressure of a dilute solution is directly proportional to the |
Diffusion rate of the solute
Ionic concentration
Elevation in boiling point
Flow of solvent from a concentrated to a dilute solution
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| 29 |
The vant Hoff factor (1) accounts for |
Degree of solubilisation of solute
The extent of dissolution of solute
The extent of dissolution of solute
The degree of decomposition of solution
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| 30 |
Equal volumes of ethylene glycol (molar mass = 62) and water (molar mass = 18) are mixed. The depression in freezing point of water is (given Krof water = 1.86 K mol-1kg and specific gravity of ethylene glycol is 1.11) |
0.003
3.33
0.333
33.3
|