1 |
|
+712 KJ mol<sup>-1</sup>
+492 KJ mol<sup>-1</sup>
-932 KJ mol<sup>-1</sup>
-960 KJ mol<sup>-1</sup>
|
2 |
|
-76 KJ
-57 KJ
-171 KJ
-114 KJ
|
3 |
During a chemical reaction heat may be |
absorbed
Evolved
Both evolved and absorbed
None of these
|
4 |
A system undergoes a change to attain the state of |
High energy
Low energy
Moderate energy
None of these
|
5 |
ΔH for an endothermic reaction carries |
Positive sign
Negative sign
Both sign
None of these
|
6 |
Energy can neither be created nor destroyed, although it can be transformed from one form to another. This is a statement of |
Law of conservation of matter
Law of definite proportions
Law of conservation of energy
None of these
|
7 |
By applying Hess's law, we can calculate |
<i style="text-align: center;">Δ</i>H
<i style="text-align: center;">Δ</i>S
<i style="text-align: center;">Δ</i>F
K
|
8 |
The amount of heat evolved or absorbed in a process in the same whether the process takes place in one or several steps is the statement of |
First law of thermodynamics
Hess's law
Coulomb's law
Phase law
|
9 |
ΔH is equal to |
E + PV
E + P<i style="text-align: center;">Δ</i>V
<i style="text-align: center;">Δ</i>E + P
<i style="text-align: center;">Δ</i>E + P<i style="text-align: center;">Δ</i>V
|
10 |
Which substances haveΔH =ΔE |
Solids
Liquids
Gases
Liquids and solids
|
11 |
The mathematical form of fist law of thermodynamics is |
|
12 |
The energy of the system and surrounding is conserved. This is a statement of |
Law of mass action
Law of definite proportion
Law of conservation of energy
Second law of thermodynamics
|
13 |
|
Adding 2(ii) + 3(iii) and subtracting i
Add i + ii + iii
Add i - ii + iii
Add i - ii - iii
|
14 |
Given data (i) heat of formation of CO2is -393.7 KJ mole-1 (ii) heat of formation of H2O is -285.8 KH mole-1 (iii) heat of combustion of CH4 is -890.00 KJ mole-1 Enthalpy of formation of methane from C and H2is calculated by Hess's law by |
Adding i + ii + iii
Adding 2(i) and ii and subtracting iii
adding i + iii and subtracting ii
Adding i + 2(ii) and subtracting iii
|
15 |
Given date (i) heat of neutralization of HCl and NaOH is -57.3 KJ mole-1 (ii) heat of neutralization of CH3COOH with NaOH is 55.2 KJ mole-1 The enthalpy of ionization of CH3COOH is a determined according to Hess's law by |
Adding i and ii
Dividing i by ii
Subtracting i from ii
Subtracting ii from i
|
16 |
Statement enthalpy of combustion of H2is -285.8 KJ mole-1then which is the standard enthalpy of formation of water |
+285.8 KH mole<sup>-1</sup>
-285.5 KJ mole<sup>-1</sup>
Zero
-218 KJ mole<sup>-1</sup>
|
17 |
The amount of heat required to convert one mole of solid directly into its vapour state at STP is called as |
Molar heat of vaporization
Standard heat of vaporization
Heat of reaction
Heat of neutralization
|
18 |
B-atom in BF3has |
sp<sup>3</sup>hybridization
sp<sup>2</sup>hybridization
sp hybridization
no hybridization
|
19 |
Which of the following molecules have its central atom sp2hybridized |
CH<sub>4</sub>
C<sub>2</sub>H<sub>2</sub>
C<sub>2</sub>H<sub>4</sub>
CCl<sub>4</sub>
|
20 |
Planar geometry of molecules is due to |
sp<sup>3</sup>hybridization
sp<sup>2</sup>hybridization
sp hybridization
P - p overlap
|
21 |
Nitrogen in NH3is sp3hybridized but the bond angle in NH3is 107° and not 109.5° due to |
sp<sup>3</sup>orbital planar
sp<sup>3</sup>orbital trigonal
Repulsion between lone pair and bonded pairs
None of them
|
22 |
The three N - Hσ-bonds are made by |
sp<sup>3</sup>- s overlap
sp<sup>2</sup>- s overlap
P - p overlap
sp - overlap
|
23 |
Three sp2hybrid are co-planar at an angle of |
104.5°
109.5°
107°
120°
|
24 |
During the formation of a chemical bond the potential energy of the system |
Decreases
Increases
Does not change
None of these
|
25 |
The geometry of 4 sp3hybrid orbitals on an atom is |
Square planar
Tetrahedral
Trigonal planar
Linear
|
26 |
Which of the following molecules have sp3hybridized carbon |
CH<sub>4</sub>
C<sub>2</sub>H<sub>4</sub>
C<sub>2</sub>H<sub>2</sub>
CO<sub>2</sub>
|
27 |
|
Excitantion of an electron from 2s to 2p-orbital
Transfer of three electrons from B to the other atoms
Excitation of two electrons form 2s orbital to 2p orbital
Formation of molecular ion
|
28 |
N-atom forms three covalent bonds, its electronic configuration is |
|
29 |
In which of the following theories the hybridizationis considered |
Vsepr
Lewis
Molecule orbital
Valence bond
|
30 |
In H2O molecule the bond angle is |
90°
109.5°
107°
104.5°
|