| 1 |
C6H6Cl6can be obtained from |
HCl and Benzene
Cl<sub>2</sub>and Benzene and AlCl<sub>3</sub>
Cl<sub>2</sub>and Benzene in diffused light
NaOCl and Benzene
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| 2 |
1, 3-Dibromopropane reacts with metallic zinc to form |
Propene
Propane
Cyclopropane
Hexane
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| 3 |
Replacement of Cl of Chlorobenzene to give phenol requires drastic conditions but chlorine of 2, 4-Dinitrochlorobenzene is readily replaced because |
NO<sub>2</sub>makes the electron rich ring at ortho and para positions
NO<sub>2</sub>withdraws electrons at metaposition
NO<sub>2</sub>donate electrons at m-position
NO<sub>2</sub>withdraws electrons at ortho and para position
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| 4 |
Which of the following reacts with chloroform and base to form phenyl isocynaide? |
Nitrobenzene
Phenol
Chlorobenzene
Aniline
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| 5 |
Iodoethane reacts with sodium in ether, the product formed is |
Pentene
Propyne
Butene
Butane
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| 6 |
When ethyl iodide and n-propyl iodide are allowed to react with sodium metal in ether, the number of alkanes that could be produced is |
Only one
Two alkanes
Three alkanes
Four alkanes
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| 7 |
The chloroform reacts with NaOH to give |
CH<sub>3</sub>COONa
Sodium oxalate
CH<sub>3</sub>OH
HCOONa
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| 8 |
Which of the following compounds on oxidation gives benzoic acid? |
Chlorophenol
Chlorotoluene
Chlorobenzene
Benzyl chloride
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| 9 |
The alkyl halide is converted into an alcohol by |
Addition
Substitution
Dehydrohalogenation
Elimination
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| 10 |
The final product formed by distilling ethyl alcohol with excess of Cl2 and Ca(OH)2is |
CH<sub>3</sub>CHO
CCl<sub>3</sub>CHO
CHCl<sub>3</sub>
(CH<sub>3</sub>)<sub>2</sub>O
|
| 11 |
C- X bond is strong in |
CH<sub>3</sub>Cl
CH<sub>3</sub>Br
CH<sub>3</sub>F
CH<sub>3</sub>I
|
| 12 |
The reaction of 4-bromobenzyl chloride with NaCN in ethanol leads to |
4-Bromobenzyl cyanide
4-Cyanobenzyl chloride
4-Cyanobenzyle cyanide
4-Bromo 2-cyanobenzyl chloride
|
| 13 |
Which of the following does not give iodoform test? |
Ethanol
Ethanal
Acetophenone
Bezophenone
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| 14 |
Cl2reacts with CS2in presence of AlCl3to form |
CHCl<sub>3</sub>
CCl<sub>4</sub>
C<sub>2</sub>H<sub>5</sub>Cl
C<sub>2</sub>H<sub>6</sub>
|
| 15 |
Benzene hexachloride is used as |
Dye
Antimaterial drug
Antibiotic
Insecticide
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| 16 |
The reaction between primary amine-chloroform and alcoholic caustic potash is called |
Wurtz reaction
Frankland reaction
Cannizzaro's reaction
Carbylamine reaction
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| 17 |
For the carbylamine reaction we need hot alc.KOH and |
Any amin and chloroform
Chloroform and Ag powder
A primary amine and chloroform
A mono alkyl amine and trichlorom-ethane
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| 18 |
The most reactive compound for electrophilic nitration will be |
Benzyl chloride
Benzoic acid
Nitrobenzene
Chlorobenzene
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| 19 |
What happens when CCl4is treated with AgNO3solution? |
NO<sub>2</sub>will be evolved
A white ppt. of AgCl will form
CCl<sub>4</sub>will dissolve in AgNO<sub>3</sub>solution
Nothing will happen
|
| 20 |
Reaction of ethylamine with chloroform in alcoholic KOH produces |
CH<sub>3</sub>OH
CH<sub>3</sub>NC
C<sub>2</sub>H<sub>5</sub>NC
C<sub>2</sub>H<sub>5</sub>CN
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| 21 |
Ethyl chloride on treatment with aqueous alkali gives |
Ethane
Ethene
Ethanal
Ethanol
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| 22 |
DDT is formed from |
Benzene and Chlorobenzene
Chloral and Chlorobenzene
Chloral and Benzene
Chlorobenzene and chlorine
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| 23 |
Which of the following with aqueous KOH will give acetaldehyde? |
1, 2-Dichloroethane
1,1-Dichloroethane
Chloracetic acid
Ethyl chloride
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| 24 |
Aryl halides are less reactive towards nucleophilic substitution reactions as compared to alkyl halides due to |
The formation of less stable carbonium ion
Resonance stabilization
Larger carbon-halogen bond
The inductive effect
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| 25 |
Carbon atom holding halogen in aryl halides is |
sp<sup>2</sup>-hybridesed
sp<sup>3</sup>-hybridesed
sp-hybridesed
sp<sup>3</sup>d-hybridesed
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| 26 |
Which of the following reagent cannot be used for preparing alkyl chloride from alcohol? |
HCl + anhyd. Zncl<sub>2</sub>
NaCl
PCl<sub>5</sub>
SOCl<sub>2</sub>
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| 27 |
Benzene is prepared from n-hexane in the presence of catalyst |
Cr<sub>2</sub>O<sub>3</sub>
Al<sub>2</sub>O<sub>3</sub>
SiO<sub>2</sub>
All above
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| 28 |
When alkyl is treated with chlorine in the presence of sunlight |
1,3 dichloroproduct is formed
1,4 dichloro product is formed
1,3,5 trichloro product is formed
Only alkyl group is substituted
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| 29 |
Which one does not declourized KMnO4 |
Alkenes
Alkynes
Bezene
All above
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| 30 |
Substitution of halogen in the benzene ring requires catalyst |
AlCl<sub>3</sub>
FeCl<sub>3</sub>
SiO<sub>2</sub>
Organo - nickel
|