| 1 |
Wolf-kishner reduction is used for the reduction of |
Nitro compounds
Carboxylic acids
Carbonyl compounds
Olefins
|
| 2 |
Reductive ozonolysis of benzene produces |
Acetone
Maleic anhydride
Phthalic acid
Glyoxal
|
| 3 |
Reduction with aluminium isopropoxide in excess of Isopropyl alcohol is called Meerwein Ponndroff-Verley reduction (MPV). What will be the final product when cyclohex-2-enone is selectively reduces in MPV reaction? |
Cyclohexanol
Cyclohex-2-enol
Cyclohexanone
Benzene
|
| 4 |
Acetone is oxidized with |
Tollen's reagent
Fehling solution
Acidic dichromate solution
Benedicts solution
|
| 5 |
Which of the following compounds gives a ketone with Grignard's reagent? |
Formaldehyde
Ethanenitrile
Ethyl alcohol
Methyl iodide
|
| 6 |
Acetal is produced by reacting alcohol in the presence of dry HCl with |
Acetaldehyde
Ketone
Ether
Carboxylic acid
|
| 7 |
Which of the following compounds does not react with NaHSO3? |
C<sub>6</sub>H<sub>5</sub>CHO
Acetophenone
Acetone
Acetaldehyde
|
| 8 |
Cyanohydrin of which of the following forms lactic acid |
HCHO
CH<sub>3</sub>COCH<sub>3</sub>
CH<sub>3</sub>CHO
CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CHO
|
| 9 |
Which reaction yields Bakelite? |
Urea with HCHO
Tetramethyl glycol with Hezamethylene diisocyanate
Phenol and HCHO
Ethylene glycol and Dimethylterephthalate
|
| 10 |
Reduction of aldehydes with HI and P gives |
Primary alcohols
Secondary alcohols
Alkanes
Tertiary alcohols
|
| 11 |
A compound possessingα-hydrogen atom, in the presence of dilute alkali formsβ-hydroxy aldehyde. This product on heating with dilute acid forms an unsaturated crotonaldehyde. The compound is |
CH<sub>3</sub>CHO
CH<sub>3</sub>CH<sub>2</sub>CHO
CH<sub>2</sub>= CH - CHO
HC = C - CHO
|
| 12 |
Formalin is an aqueous solution of |
Furfural
Fluorescein
Formaldehyde
Formic acid
|
| 13 |
Acetone is prepared by |
Oxidation of n-propyl alcohol
Oxidation of acetaldehyde
Pyrolysis of calcium acetate
Pyrolysis of calcium acetate as well as acetic acid
|
| 14 |
A compound A has a molecular formula C2Cl3OH. It reduces Fehling solution and on oxidation produces a monocarboxylic acid B.A can also be obtained by the action of Cl2on Ethanol. A is |
Chloral hydrate
CHCl<sub>3</sub>
CH<sub>3</sub>Cl
Chloroacetic acid
|
| 15 |
Self condensation of acetaldehyde in the presence of dilute alkalies gives |
An acetal
An aldol
Mesitylene
Propionaldehyde
|
| 16 |
Which of the following does not react with phenyl hydrazine? |
Ethanol
Ethanal
Acetone
Acetophenone
|
| 17 |
A nucleophilic reagent will readily Attack |
Ethylene
Ethanal
Ethanol
Ethylamine
|
| 18 |
When vapours of isopropyl alcohol are passed over heated copper, the major product obtained is |
Propane
Propylene
Acetaldehyde
Acetone
|
| 19 |
Which of the following is hypnotic? |
Acetaldehyde
Metaldehyde
Paraldehyde
None
|
| 20 |
Wacker method involves the conversion of alkene using PdCl2into corresponding |
Alcohol
Ketone
Aldehyde
Ether
|
| 21 |
Which of the following gives iodoform on heating with a solution of I2containing Na2CO3? |
Ethyl alcohol
Acetone
Ethyl alcohol as well as acetone
Methyl alcohol
|
| 22 |
Aldehydes can be distinguished from ketones by using |
Schiff's reagent
Conc. H<sub>2</sub>SO<sub>4</sub>
Anhy. ZnCl<sub>2</sub>
Resorcinol
|
| 23 |
Aromatic aldehydes undergo disproportionation in presence of sodium or potassium hydroxide to give corresponding alcohol and acid. The reaction is known as |
Wurtz reaction
Cannizzaro reaction
Friedel Craft reaction
Claisen reaction
|
| 24 |
Which of the following does not turn Schiff's reagent to pink? |
Formaldehyde
Bezaldehyde
Aceton
Methyl chloride
|
| 25 |
At room temperature formaldehyde is |
Gas
Liquid
Solid
None of the above
|
| 26 |
Cannizzaro reaction is not given by |
Trimethyl acetaldehyde
Acetaldehyde
Benzaldehyde
Formaldehyde
|
| 27 |
On heating acetaldehyde with ammonical silver nitrate solution, we get |
CH<sub>3</sub>OH
Silver acetate
HCHO
Silver mirror
|
| 28 |
Aldehydes are produce in atmosphere by |
Oxidation of secondary alcohols
Reduction of alkenes
Reaction of oxygen atoms with hydrocarbons
Reaction of oxygen atoms with ozone
|
| 29 |
Propyne on hydrolysis in presence of H2SO4and HgSO4gives |
Acetaldehyde
Acetone
Formaldehyde
None
|
| 30 |
Tollen's reagent is |
Ammonical cuprous chloride
Ammonical cuprous oxide
Ammonical silver bromide
Ammonical silver nitrate
|