| 1 |
Lower carboxylic acids are soluble in water due to |
Low molecular weight
Hydrogen bonding
Dissociation into ions
Easy hydrolysis
|
| 2 |
Hydrolysis of trichloromethane with aqueous KOH gives |
Potassium formate
Acetylene
Chloral
Methanol
|
| 3 |
If acetyl chloride is reducing in the presence of BaSO4and Pd, then |
CH<sub>3</sub>CHO is formed
CH<sub>3</sub>CH<sub>2</sub>OH is formed
CH<sub>3</sub>COOH is formed
CH<sub>3</sub>COCH<sub>3</sub>is formed
|
| 4 |
Which of the following is the strongest acid? |
CF<sub>3</sub>COOH
CBr<sub>3</sub>COOH
CH<sub>3</sub>COOH
CCl<sub>3</sub>COOH
|
| 5 |
The order of decreasing ease of reaction with ammonia is |
Anhydrides, esters, ethers
Anhydrides, ethers, esters
Ethers, anhydrides, esters
Esters, ethers, anhydrides
|
| 6 |
The acid showing salt like character in aqueous solution is |
Acetic acid
Benzoic acid
Formic acid
<span style="color: rgb(34, 34, 34); font-family: arial, sans-serif; font-size: small;">α - Aminoacetic acid</span>
|
| 7 |
In the presence of Aluminium ethoxide, aldehydes get converted into esters. The reaction is known as |
Schmidt reaction
Aldol condensation
Beckmann's rearrangement reaction
Tischenko reaction
|
| 8 |
A colourless liquid, at room temperature reacts with soda lime to form sodium salt of carboxylic acid and ammonia gas. The liquids is |
Propanamide
Propanoic acid
Formamide
Methyl Ethanoate
|
| 9 |
Lactic acid on heating with dil. H2SO4gives |
Acetic acid
Propionic acid
Acrylic acid
Formic acid
|
| 10 |
From the following values of dissociation constants of four acids which value represents the strongest acid? |
2 x 10<sup>-2</sup>
0.02 x 10<sup>-1</sup>
3 x 10<sup>-4</sup>
2 x 10<sup>-4</sup>
|
| 11 |
Acyl halide is formed by reacting PCl5with |
Alcohol
Ester
Amide
Both carboxylic acids as well as esters
|
| 12 |
Which of the following order is incorrect w.r.t property indicated? |
Formic acid > Acetic acid > Propionic acid (ACID STRENGTH)
Cyclohexanol < Phenol < Benzoic acid ( ACID STRENGTH)
Benzamide < Aniline < Cyclohexylamine ( ACID STRENGTH)
FCH<sub>2</sub>COOH > CICH<sub>2</sub>COOH > BrCH<sub>2</sub>COOH (ACID STRENGTH)
|
| 13 |
What is formed when oxalic acid is dehydrated by conc. H2SO4? |
C + CO<sub>2</sub>
CO
CO<sub>2</sub>
CO + CO<sub>2</sub>
|
| 14 |
Acetamide and NaOBr/OH-produce |
Ethanamine
Methanamide
CH<sub>3</sub>CN
NH<sub>3</sub>
|
| 15 |
Acidic hydrolysis of acetamide gives |
Acetaldehyde
Acetic acid
Methyl amine
Formic acid
|
| 16 |
Acetamide is |
Highly acidic
Highly basic
Neutral
amphoteric
|
| 17 |
Ethyl alcohol reacts with acetyl chloride to form |
Ethyl chloride
Acetic acid
Methyleacetate
Ethyleacetate
|
| 18 |
Weakest acid among the followings is |
Acetic acid
Phenol
Water
Acetylene
|
| 19 |
An organic acdi having molecular formula C2H4O2is |
Formic acid
Acetic acid
Oxalic acid
Propionic acid
|
| 20 |
Glacial Acetic acid is |
Pure acetic acid at 100<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
Acetic acid mixed with methanol
Pure acetic acid at 0<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
Pure acetic acid above 16.6<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
|
| 21 |
The reaction of acetaldehyde with HCN followed by hydrolysis gives a product which exhibits |
Metamerism
Tautomerism
Enatiomerism
Geometrical isomerism
|
| 22 |
Which of the following does give violet colour with neutral ferric chloride? |
Acetic acid
Salicaylic acid
Formine acid
Benzoic acid
|
| 23 |
Aspirin is |
Acetyl salicylic acid
Phenyl salicylic acid
Salicylic acid
Benzoic acid
|
| 24 |
When acetamide reacts with Br2and caustic soda, then we get |
Acetic acid
Bromoacetic acid
Methyl amine
Ethylamine
|
| 25 |
Amides on treatment with Br2and KOH are converted into amines, the reaction is known as |
Hoffmann's bromamide reaction
Hoffmann's methylation
Gabriel phthalimide reaction
H.V.Z reaction
|
| 26 |
Between CH3COOH and HCOOH, HCOOH will be |
Less acidic
Equally acidic
More acidic
None
|
| 27 |
Of the following four reactions, formic acid and acetic acid differ in which respect? |
Replacement of hydrogen by sodium
Formation of ester with alcohol
Reduction of Fehling solution
Blue litmus reaction
|
| 28 |
Acetic acid is manufactured by the fermentation of |
Ethanol
Methanol
Ethanal
Methanal
|
| 29 |
Acetic acid is obtained when |
Methyl alcohol is oxidized with potassium permanganate
Calcium acetate is distilled in the presence of calcium formate
Acetaldehyde is oxidized with potassium dichromate and sulphuric acid
Glycerol is heated with sulphuric acid
|
| 30 |
When acetamide is hydrolysed by boiling with acid the product obtained is |
Ethyl amine
Ethyl alcohol
Acetic acid
Acetaldehyde
|