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PPSC Chemistry Part I Physical Chemistry Online Test MCQs With Answers
Question # 1
Which of the following statement is not related to collision theory.
Choose an answer
Molecules must collide with each other to do a chemical reaction
Molecules must posses a minimum amount of energy
Molecules must have proper orientation
Collision theory is applicable to liquid only.
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Question # 2
The half life period of any first order reaction.
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Is half the specific rate constant
Is independent of the initial concentration
Is always the same whatever the reaction
Is directly proportional to the initial concentration of the reactant
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Question # 3
The maximum number of electron is an atom with l = 2 and n = 3 is
Choose an answer
2
6
10
12
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Question # 4
The experimental relationship between rate of the reaction and concentration of the reactants is called.
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Rate law
Law of mass action
Le-Chatelier's principle
Rate constant
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Question # 5
The branch of physics that mathematically describes the wave properties of electron in atomic is called.
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Statistical Mechanics
Quantum Mechanics
Chemical statistics
Thermodynamics
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Question # 6
The number of mole of the solute dissolved per dm3 of the solution is called.
Choose an answer
Molality
Formality
Normality
Molarity
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Question # 7
The number of moles of solute dissolved in 1000 gram of the solvent is called
Choose an answer
Formality
Molality
Molarity
Mole fraction
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Question # 8
Which of the following statement is not related with high quantum yield reasons.
Choose an answer
Formation of reactive intermediates which may act as catalyst
The active molecules may collide with other molecules and activates these molecules.
The reaction may be exothermic and heat evolve may activate other molecule
The primary photo chemical process may be reversed
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Question # 9
The glow of yellow phosphorous as is result of slow oxidation in air is called.
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Chemiluminescene
Luminescence
Bioluminescence
Photolysis
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Question # 10
They hydrolysis of methly acetate is a reaction of.
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First order
Second order
Third oirder
Fourth order
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Question # 11
In a standard Weaton cell the cathode is
Choose an answer
Cadmium amalgam
Mercury
Platinum
Carbon
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Question # 12
The magnetic quantum number (m) specifies the individual orbital in a Sub shell for a given l, m can be.
Choose an answer
l,l- l........-1
l........2, l -3.......-2l
l-l-2,..........-l
l-2,l-4, ............-4l
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Question # 13
Which is the correct configuration of Fe3+ (Z= 26)?
Choose an answer
[Ar] 4s
2
, 3d
6
[Ar] 4s
2
, 4d
5
[Ar] 3d
5
None of these
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Question # 14
The rate constant for 3rd order reaction has the dimentions of.
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mol-2 s-1
I2 mol-2 s-1
mol I -1 s-1
I-1 mol -1 s-1
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Question # 15
The volume of given mass of gas at constant pressure is directly proportional to the absolute temperature.This is a statement of.
Choose an answer
Charles's law
Boyle's law
Avogadro's law
Dalton's law
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Question # 16
Which of the following properties of a system does not change in a state of equilibrium.
Choose an answer
Density
Pressure
Colour
All above properties
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Question # 17
In an adiabatic system, if work in done, the temperature must.
Choose an answer
Increase
Decrease
Remain the same
Increase than decrease
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Question # 18
At constant temperature , the decrease in Halmholts free energy is equal to.
Choose an answer
Decrease in entropy
Increase in entropy
Reversible work done by the system
All types of work done
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Question # 19
In proper rotation (Cn) an object is rotated through an angle of.
Choose an answer
a/n radians
2n/n radians
3n/n radians
4n/n radians
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Question # 20
A drop of a liquid acquires spherical shape because of.
Choose an answer
Its viscous nature
Capillary action
The tendency to acquire minimum surface are
Its shape
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Question # 21
Poise is a unit of.
Choose an answer
Refractive index
Optical activity
Fluidity
Viscosity
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