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MDCAT Chemistry Chapter 16 Alcohols and Phenols Online Test MCQs With Answers
Question # 1
Phenol is completely soluble in water above
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25°C
62.3℃
68.5°C
66.50°c
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Question # 2
Which is an intermediate in Svl
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Ethoxide ion
Alkene
Alkyl halide
Carbocation
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Question # 3
To prepare ethane by Wurtz synthesis the suitable alkyl halide is
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Ethyl iodide
any alkyl iodide
Ethyl chloride
Methyl bromide
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Question # 4
Esterification of CH3COOH isreaction
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Acid base
Electrophilic
Redox
Nucleophilic
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Question # 5
When purely alcoholic solution of sodium/potassiumhydroxide and halogenoalkanes are reacted an alkene is formed, what is the mechanism of reaction?
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Elimination
Debromination
Dehydration
Reduction
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Question # 6
The alkaline hydrolysis of bromoethane shown below gives alcohol as the product: H3C-CH2-Br-------H3C-CH2-OH
The reagent and the condition used in this reaction may be:
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H20 at room temperature
KOH in alcohol
Ethanol. heat
Dilute NaOH(aq) warm
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Question # 7
Ethyl alcohol reacts with PCL and produces:
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Haloalkane
Alkyl halide & H3PO3,
Alkyl halide & POCl3
Alkyl halides &H3PO4.
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Question # 8
Relative acidic strength of alcohol, phenol, water and carboxylie acid is
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Carboxylic acid > Alcohol > Phenol > Water
Carboxylic acid > Phenol > Water> Alcohol
Water > Alcohol> Phenol > Carboxylic acid
Phenol > Carboxylic acid > Alcohol> Water
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Question # 9
The reaction of formaldehyde with HCN is
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Nucleophilic substitution
Electrophilic substitution
Nucleophilic addition
Free radical addition
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Question # 10
An alcohol is converted to an aldehyde with same number of carbon atoms as that of alcohol in the presence of K2Cr2O7/H2S04 the alcohol is
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CH3C(CH3)2OH
(CH3)3COH
CН3СН2СН2OH
(CH3)2CHOH
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Question # 11
The reagent used to distinguish between ethanol and propanal is
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I2/ NaOH
Benedict's reagent
LiAIH
sodium nitroprusside
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Question # 12
Which one of the following groups is indicated when HCI is formed by reaction of ethanol with phosphorous pentachloride?
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Amino group
Halide group
Hydroxyl group
Hydride group
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Question # 13
Which reagent is responsible for the conversion of ketone to secondar alcohul
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NaAlH
NaBH4
Al
Red P
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Question # 14
A mixture of 1-chloropropane and 2-chloro-propane when treated with alcoholic KOH, gives
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Prop-2-ene
Isopropy lene
Propene
A mixture of prop-l-ene
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Question # 15
Out of monochloro, monobromo and mongiodo derivatives of ethane, the mos reactive compound towards nucleophilic substitution will be
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C2H5Br
C2H5Cl
C2H5I
All are equally reactive
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Question # 16
In aldehydes and ketones carbon of carbonyl group is;
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sp³ hyhridized
sp² hybridized
sp hybridized
un hybridized
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Question # 17
What is true about an alcohol and phenol
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Both are more acidic than water
Both react with NaOH
Both produce CO2 with Na2CO3
Both, produce H2 with Na
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Question # 18
Which of the following is soluble in water?
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СН3ОН
CCL4
CHCI3
CS2
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Question # 19
Oxidation of secondary alcohol produces
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Aldehyde
Ketone
Alkyl halide
Ester
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Question # 20
The species which are produced by heterolytic bond breaking and can act as electron pair donor
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Free radicals
Cations
Nucleophiles
electrophile
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Question # 21
The conversion of tertiary alcohols into alkenes in the presence of K2Cr2O7 + H2SO4 is
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Addition reaction
C-H bond cleavage
Elimination reaction
Combustion reaction
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