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MDCAT Chemistry Chapter 13 Fundamental principles of organic chemistry Online Test MCQs With Answers
Question # 1
C-H bond length in the benzene is
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0.99A°
1.09A°
1.12A°
1.34A°
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Question # 2
Acetylide can give back ethyne upon treatment with
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water
strong base
dil. Acid
weak base
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Question # 3
Which one of the following is a powerful electrophile used to attack on the electrons of benzene ring?
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FeCl2
Cl+
FeCl-4
Cl2
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Question # 4
Dehydrohalogenation of alkyl halides happens in the presence of
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Pd
Ni
Zn
KOH/alcohol
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Question # 5
Ethyl and methyl groups are equidistant in a chain, the preference is given to?
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Ethyl
methyl
both ethyl and methyl
methyl mostly
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Question # 6
When 1-butene reacts with bromine, the product formed will be
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1, 3-dihydroxy butane
But-1, 2-diol
1, 3-dihydroxy butan-diol
1,2-dibromo butane
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Question # 7
Which of the following is not an electrophilic substitutional reaction of benzene?
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Free radical chlorination of benzene
Friedel Craft alkylation
Sulphonation
Nitration
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Question # 8
Ethane when completely halogenated in excess of chiorine can form
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Hexachloroethane
Dichloroethane
Pentachloroethane
1.1.2.2-terachloroethane
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Question # 9
Benzene in the presence of AICl3 produces acetophenone when reacts with
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AcetyI chloride
EthyI benzene
Acetic acid
Ethanoic acic
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Question # 10
Naphthalene has two fused aromatic ring of carbon atom the molecular formula
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C10H8
C10H14
C10H10
C12H12
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Question # 11
The reaction that generates an ionic bond is
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Halogenation of ethene
polymerization of ethene
Hydrogenation of ethyne
Reaction of ethyne withs sodamide
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Question # 12
Which of the following is electrophile for alkylation?
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NO+2
SO3
R+
Both a & b
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Question # 13
Aniline is the derivative of the benzene containing the
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Hydroxyl group
Amino group
Amido group
Imido group
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Question # 14
Ethene can give all of the following reactions except
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Addition
Free radical substitution
Hydrohalogenation
Hydration
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Question # 15
During the nitration of benzene the nitrating agent is
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NO3
NO2+
NO2-
HNO3
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Question # 16
The addition of HCI to ethene gives?
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Chloroethane
1,2-dichloroethane
1.1-dichloroethane
2-chloroethane
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Question # 17
The origin ofacidic nature of alkyne is?
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small size of C
Small size of H
polarity of triple bond
sp hybridization
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Question # 18
Glyoxal molecule has?
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two carbonyl groups
One aldehydic and one carbonyl group
Two aldehydic groups
Two carboxyl group
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Question # 19
The reaction of alkyl halide in the presence of alcoholic KOH is
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Substitution
Addition
Acid-base
Elimination
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Question # 20
The compound used to distinguish the ethyne and ethene is
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Alkaline KMnO4
Ammonical AgNO3
Bromine water
Tollen's Reagent
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