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MDCAT Chemistry Online Test MCQs With Answers
Question # 1
Corrundam is ore of which element?
Choose an answer
Al
Th
In
Mg
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Question # 2
A temperature at which two cyrstalline forms of a substances coexist in equilibrium is called
Choose an answer
standard temperature
critical temperature
transition temperature
absolute temperature
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Question # 3
The law of distribution of energy is given by
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Clausius
Maxwell
Bernoulli
Boltzmann
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Question # 4
Chloroform (CHCl3) is?
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Primary alkyl halide
Secondary alkyl halide
Tertiary alkyl halide
a liquid
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Question # 5
Formation of Picric acid from phenol needs heating, one possible reason for it is
Choose an answer
acidity of phenol
e- donating nature of-OH
acidity of picric acid
e- with drawing effect of- NO2
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Question # 6
Covalent bonds are least likely to be formed:
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between atoms of the same element
between atoms of different elements on the right of the periodic table
by head of the group elements with high ionization energies
between an element in Group I and an element in Group Vll
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Question # 7
If there are weak intermolecular forces in a liquid, it will be
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more volatile
less volatile
more dense
less heavy
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Question # 8
The most abundant protein in the human body is
Choose an answer
Collagen
Keratin
Myosin
Albumin
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Question # 9
The relationship between density and molar mass of a gas is
Choose an answer
Directly proportional
Inversly proportional
Straight line
Stoichiometric
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Question # 10
For reaction of methane and chlorine light is not available then
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Reaction will take place rapidly
No Reaction take place
Reaction occurs at double the rate
May all cases occur
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Question # 11
How many kinds of space lattices are possible in a crystal?
Choose an answer
23
7
230
14
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Question # 12
Which of the following compound is least reactive
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HCHO
CH3CHO
CH3COCH3
C6H5CHO
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Question # 13
Elements of group IV-A are
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neither strongly electropositive nor strongly electronegative
strongly electropositive
strongly electronegative
none of these
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Question # 14
The electrical conductivity of the metals decreases with the increasing temperature. This is because
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the number of free electrons decrease
the bonds of the metal atoms become weak
the to and fro motion of the metal ions decrease
the increase of to and fro motion of the metal ions hinders the free movement of electrons
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Question # 15
Anthracene contains number of fused benzene rings
Choose an answer
1
2
3
4
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Question # 16
Kerosene is liquid at room temperature.This is due to:
Choose an answer
organic nature
H-bonding
molecular size
dipole-dipole forces
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Question # 17
When a compressed gas is allowed to expand into a region of low pressure, it produce:
Choose an answer
Vapours
Cooling effect
Heating effect
None of above
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Question # 18
If 1 mole of an ideal gas is heated from 273.15 K to 283.15 K at 1 atmospheric pressure, then increase in its energy is
Choose an answer
0.082 atm.dm
3
0.821 atm.dm
3
8.21 atm.dm
3
40.6 kJ
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Question # 19
The deviation of a gas from ideal behaviour is maximum at
Choose an answer
-10°C and 5.0 atm
100°C and 2.0 atm
-10°C and 2.0 atm
0°C and 2.0 atm
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Question # 20
For a particular halogen, the reactivity of alkyl halides
Choose an answer
remains same with C-increase
decreases with C-increase
increases with C-increase
decreases with C-decrease
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Question # 21
NH
3
shows maximum boiling among the hydrides of group V elements. The is due to:
Choose an answer
pyramidal structure of NH
3
H-bonding between its molecules
enhanced electronegative character
very small size of nitrogen
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Question # 22
Li resembles with Mg, because
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the ratio of their charge to size is nearly the same
both have nearly same size
both are metallic in nature
both are found together in nature
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Question # 23
Which of the following is not molecular crystal
Choose an answer
Sugar
Iodine
Ice
Graphite
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Question # 24
The movement of gas molecules from a region of high pressure to vacuum is called:
Choose an answer
Evaporation
Effusion
Conduction
Diffusion
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Question # 25
CO
2
gas is dissolved in water due
Choose an answer
dipole-dipole interactions
higher molecular mass of CO
2
ion dipole attractive forces
hydrogen bonding
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Question # 26
Partial pressure of gases in a mixture depend upon:
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Number of moles
Number of protons
Number of electrons
Number of neutrons
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Question # 27
Sugar crystals belong to the system
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cubic
monoclinic
triclinic
orthorhombic
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Question # 28
Butane has isomeric forms
Choose an answer
3
4
2
1
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Question # 29
If the rate of the reaction is equal to the rate constant, the order of the reaction is
Choose an answer
3
1
0
2
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Question # 30
In the reaction A+B→ Products, if B is taken in excess, then it is an example of
Choose an answer
Second order reaction
zero order reaction
Pseudo first order reaction
first order reaction
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Question # 31
If R, T, M, V and P are gas constant, temperature, molar mass, volume and pressure then density is given by:
Choose an answer
M/V
RT/M
PM/RT
V/M
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Question # 32
Gases are effused through a whole due to ______ motion
Choose an answer
Vibration
Rotaional
Translational
Chaotic
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Question # 33
The phenomenon in which sudden expansion of a gas causes cooling is called
Choose an answer
evaporation
cooling
Joule Thomson effect
sublimation
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Question # 34
A line parallel to x-axis is obtained when graph is drawn between
Choose an answer
Volume on abscissa & pressure on ordinate
Volume on abscissa & PV on ordinate at all conditions
Pressure on abscissa & PV on ordinate at constant temperature
None of these
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Question # 35
The elements for which the value of ionization energy is low can
Choose an answer
Gain electrons readily
Lose electron less readily
Gain electrons with difficulty
Lose electron readily
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Question # 36
On the basis of intermolecular forces diamond is a
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ionic solid
covalent solid
metallic solid
molecular solid
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Question # 37
Neutralization of acid-base is
Choose an answer
Spontaneous
Exothermic
Non spontaneous
Both "a" and "c
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Question # 38
One dm3 of H2 and O2: has different masses but no. of particles are
Choose an answer
same
H2 has greater
different
O2 has greater
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Question # 39
In gasses and liquid, temperature is the measure of:
Choose an answer
Average transnational kinetic energies of molecules.
Average vibrational kinetic energies of molecules.
Average rotational kinetic energies of molecules.
None of above.
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Question # 40
When does average rate become equal to instantaneous rate of reaction
Choose an answer
At the start of reaction
time interval is zero
at the end of reactior
time interval approaches zero
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Question # 41
Equal volumes of gases at the same temperature and pressure contain equal number of particles.This statement is direct consequence of
Choose an answer
Perfect gas law
Partial law of volumes
Charle's law
Ideal gas equation
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Question # 42
The highest melting point is observed by
Choose an answer
Butanoic acid
Propanoic acid
Pentanoie acid
HCI
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Question # 43
Tertiary alcohols are the easiest to dehydrate because
Choose an answer
They form stable carbocation
They have less hydrogen
They have bigger size
They are polar
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Question # 44
Which compounds is alicyclic in nature?
Choose an answer
Cyclobutane
Iso-bstand
n-Butane
Toluend
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Question # 45
The maximum hydrogen bonding is in:
Choose an answer
diethyl ether
ethanol
water
benzene
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Question # 46
The specifie substance (metabolite) that fits on the enzyme surface and is converted to products is called
Choose an answer
Co-factor
Isoenzyme
Prosthetic group
Substrate
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Question # 47
As gases can adopt the shape of the container so they have
Choose an answer
no fixed shapes
fixed shapes
different shapes
definite shapes
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Question # 48
During esterifcation, the alcobol molecule acts as:
Choose an answer
Oxidizing agent
Electrophile
Reducing agent
Nucleophile
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Question # 49
When we dissolve 15.8 g of KMnO4 in 1000g of H20. The solution is
Choose an answer
, 0.1 M
0.1 M
0.2 M
0.2 M
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Question # 50
Which one of the following is not true of metallic bonding?
Choose an answer
it gives rise to excellent electrical conductivity
electrons are following to move throughout the structure
the strength of metallic bonds increases down a group
the strength of metallic bonding affects the boiling point of metals
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Question # 51
Water has high boiling point which is due to
Choose an answer
weak dissociation
hydrogen bonding
high specific heat
high dielectric constant
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Question # 52
What types of bonds are broken when water turns into steam on heating?
Choose an answer
covalent
permanent dipole interactions
hydrogen bonds
induced dipole interactions
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Question # 53
At higher temperature what is true for gases
Choose an answer
pressure is decreased
volume is decreased
number of moles are decreased
KE is increased
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Question # 54
Carboxylic acids reacts with sodium carbonate, & gas evolved in this reaction
Choose an answer
CO2
H2
CO
Both a &b
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Question # 55
Which pair of molecules have debye force
Choose an answer
Ne and Ne
Argon and water
Na
+
ion and water
Water and water
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Question # 56
When 1-butene reacts with bromine, the product formed will be
Choose an answer
1, 3-dihydroxy butane
But-1, 2-diol
1, 3-dihydroxy butan-diol
1,2-dibromo butane
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Question # 57
Surface tension is measured by
Choose an answer
viscometer
barometer
stalagmometer
manometer
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Question # 58
Graham s law refers to
Choose an answer
Boiling point of gases
Gas compression problems
Gaseous diffusion
Volume changes of gases due to change in temperature
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Question # 59
NaCI is completely ionized in water due to the presence of:
Choose an answer
dipole-dipole forces
ion- dipole forces
H-bonding
London dispersimforces
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Question # 60
Which of the following is not heterocyclic compound?
Choose an answer
Naphthalene
Furan
Pyridine
Pyrrole
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Question # 61
When a compressed gas is allowed to pass through a nozzle of a jet into a region of low pressure, it produces
Choose an answer
cooling
vaporization
fusion
expansion
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