Question # 1

H₂+ L₂----2Hl

In the above equilibrium system, if the concentration of reactants at 25°C is increased, the value K_C will :

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Remains Constant

Increases

Cecreases

Depends upon nature of reactans

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Decrease in temperature favour more dissolution of the salt

Increase in temperature favour more dissolution of the salt

Lowering pressure favour more dissolution of the salt

Increasing pressure favour more dissolution of the salt

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Increase in concentration of 1

Decrease in concentration of I₂

Increase in temperature

Increase in total pressure

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4 mole per dm³

2 mole per dm³

0.33 mole per dm³

0.67 mole per dm³

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High temperature

Low temperature

Low pressure

High pressure

pH of water is 7, if 0.01 M NaOH is added, than its pH is

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12

14

zero

10

The correct relation b/wK_{c and}K_{p is :}

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K_p = K_c[P/N] ^Δn

K_{c =}K_p(RT) ^Δn

K_{p =}K_c(RT) ^Δn

strength of an acid can be determined by

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P^ka

P^kp

P^oH

P^kw

N₂ + O₂ ⇌2NO

The unit of K_c for tis reaction will be:

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No unit

mol^-2 dm^-3

mol^-1 dm^-3

mol^-2 dm⁺³

Which of the following favours the reverse reaction in chemical equilibrium?

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Increasing the concentration of the reactant

Removal of the least one of the products at regular intervals

Increasing the concentration of one or more of the products

None of these

The pH of 10^-3mole dm^-3of an aqueous solution of H₂SO₄is

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3.0

2.7

2.0

1.5

In an exothermic reaction, a 10° rise in temperature will

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Decrease the value of equilibrium constant

Double the value of K_c

Not produce any change in K_c

Produce some increase in K_c

The equilibrium constant in a reversible chemical reaction at a given temperature

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Depends on the initial concentration of the reactants

Depends on the concentration of one of the products at equilibrium

Does not depend on the initial concentration of rectants

It is characteristic of the reaction

The best buffer is prepared when molar concentrations of the salt and acid are equal, then its pH and pKa value are related

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pH = pKa

pH < pKa

pH > pKa

pH x pKa = 14

Acetic acid is 1.33% ionized, In 1000 molecules of 0.1 M acetic acid the number of H⁺ions is

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1.33

13.3

1.33

1

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Introduction of an inert gas at constant volume

Introduction of PCl₃(g) at constant

Introduction of PCl₅(g) at constant volume

Introduction of Cl₂at constant volume

The state of equilibrium refers to

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State of rest

Dynamic state

Stationary state

State of inertness

ph of the buffer CH₃COOh + CH₃COONa is 3.76. If the mixture contains 1 molar acetic acid and 0.1 molar sodium acetate, then pKa of this buffer is

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3.76

4.76

5.76

6.76

The solubility of PbF₂is 2.6 x 10^-3mole dm^-3then its solubility product is

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2.6 x 10^-3

6.76 x 10^-6

5.2 x 10^-6

7.0 x 10^-8

2SO₂+ O₂⇌2SO₂H= 188KJ mole^-1

Which statement about following equilibrium is correct :

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The value ofK_pfalls with arise in temperature.

The value ofK_pis equal tok_c.

The value ofK_pfalls with the increase pressure.

Adding V₂O₅catalyst increase the equilibrium yield of Sulphur trioxide.

Le-chatlier's principle is applied on the reversible reaction in order to

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Determine the rate of reaction

Predict the direction of reaction

Determine the extent of reaction

Find best conditions for favorable shifting the position of equilibrium

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The value of K_pfalls with a rise in temperature

The value of K_pfalls with increasing pressure

Adding V₂O₅catalyst increase the equilibrium yield of sulphur trioxide equilibrium yield of sulphur trioxide

The value of K_pis equal to K_c

Product of concentration of ions raised to the power equal to the co-efficient of ions in balanced equation for saturated solution of a salt is called

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Ionic product

Equilibrium constant K_c

K_w

Solubility product (K_sp)

K_spvalue for PbSO₄= 1.8 x 10^-8mole²dm^-6. The maximum concentration of Pb⁺⁺ions is

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1.34 x 10^-4mole dm^-3

1.8 x 10^-4

3.6 x 10^-16mole dm^-3

1.0 x 10^-8mole dm^-3

Reactions that proceed on both sides and never go to completion are called

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Irreversible reactions

Reversible reactions

Opposing reactions

Spontaneous reactions

The ionic product of H⁺ions and OH^-in water is called ionization constant of water Kw. The value of Kw at 25°C is

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0.11 x 10^-14

0.30 x 10^-14

1.0 x 10^-14

3 x 10^-14

An aqueous solution is neutral when its

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pH = 14

pH = zero

pH = 7

Kw = 10^-7

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Temperature is increased

Pressure is increased

HCl is added

HCl is removed

Chemical equilibrium involving reactants and products in more than one phase is called

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Static

Dynamic

Homogeneous

Heterogeneous

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