Question # 1

For which system does the equilibrium constant, kc has units of (concentration) ?

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N₂+3H_2-------2NH₃

H₂+L₂---------2HL

2NO₂----------N₂O₄

2HF--------H2+F₂

pH of 0.1 molar HCl solution is

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1

zero

13

14

The rate at which a substance reacts is directly proportional to its active mass and the rate of reaction is directly proportional to the product of the active masses of reacting substances, is called

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Law of conservation of energy

Le-Chateliers principle

Law of mass action

None of these

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HF is stable and does not decompose even at 2000°C

HF is stable and slowly decomposes at 2000°C

HF is strong acid

HF produces equal moles of hydrogen and fluorine

The rate of forward reaction is two times that of the reverse reaction at a given temperature and identical concentration, K equilibrium is

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0.5

1.5

2.5

2.0

For which system does the equilibrium constant. K_chas units of

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K_bvalue of NH₄OH is 1.81 x 10^-5and its conjugate acid has K_a= 5.7 x 10^-10pKb of the base is 4.74, pKa of its conjugate acid is

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-4.74

4.74

10

9.26

A chemical reaction A---------->B is said to be in equilibrium when :

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Rate of transformation of A to B is equal to B to A.

50% reactant has been changed to B.

Conversion of A to B is 50% complete

Complete conversion of A to B has taken place.

1.1 mol of A is mixed with 2.2 mol of B and the mixture is kept in on litre flask till the equilibrium is reached. At equilibrium, 0.2 mol of C is formed. If the equilibrium reaction is A+2B 2C+D, the value of equilibrium constant is

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0.002

0.004

0.001

0.003

strength of an acid can be determined by

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P^ka

P^kp

P^oH

P^kw

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The pH of 10^-3mole dm^-3of an aqueous solution of H₂SO₄is

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3.0

2.7

2.0

1.5

In exothermic reversible reaction increase in temperature shift the equilibrium to :

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Remains unchanged.

Product side.

Reactant side.

None of above.

What happens when reaction is at equilibrium and more reactant is added :

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Forward reaction rate is increased.

Forward reaction rate is decreased.

Backward reaction rate is increased.

Equilibrium remains unchanged.

The rate of which the reaction proceeds is directly proportional to the product of the active masses of the reactants is according to

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Law of mass action

Le Chateliers principle

Equilibrium law

Law of constant proportion

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32

64

16

4

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Shift reaction toward forward direction

Shift reaction backward

Lower the value of K_c

No change in reaction

If pH of buffer of 1 mole dm^-3of HCOOH + 0.1 mole dm^-3HCOONa having pKa = 3.78 is

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1.78

2.78

3.78

4.78

According to Le-Chatelier's principal, adding heat to a solid and liquid in equilibrium will cause the

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Amount of solid to decrease

Amount of liquid to decrease

Temperature to rise

Temperature to fall

K_spvalue for PbSO₄= 1.8 x 10^-8mole²dm^-6. The maximum concentration of Pb⁺⁺ions is

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1.34 x 10^-4mole dm^-3

1.8 x 10^-4

3.6 x 10^-16mole dm^-3

1.0 x 10^-8mole dm^-3

K_bfor NH₄OH is 1.81 x 10^-5, then K_avalue of its conjugate base is

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1.81 x 10⁺⁵

1.81 x 10^-9

5.5 x 10^-9

5.5 x 10^-10

pKb value of NH₄OH is 4.74. If the concentration of NH₄OH is 1 molar containing 0.1 molar NH₄Cl, then pH of this buffer will be

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3.74

10.26

4.74

9.26

Extent to H₂ + L₂à2Hl can be increased by :

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Increasing temperature.

Increasing product.

Increasing pressure.

Adding a catalyst.

An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtration. What are the main ion in filtrate?

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Ag⁺ and NO_3- only

Ag⁺ and Ba² and NO^-3

Ba² and NO^-3

Ba² and NO^-3and Cl-

Hydrogen gas and iodine vapours combine to form Hl at 425°C, the same composition of mixture is present if we start with decomposition of Hl. It suggests

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A static equilibrium

Law of mass action

A dynamic equlibrium

Irreversible reaction

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High temperature

Low temperature

Low pressure

High pressure

Buffers having pH less than 7 are made

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Mixture of weak acid + salt of it with strong base

Mixture of weak acid + salt of it with weak base

Mixture of weak base + salt of it with strong acid

Mixture of weak base + salt of it with weak base

Product of concentration of ions raised to the power equal to the co-efficient of ions in balanced equation for saturated solution of a salt is called

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Ionic product

Equilibrium constant K_c

K_w

Solubility product (K_sp)

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High temperature and low pressure

Low temperature and high pressure

Low temperature and low pressure

High temperature and high pressure

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Low pressure

High pressure

High temperature

High concentration of SO₂

Two moles of HI was heated in a sealed tube at 440°C till the equilibrium was reached. HI was found to be 22% decomposed. The equilibrium constant for dissociation is

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0.282

0.0796

0.0199

1.99

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