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ECAT Chemistry Chapter 21 Alkyl Halides Online Test MCQs With Answers
Question # 1
General formula of alkyl halide is:
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R----X
R----OH
R------COH
R------COOH
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Question # 2
Benzene reacts with chlorine to form benzene hexachloride in presence of
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Nickel
AlCl
3
Bright sunlight
Zinc
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Question # 3
What is the total number of different chloroethanes, formula C
2
H
6-n
Cl
n
, where n can be any integer from 1 to 4
Choose an answer
4
6
7
8
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Question # 4
Which reaction is example of nucleophilic substitution
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Question # 5
Benzene hexachloride is used as
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Dye
Antimaterial drug
Antibiotic
Insecticide
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Question # 6
E
2
has molecularity :
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One
Two
Three
Half
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Question # 7
Which of the following reacts with chloroform and base to form phenyl isocynaide?
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Nitrobenzene
Phenol
Chlorobenzene
Aniline
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Question # 8
1, 3-Dibromopropane reacts with metallic zinc to form
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Propene
Propane
Cyclopropane
Hexane
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Question # 9
Which of the following undergoes uncleophilic substitution exclusively by S
N
1 mechanism?
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Benzyl chloride
Ethyl chloride
Chlorobenzene
Isopropyl choride
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Question # 10
The order of reactivity for a given halogen in Grignard's reagent is:
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CH
3
X > C
2
H
5
X > C
3
H
4
X > C
4
H
4
X
C
2
H
5
X > C
3
H
7
X > C
4
H
5
X > CH
4
X
C
3
H
7
X > C
4
H
7
X > CH
3
X > C
2
H
5
X
C
4
H
4
X > C
3
H
7
X > C
2
H
5
X > CH
4
X
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Question # 11
When alkyl halide is heated with aqueous solution of ammonia at 100°C the major product is
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Primary amine
Secondary amine
Tertiary amine
Mixture of amines and salt
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Question # 12
Which of the following reagent cannot be used for preparing alkyl chloride from alcohol?
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HCl + anhyd. Zncl
2
NaCl
PCl
5
SOCl
2
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Question # 13
Which halide among the following is used as methylating agent?
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CH
3
l
C
2
H
5
Cl
C
2
H
5
Br
C
6
H
5
Cl
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Question # 14
CFCs undergo homolytic fission by uv light in the stratosphere which radical could result from this irradiations of CHCICF
2
Cl.
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CHF Cl C FCl
CH Cl CF
2
Cl
CHF CF
2
Cl
C FCl CF
2
Cl
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Question # 15
Grignard's reagent was prepared in:
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1900
1910
1920
1930
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Question # 16
Steps in SN , reactions are:
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One
Two
Three
Four
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Question # 17
The most reactive compound for electrophilic nitration will be
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Benzyl chloride
Benzoic acid
Nitrobenzene
Chlorobenzene
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Question # 18
What is the total number of different chloroethanes of formula C
2
H
6-n
Cl
n
possible (n may be 1 to 6)
Choose an answer
6
8
9
10
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Question # 19
Ethyl alcohol gives ethyl chloride with the help of
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SOCl
2
NaCl
Cl
2
KCl
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Question # 20
Metal used in the preparation of Grignard's reagent is:
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Ca
Na
Mg
Zn
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Question # 21
Dehydrohalogenation of alkyl halides produces
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Alcohol
Alkane
Alkene
Alkyne
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Question # 22
Elimination bimolecular reactions involve:
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First order Kinetics
Third order kinetics
Zero order kinetics
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Question # 23
Grignard's reagent on treatment with dry CO
2
and HCI yields
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Ester
Alcohol
Carboxylic acid
Aldehyde
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Question # 24
The reactivity order of alkyl halides for a paricular alkyl group is
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Fluoride > chloride > bromide > iodide
Chloride > bromide > fluoride > iodide
Iodide > bromide > chloride > fluoride
Bromide > iodide > chloride > fluoride
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Question # 25
When primary amine reacts with chloroform in ethanolic KOH, then the product is
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An isocyanide
An aldehyde
A cyanide
An alcohol
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Question # 26
Any other aldehyde except formaldehyde on reaction with Grignard's will produce
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Secondary alcohol
Primary alcohol
Tertiary alcohol
Aromatic alcohol
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Question # 27
Best medhod of preparation of alkyl halide from alcohals is by its reaction with:
Choose an answer
HX
SOCl
2
Px
5
and PX
3
All
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Question # 28
A carbon atom carrying a postitive charge and attached to three other atoms of groups is called
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Caronium ion
Carbanion
Oconium ion
Carba ion
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Question # 29
Which of the following with aqueous KOH will give acetaldehyde?
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1, 2-Dichloroethane
1,1-Dichloroethane
Chloracetic acid
Ethyl chloride
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Question # 30
Which represents nucleophilic aromatic substitution reaction?
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Reaction of benzene with Cl
2
in sunlight
Benzyl bromide hydrolysis with water
Reaction of NaOH with dintrofluoro benzene
Sulphonation of benzene
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Question # 31
The compounds or species in search of electrons are called
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Elctrophiles
Nucleophile
Nitrities
Bases
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