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ECAT Chemistry Chapter 21 Alkyl Halides Online Test MCQs With Answers
Question # 1
Alkyl halides are considered to be very reactive compounds towards nucleophiles because
Choose an answer
They have an electrophilic carbon
They have an electrophilic carbon and a good leaving group
They have an electrophilic carbon and a bad leaving group
They have a nucleophilic carbon and a good leaving group
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Question # 2
By simply reacting Grignand's reagent with water we get
Choose an answer
An alkane
Higher alkane
An alkene
An alkyne
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Question # 3
The rate of E
1
reaction depends upon
Choose an answer
The concentration of substrate
The concentration of nucleophile
THe concentration of substrate as well as nucleophile
None of the above
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Question # 4
SN
2
reactions can be best carried out with:
Choose an answer
Prl. alkyl halide
Sec. Alkyl halide
Ter. Alkyl halide
All of three
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Question # 5
Most reactive halide towards S
N
1 reaction is
Choose an answer
n-Butyl chloride
sec-Butyl chloride
tert-Butyl choride
Allyl chloride
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Question # 6
On warming with silver powder,chloroform is converted into
Choose an answer
Acetylene
Hexachloroethane
1,1,2,2-tetrachloroethane
ethylene
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Question # 7
If ketone reacts with Grignard's reagent, it also produces alcohol, But it will be a
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primary alcohol
Secondary alcohol
Tertiary alcohol
Aromatic alcohol
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Question # 8
How many monochlorobutanes will be possible on chlorination of n-butane?
Choose an answer
1
2
3
5
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Question # 9
Replacement of Cl of Chlorobenzene to give phenol requires drastic conditions but chlorine of 2, 4-Dinitrochlorobenzene is readily replaced because
Choose an answer
NO
2
makes the electron rich ring at ortho and para positions
NO
2
withdraws electrons at metaposition
NO
2
donate electrons at m-position
NO
2
withdraws electrons at ortho and para position
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Question # 10
Which of the following undergoes uncleophilic substitution exclusively by S
N
1 mechanism?
Choose an answer
Benzyl chloride
Ethyl chloride
Chlorobenzene
Isopropyl choride
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Question # 11
Thre rate of S
N
2 reaction depends upon the
Choose an answer
Concentration of alkyl halides
Concentration of nucleophile
Concentration of alkyl halides and nucleophile
None of the above
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Question # 12
What is the total number of different chloroethanes, formula C
2
H
6-n
Cl
n
, where n can be any integer from 1 to 4
Choose an answer
4
6
7
8
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Question # 13
Dehydrohalogenation of alkyl halides produces
Choose an answer
Alcohol
Alkane
Alkene
Alkyne
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Question # 14
When metallic sodium in ether is heated with ethyl chloride, which alkane is formed
Choose an answer
Propane
Ethane
Iso-butane
N-butane
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Question # 15
The reaction of an alkyl halide with RCOOAg produces
Choose an answer
Ester
Ether
Aldehyde
Ketone
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Question # 16
The alkyl halide is converted into an alcohol by
Choose an answer
Addition
Substitution
Dehydrohalogenation
Elimination
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Question # 17
In primary alkyl halides, the halogen atom is attached to a carbon which attached to how many carbon atoms?
Choose an answer
Two
Three
One
Four
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Question # 18
Which of the following reacts with chloroform and base to form phenyl isocynaide?
Choose an answer
Nitrobenzene
Phenol
Chlorobenzene
Aniline
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Question # 19
Reaction of Griganard's reagent with CO
2
gives:
Choose an answer
Aldehyde
Pri-alcohol
Sec-alcohal
Carboxylic acid
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Question # 20
What happens when CCl
4
is treated with AgNO
3
solution?
Choose an answer
NO
2
will be evolved
A white ppt. of AgCl will form
CCl
4
will dissolve in AgNO
3
solution
Nothing will happen
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Question # 21
To get DDT, chlorobenzene has to react with one of the following compound in the presence of conc.H
2
SO
4
Choose an answer
Trichloroethane
Dichloroacetone
Dichloroacetaldehyde
Trichloroacetealdehyde
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Question # 22
For which mechanisms, the first step involved is the same:
Choose an answer
E
1
and E
2
E
2
and SN
2
E
2
and E
1
E1 and SN
1
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Question # 23
SN2 reaction can be best carried out with
Choose an answer
Primary alkyl halides
Secondary alkyl halides
Tertiary alkyl halides
All the three
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Question # 24
Choose an answer
Electronphilic substitution
Electrophilic addition
Free radical substitution
Nuclephilic substitution
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Question # 25
Dehydrohalogenation of alkyl halides give
Choose an answer
Alkanes
Alkenes
Alkynes
Alkdehyde
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Question # 26
Which of the following chlorocompounds is heat easily hydrolysed by hydorxide ion to give the product indicated
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Question # 27
Elimination bimolecular reactions involve:
Choose an answer
First order Kinetics
Third order kinetics
Zero order kinetics
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Question # 28
Alkanes may be prepared by the reaction of alkyl halides with
Choose an answer
Alcohol
Carboxylic acid
Grignard reagents
None of these
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Question # 29
When primary amine reacts with chloroform in ethanolic KOH, then the product is
Choose an answer
An isocyanide
An aldehyde
A cyanide
An alcohol
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Question # 30
When an alcohol reacts with SOCI
2
an alkyl halide is formed. What are two other products
Choose an answer
SO
2
and HCI
SI
2
and H
2
O
HCI and H
2
O
H
2
S and HCI
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Question # 31
In which of the following reactions is the inorganic reagent acting as a nucleophile
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