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ECAT Chemistry Chapter 11 Reaction Kinetics Online Test MCQs With Answers
Question # 1
Which statement is not correct
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Enzymes catalyst a specific reaction
Enzymes show catalytic activity at a specific temperature
The catalytic activity of enzymes is stopped if optimum pH is changed
The catalytic activity is poisoned by a co-enzymes
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Question # 2
The number of atoms or molecules whose concentrations determine the rate of the reaction is called
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Molecularity
Order
Rate of reaction
Rate constant
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Question # 3
The rate of reaction is denoted by
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dc/dp
dc/ac
dc/dT
dc/dt
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Question # 4
Factor which slows down the rate of reaction is
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Small size of the particles of the reactant
High temperature of reaction
More concentration of reactant
Lowering the temperature
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Question # 5
In the hydrolysis of CH
3
COOC
2
H
5
the acid produced is
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Inhibitor
Catalyst
Auto catalyst
None of above
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Question # 6
If the rate of decay of radioactive isotope decreases from 200 cpm to 25 cpm after 24 hours, what is its half life :
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8 hours
6 hours
4 hours
3 hours
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Question # 7
By the use of catalysis the energy of activation is
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Decreased
Increased
Not affected
None
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Question # 8
The unit of rate constant k is the same as that of the rate of reaction in
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First order reaction
Second order reaction
Third order reaction
Zero order reaction
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Question # 9
Choose an answer
2
3
4
9
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Question # 10
Rate law of an equation is obtained :
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From a balance equation.
Can be calculated theoretically as well as determined experimentally.
It is only calculated theoretically.
Experimentally.
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Question # 11
For a chemical reaction to take place the particles must have sufficient energy for the effective collisions, the energy is called
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Average energy
Activation energy
Potential energy
Collision energy
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Question # 12
Rate of chemical reaction depends upon :
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The number of total collisions per second.
Number of molecules taking part in a chemical reaction.
Number of fruitful collisions per second
Number of fruitless collisions per second.
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Question # 13
The rate constant k of a reaction activation energy Ea and temperature are related by Arrhenius in the form of an equation which is
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Question # 14
With increases in temperature of 10 K of the reacting gases the rate of reaction is doubled because
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Increase in number of collisions
Number of molecules having energy more than Ea is doubled
Increase in order of reaction
Increase in surface area
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Question # 15
The experimental relationship between a reaction rate and the concentration of reactants is known as
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Order
Molecularity
Rate constant
Rate law
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Question # 16
The reaction rate is expressed in the units of
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mol dm
-3
S
-
mol dm
-3
mol dm
-3
N
-
dm
-3
S
-
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Question # 17
When we perform the same reaction by taking two different initial concentrations of a reactant for a second order reaction then
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Reaction becomes exothermic
Energy of activation is different
Mechanism of reaction is changed
Half life period is changed
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Question # 18
When the rate of reaction is entirely independent of the conc. of reaction molecules then order of reaction is
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Zero
First
Second
Third
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Question # 19
In the manufacture of NH
3
by Haber's process catalyst used is iron its catalytic efficiency is poisoned by
Choose an answer
Presence of Al
2
O
3
Presence of Cr
2
O
3
MnO
2
CO present with H
2
gas
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Question # 20
The rate of reaction :
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Decreases as the reaction proceeds
Increases as the reaction proceeds
May decrease or increase reaction proceeds
Remains same as the reaction proceeds
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Question # 21
In zero order reaction, the rate is independent of :
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Temperature of reaction
Concentration ofreactants
Concentration of products
None of these.
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Question # 22
Dilatometric method is used for rate determination when
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Reactions involving change of optical
Reactions involving change of optical activity
Reactions involving small volume change
None of above
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Question # 23
It rate law of an equation is written as
dx/dt=K[A][B] ?
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Reaction is independent of the concentration of A and B.
Product is decreasing with passage of time.
Reactant in increasing with passage of time.
Reactant is increasing with passage of time.
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Question # 24
Optical rotation method is sued when
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Reaction involve ions
Change of refractive indices
Reactions involving change of optical activity
None of the above
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Question # 25
Which one of the following reaction rate is effected by the light
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Question # 26
When initial concentration of reactants an order of reaction is given, then its half life period can be calculated by the equation
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Question # 27
If a reactant or product of a reaction absorbs radiation, then physical method for determining the rate of reaction is
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Spectrometry
Refractometry
Conductivity measurement
Optical method
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Question # 28
Half life period of a first order reaction is independent of:
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Presence of catalyst.
Conditions of temperature
Initial concentration of the compound
All of above
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Question # 29
Choose an answer
Zero
1
2
1.5
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Question # 30
Value of rate constant k is specific for a reaction, and varies from reaction to reaction. The value of k of a reaction changes with
Choose an answer
Time
Temperature
Concentration of reactants
Order of reaction
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Question # 31
Group l-A elements react with water fastly than the reaction of group ll-A elements because
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l
A
elements are more soft then ll
A
l
A
elements are non-metals
l
A
elements have 1 electron in their outermost s-orbital and are strongly electropositive
l
A
elements make ionic bond
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